Inorganic-organic hybrid materials with high water stability and blue-green emission and photoelectric response properties
A technology of photoelectric response and organic hybridization, which is applied in the direction of luminescent materials, organic chemistry, and compounds of group 5/15 elements of the periodic table. It can solve problems such as unfavorable practical applications, easy collapse, and performance impact, and achieve good water stability. properties, short reaction time, and high yield
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[0022] In order to make the content of the present invention easier to understand, the technical solutions of the present invention will be further described below in conjunction with specific embodiments, but the present invention is not limited thereto.
[0023] An inorganic-organic functional hybrid material with high water stability and blue-green light emission and photoelectric response performance, its molecular formula is C 38 h 34 P 2 Ag 2 Br 4 , whose structure is characterized by the inclusion of an organic quaternary phosphorus salt (1,2-DBTPP) 2+ and an inorganic silver bromide anion (Ag 2 Br 4 ) 2- , its silver center is planar triangular coordination, two AgBr 3 Plane triangles are formed by sharing edges (Ag 2 Br 4 ) 2- , organic quaternary phosphorus salts and inorganic (Ag 2 Br 4 ) 2- held together by electrostatic interaction.
[0024] Its synthetic method comprises the following steps:
[0025] Dissolve 1,2-DBTPP·2Br (0.0710g, 0.1mmol) and Ag...
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