Screening method for petroleum coke used for industrial silicon, carbonaceous reducing agent and smelting method for industrial silicon
A screening method, petroleum coke technology, applied in the smelting of industrial silicon, the screening of petroleum coke for industrial silicon, and the field of carbonaceous reducing agents, can solve the problems that have not been seen before, and the reactivity of petroleum coke needs to be improved, so as to improve efficiency, The effect of protecting forest resources and ecological environment and reducing production costs
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[0057] According to another preferred embodiment of the present invention, based on the weight of the carbonaceous reducing agent, the content of bituminous coal and / or anthracite is 30-70% by weight, the content of petroleum coke is 30-70% by weight, and the content of charcoal is 0% by weight;
[0058] Among them, petroleum coke meets the following conditions at the same time:
[0059] (1) The volatile matter content is 14-18% by weight,
[0060] (2) The Hash Grindability Index of the cake is 30-60.
[0061] In this preferred embodiment, further preferably, the petroleum coke also satisfies: the content of fixed carbon on a dry basis is 88-92% by weight;
[0062] Further preferably, the petroleum coke also satisfies: the sulfur content is 0-2% by weight.
[0063] Further preferably, the petroleum coke also meets the requirement that the ash content is 0-0.2% by weight.
[0064] Further preferably, the petroleum coke also satisfies that the content of Fe is 0-60ppm.
[0...
Embodiment
[0075] The present invention will be described in detail through examples below, but the present invention is not limited thereby. In the following examples, unless otherwise specified, all materials used are commercially available, and all methods used are conventional methods in the art.
[0076] Among them, the bituminous coal comes from Ningxia region, with a volatile content of 25% by weight and an ash content of 7.5% by weight.
[0077] The determination method of the volatile content in bituminous coal is: GB-T 212-2008 coal industrial analysis method.
[0078] The determination method of ash content in bituminous coal is: GB-T 212-2008 coal industrial analysis method.
[0079] The determination method of volatile matter content in petroleum coke is: SH / T0026-1990 determination method of volatile matter in petroleum coke.
[0080] The method of sintering treatment of petroleum coke includes: the sintering treatment process and conditions of petroleum coke in SH / T 0026...
Embodiment 1
[0096] Mix the silica and the carbonaceous reducing agent uniformly, the carbonaceous reducing agent includes bituminous coal and petroleum coke A, wherein, based on the weight of the carbonaceous reducing agent, the content of bituminous coal is 30% by weight, and the content of petroleum coke A is 70% by weight , the weight ratio of silica and carbonaceous reducing agent is 1:1.15, and the mixture is put into submerged arc furnace for smelting heat treatment.
[0097] During the smelting process, there were no undesired phenomena such as rising of the furnace bottom, stinging fire, and death of the material surface. The furnace is in good condition during the smelting process: it can be observed that the electrode is deeply and stably buried in the charge, the sinking speed of the charge surface is fast, the gas emerges evenly through the upper part of the furnace, the current load is stable, the silicon is produced smoothly, and the silicon production rate reaches 30.5%. , ...
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