Diquat wastewater treatment method
A technology for wastewater treatment and diquat, which is used in extraction water/sewage treatment, water/sludge/sewage treatment, chemical instruments and methods, etc. It can solve the problem of large fluctuations in effluent quality, high-concentration wastewater discharge, and trouble for producers. and other problems, to achieve effective and efficient treatment methods, save production costs, and reduce pressure.
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Embodiment 1
[0025] A method for treating diquat wastewater, comprising the following steps:
[0026] (1) Pour 1600L of waste water into the reactor and adjust the pH value to 10;
[0027] (2) Add 800L of extractant;
[0028] (3) start stirring, and the reaction time is 60 minutes;
[0029] (4) stop reaction, oil and water are separated;
[0030] (5) the separated extractant continues to repeat the extraction 4 times to saturation;
[0031] (6) Mix the saturated extractant with dilute sulfuric acid at a ratio of 1 to 1 by volume, stop layering after stirring the reaction, separate the oil phase and continue to use it as the extractant, and the acid solution contains a large amount of bipyridyl, which can be used again Production.
Embodiment 2
[0033] A method for treating diquat wastewater, comprising the following steps:
[0034] (1) Pour 1600L of waste water into the reactor and adjust the pH value to 10.5;
[0035] (2) Add 800L of extractant;
[0036] (3) start stirring, and the reaction time is 55 minutes;
[0037] (4) stop reaction, oil and water are separated;
[0038] (5) the separated extractant continues to repeat the extraction 5 times to saturation;
[0039] (6) Mix the saturated extractant with dilute hydrochloric acid at a ratio of 1 to 1 by volume, stop layering after stirring the reaction, separate the oil phase and continue to use it as the extractant, and the acid solution contains a large amount of bipyridine, which can be used again Production.
Embodiment 3
[0041] As a comparative example, 1600L of waste water was treated with powdered activated carbon by traditional method, and the dosing ratio was 2 / 1000.
[0042] By comparing the average effect of embodiments 1 and 2 with embodiment 3, as shown in table 1:
[0043] Table 1 Comparison of the effects of the two methods
[0044] Influent concentration (mg / L) Effluent concentration (mg / L) Removal rate Activated carbon treatment 1335 170.38 87.24% Extraction treatment 1335 54.89 95.89%
[0045] Cost comparison of the two methods:
[0046] Activated carbon treatment, the dosing ratio is 2 / 1000, that is, the dosage of 1 ton of wastewater is 2KG, and the amount of wastewater treated in a year is about 15,000 tons, that is, the consumption of activated carbon is about 30 tons, and the purchase cost is 270,000 yuan. Hazardous waste treatment The cost is 240,000 yuan, and the total is 510,000 yuan.
[0047] Extraction treatment, after the extractant ...
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