Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Thermoplastic vulcanized rubber nano composite material and preparation method thereof

A nanocomposite material, thermoplastic vulcanization technology, applied in the direction of nanotechnology, nanotechnology, nanotechnology for materials and surface science, etc., can solve the problems of product performance impact, polyamide failure to enter the interlayer in time, etc.

Active Publication Date: 2019-09-13
INST OF CHEM CHINESE ACAD OF SCI
View PDF4 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The preparation method is simple and the production cost is low, but this method is to add montmorillonite mud after polyamide melting, which will cause the montmorillonite mud to be completely mixed with the copolymer in the future, and the water between the layers will be gasified due to high temperature. As a result, the polyamide failed to enter the interlayer in time. At the same time, the energy generated only by water vaporization was not enough to completely peel off the montmorillonite layer, so a completely peeled composite material could not be obtained, and its product performance was greatly affected. influences

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Thermoplastic vulcanized rubber nano composite material and preparation method thereof
  • Thermoplastic vulcanized rubber nano composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0101] In this embodiment, the thermoplastic vulcanizate is acrylic rubber / PET, wherein the rubber-to-plastic ratio is 70 / 30, the mass ratio of nanomaterials to thermoplastic vulcanizate is 2:100, the liquid medium used is water, and the auxiliary agent used is poly Sorbitate, the nano material that adopts is layered nano montmorillonite, the antiaging agent that adopts is tris (2,4-di-tert-butylphenyl) phosphite, prepares nano composite material according to the following method:

[0102] (1) Stir the liquid medium, and at the same time add nanomaterials at a speed of 5.5g / min for continuous stirring and disperse evenly, and the weight ratio of liquid medium to nanomaterials is 11:1;

[0103] (2) Add additives to the continuous stirring solution of step (1) in batches or at a time at a speed of 0.1g / min to obtain a paste, the consistency of which is 95mm, the additives and nanomaterials The weight ratio is 2:1;

[0104] (3) mixing the paste obtained in step (2) with thermopl...

Embodiment 2

[0109] In this embodiment, the thermoplastic vulcanizate is acrylic rubber / PET, wherein the rubber-to-plastic ratio is 20 / 80, the mass ratio of nanomaterials to thermoplastic vulcanizate is 10:100, and the liquid medium used is propionitrile and water, propionitrile The mass ratio to water is 1:6, the additives used are casein, tragacanth gum and safflower gum, the weight ratio is 1:2, the nanomaterial used is kaolin, and the anti-aging agent used is antioxidant 1035 , prepare nanocomposites according to the following method:

[0110] (1) Stir the liquid, and at the same time add nanomaterials at a speed of 20g / min for continuous stirring to disperse evenly, and the weight ratio of the liquid medium to the nanomaterials is 100:1;

[0111] (2) Add additives to the continuous stirring solution of step (1) at a speed of 5g / min to obtain a paste, the consistency of the paste is 32mm, and the weight ratio of the additives to nanomaterials is 10 :1;

[0112] (3) mixing the paste o...

Embodiment 3

[0117] In this embodiment, the thermoplastic vulcanizate is acrylic rubber / PET, wherein the rubber-to-plastic ratio is 50 / 50, the mass ratio of nanomaterials to thermoplastic vulcanizate is 0.1:100, the liquid medium used is water, and the auxiliary agent used is rosin Amine-ethylene oxide polycondensate, the nanomaterials used are Co / Mg-LDHs and nano-montmorillonite, the mass ratio is 1:4, and the nanocomposite material is prepared according to the following method:

[0118] (1) Stir the liquid medium, and at the same time add nanomaterials at a speed of 0.01g / min for continuous stirring to disperse evenly, and the weight ratio of liquid medium to nanomaterials is 0.1:1;

[0119] (2) Add additives to the continuous stirring solution of step (1) at a speed of 13g / min to obtain a paste, the consistency of the paste is 46mm, and the weight ratio of the additives to nanomaterials is 65 :1;

[0120] (3) mixing the paste obtained in step (2) with thermoplastic vulcanizate to obtai...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Consistencyaaaaaaaaaa
Tensile strengthaaaaaaaaaa
Tensile strengthaaaaaaaaaa
Login to View More

Abstract

The invention relates to the field of nano composite materials and in particular to a thermoplastic vulcanized rubber nano composite material and a preparation method thereof. The nano composite material is prepared from a premix through melting and commixing, wherein the premix is prepared from a nano material which is combined with a liquid medium and is fed into and adhered to thermoplastic vulcanized rubber granules; and the thermoplastic vulcanized rubber granules comprise nonpolar granules and polar granules. The preparation method comprises the following steps: mixing the liquid mediumwith the nano material so as to obtain an ointment, pasting the ointment to surfaces of the thermoplastic vulcanized rubber granules, and carrying out melting and commixing, so as to obtain the nano composite material. The nano composite material provided by the invention has excellent toughness, and in addition is short in process, low in cost and applicable to popularization and application.

Description

technical field [0001] The invention relates to the field of nanocomposite materials, in particular to a thermoplastic vulcanized rubber nanocomposite material and a preparation method thereof. Background technique [0002] In the existing technology, nanomaterials and polymers are often mixed and extruded to form composite materials. Although the tensile strength of such composite materials has been improved, due to problems such as poor compatibility between nanomaterials and polymers, this type of material The impact resistance performance is generally not high. [0003] In order to solve the above problems, methods such as intercalation in-situ polymerization are often used to make the polymer react between the layers of nanomaterials to improve the impact resistance of the composite material. However, this process takes a long time, the polymerization reaction conditions are harsh, and the solvent is not easy. Recycling will bring derivative problems such as environmen...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C08L33/00C08L67/02C08K3/34C08L89/00C08L5/00C08L71/02C08K3/22C08L9/02C08L77/00C08L29/04C08K3/24C08K5/41C08L55/02C08L1/02C08K5/098C08L33/26C08K3/04C08L39/00C08K3/18C08L35/06C08L39/04C08K3/02C08J3/205B82Y30/00
CPCB82Y30/00C08J3/2053C08K2003/023C08K2201/011C08L9/02C08L33/00C08L55/02C08L67/02C08L2205/025C08L2205/03C08L2205/035C08K3/346C08L89/005C08L5/00C08L71/02C08K3/22C08L77/00C08L29/04C08K3/24C08K5/41C08L1/02C08K5/098C08L33/26C08K3/042C08L39/00C08K3/18C08L35/06C08L39/04C08K3/041C08K3/02
Inventor 马永梅张京楠郑鲲曹新宇尚欣欣叶钢
Owner INST OF CHEM CHINESE ACAD OF SCI
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com