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A kind of dyeing method of leuco body pad dyeing

A dyeing method and leucosome technology, applied in the dyeing field, can solve the problems of decreased tearing strength, insufficiently stable fabrics, and weak fiber binding force, etc., and achieve the effects of stable reduction potential, improved production efficiency, and strong binding ability

Active Publication Date: 2020-11-17
李瑞卿 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above dyeing methods mostly have the following problems: (1) Polyester is dyed with disperse dyes, and the light fastness is poor; after dyeing, reduction cleaning is required, and the color fastness of deep and thick colors is poor, and fades and grays after washing; When dyeing dyes, most of them need to use high-temperature process, and the cost of energy consumption is relatively high; disperse dyes are also prone to heat condensation, which is easy to cause defects such as color flowers and stains; There is a problem that it cannot meet the needs of consumers; reactive dyes dyed nylon has poor levelness, and high-temperature dyeing can easily cause the fabric to feel hard and even reduce the tear strength, especially 10D-30D light and thin nylon. The strength damage is relatively large; (3) When reactive dyes are dyed in dark colors, the soaping fastness of the dyed finished product is generally poor, and it is easy to fade, lighten, and become old after repeated washing; the fabrics dyed with reactive dyes are not resistant to rinsing, if 84 disinfectant is added to the laundry It will cause partial decolorization and affect the appearance of wearing; (4) the dyeing process of acid or reactive dyes is longer, and the operation control is more difficult
Leucoic acid is difficult to process and is relatively seldom used; suspension dyeing is more commonly used, but the dye suspension is insoluble in water, and the dye molecule particles in the dye solution are large, it is difficult to fully enter the fiber, and the binding force with the fiber is weak, so The optimum level of fastness that should be achieved cannot be guaranteed; the leuco dyeing method is to convert the vat dye into the sodium salt of the leuco by pre-reduction, which is absorbed by the fiber in the dye bath, and then oxidized to form a water-insoluble dye The color lake is fixed on the fiber, which can give full play to the advantages of vat dyes
[0005] However, the existing leuco dyeing still has the following disadvantages: because the initial dyeing is faster and easy to dye flowers; the amount of caustic soda and reducing agent is still high, which is easy to cause fiber damage
[0008] The dyeing of vat dyes generally adopts the suspension pad dyeing method. The main reason is that the reducing agent decomposes too fast in the leuco state, is not stable enough, and the fabric is easy to be dyed.
As a result, the leuco dyeing method cannot be widely used in the pad dyeing process

Method used

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  • A kind of dyeing method of leuco body pad dyeing
  • A kind of dyeing method of leuco body pad dyeing
  • A kind of dyeing method of leuco body pad dyeing

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] This embodiment is a comparative experiment of the composite reducing agent and hydrosulfite under the same alkaline environment.

[0028] The higher the concentration of mother liquor, the stronger its reducibility. Configure the high-concentration mother liquor of the composite reducing agent and hydrosulfite of the same concentration, configure the alkali of 40g / L, the mother liquor 1 of the composite reducing agent of the present invention of 50g / L, configure the mother liquor of 40g / L alkali, and the hydrosulfite of 50g / L 2.

[0029] Dilute the two mother liquors by 5 times and 10 times respectively, and measure and observe the reduction potential value changes of the mother liquor and the diluent. After the mother liquor is prepared, measure its reduction potential value, measure the reduction potential value after 15 minutes after diluting the mother liquor by 5 times, dilute the mother liquor by 10 times after 5 hours, and measure the potential value after wait...

Embodiment 2

[0034] 20g / L, 25g / L, 30g / L, 40g / L, 50g / L composite reducing agents will be prepared respectively, and under different alkalinity, the preparation solution will be measured at room temperature after 1 hour and 20 hours. Reductive changes. See Table 2 for details.

[0035] Table 2 The measured value of the solution placed for 1 hour

[0036]

[0037] Table 3 Measured value after placing the solution for 20 hours

[0038]

[0039]

[0040]According to the data, the composite reducing agent of the present invention is very stable in the high-concentration region, and the potential fluctuation is small. When the combined alkali concentration is above 30g / L and the composite reducing agent is above 20g / L, the leucosome sodium salt state can be stably formed. The composite reducing agent with the same concentration of the present invention has little change in its reducing potential value after standing still for 1 hour and after standing still for 20 hours under the same...

Embodiment 3

[0042] In this embodiment, cotton loose fibers for color spinning are used, and the composite reducing agent of the present invention is used to carry out dyeing by exhaust dyeing process. The specific process is as follows:

[0043] Configure high-concentration leucochrome sodium salt dye solution, the specific steps are as follows: first add 50wt% water in the container, turn on the agitator, heat up to 30-60°C and pour in caustic soda; pour in the dye while heating up and stirring , fully stirred for 20-30min; add water to cool down to 50°C, add composite reducing agent, stir for 45min, add cold water to 100wt% liquid volume for later use. At this time, the leucosome sodium salt staining solution is in a microcolloid state. The specific ingredients are shown in Table 4 and Table 5:

[0044] Table 4 Composition list

[0045] 3GL yellow FB red caustic soda Compound reducing agent Concentration(g / L) 5 60 50 40

[0046] Table 5 The ratio of co...

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Abstract

The invention discloses a dyeing method for leuco body pad dyeing. The dyeing method includes the following steps of padding, oxidizing and washing, wherein the padding technology includes of paddingin a dye vat with a penetrating agent and padding in a dye vat with leuco body sodium salt dye liquor, the leuco body sodium salt dye liquor is prepared from a composite reducing agent and dye, and the composite reducing agent includes one or more of thiourea dioxide, reducing sugar, a chemical potential control agent, sodium nitrite, acrylamide, furfural, cyclohexanone and trichloroacetic acid. By the adoption of the composite reducing agent, a leuco body reducing method is applied and implemented in pad dyeing, and an obtained dyed product is deep in color and high in fastness.

Description

technical field [0001] The invention relates to the field of dyeing, in particular to a leuco-padding dyeing method. Background technique [0002] Dyeing methods are generally divided into disperse dyeing, acid dyeing, reactive dyeing and other dyeing methods according to different dyes. The above dyeing methods mostly have the following problems: (1) Polyester is dyed with disperse dyes, and the light fastness is poor; after dyeing, reduction cleaning is required, and the color fastness of deep and thick colors is poor, and fades and grays after washing; When dyeing dyes, most of them need to use high-temperature process, and the cost of energy consumption is relatively high; disperse dyes are also prone to heat condensation, which is easy to cause defects such as color flowers and stains; There is a problem that it cannot meet the needs of consumers; reactive dyes dyed nylon has poor levelness, and high-temperature dyeing can easily cause the fabric to feel hard and even ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06P1/22D06P1/649D06P1/651D06P1/673D06P3/60
CPCD06P1/22D06P1/6491D06P1/6495D06P1/65112D06P1/65131D06P1/6735D06P3/6025
Inventor 李瑞卿周长文王伟
Owner 李瑞卿
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