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A kind of separator comprising graphene/cellulose composite material and preparation method thereof

A composite material and composite material layer technology, applied in the field of separators containing graphene/cellulose composite materials and their preparation, can solve the problem of limiting the service life of lithium-ion batteries, energy density and theoretical capacity, lithium-ion battery energy density and actual capacity. low, threatening personal safety and other problems, to achieve the effect of increasing charge-discharge cycle performance, high liquid absorption, and increasing safety performance

Active Publication Date: 2020-10-30
BEIJING NORMAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the separators commonly used in lithium-ion batteries are multi-layer structures or ceramic-coated separators; they can play a good role in blocking positive and negative materials and supports, and when the separator is punctured, local heating will occur. If the diaphragm barrier layer can quickly melt and close the cells, it can prevent the battery from exploding due to heat, but when the local heating rate is greater than the melting rate, the blocking effect cannot be achieved.
Moreover, after long-term use, metal lithium will crystallize on the negative electrode to form dendritic metal lithium—dendrites; when the dendrites grow to a certain extent, they will puncture the diaphragm, causing an internal short circuit in the battery, which seriously threatens personal safety. This severely limits the extension of the service life, energy density and theoretical capacity of Li-ion batteries
[0004] Not only that, the energy density and actual capacity of lithium-ion batteries prepared by the current technology are relatively low, which can no longer meet people's needs; the main reason is that the performance of the separator directly affects the internal resistance of the battery, discharge capacity, The cycle life and the safety performance of the battery, therefore, the manufacture of lithium-ion batteries has extremely high requirements for the consistency of the separator material products. In addition to the basic requirements of thickness, surface density, and mechanical properties, the size and distribution of the separator micropores Uniformity also has high requirements

Method used

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  • A kind of separator comprising graphene/cellulose composite material and preparation method thereof
  • A kind of separator comprising graphene/cellulose composite material and preparation method thereof
  • A kind of separator comprising graphene/cellulose composite material and preparation method thereof

Examples

Experimental program
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preparation example Construction

[0052] Preparation of the positive electrode sheet: 85 parts of the positive active material lithium cobaltate, 5 parts of acetylene black, 5 parts of conductive graphite, and 5 parts of PVDF are fully mixed with N-methylpyrrolidone to obtain the positive electrode slurry, which is evenly coated on the surface of the aluminum foil current collector to complete Positive sheet preparation.

[0053] Preparation of negative electrode sheet: 87 parts of conductive graphite, 5 parts of acetylene black, 5 parts of hydroxymethylcellulose sodium binder, and 3 parts of styrene-butadiene rubber binder are fully mixed with ethanol-water mixed solution to obtain negative electrode slurry Material, evenly coated on the surface of the copper foil current collector, to complete the preparation of the negative electrode sheet.

Embodiment 1

[0055] Step 1) fully mix natural flake graphite 60g and methyl cellulose 100g, and ball mill 15h at room temperature to obtain composite graphene cellulose material powder;

[0056] Step 2) Sodium dodecylbenzene sulfonate 25g is dissolved in 460mL water, then the graphene cellulose material 160g obtained in step (1) is dissolved in the above water, fully stirred, and the graphene cellulose mixed slurry is obtained;

[0057] Step 3) applying the mixed slurry scraper of step 2) to one side of the polypropylene diaphragm base layer;

[0058] Step 4) Dry the diaphragm base layer coated with the mixed slurry in step 3) in a vacuum oven at 40° C. for 2 hours to prepare the diaphragm comprising graphene / cellulose composite material; the graphene / cellulose The thickness of the composite coating is 2 μm.

[0059] Step 5) the lithium-ion battery is assembled:

[0060] Put the graphene / cellulose composite diaphragm obtained in step 4) between the positive electrode and the negative ele...

Embodiment 2

[0063] Repeat embodiment 1, difference is:

[0064] Step 1) fully mix natural flake graphite 30g and ethyl cellulose 100g, and ball mill 5h at room temperature to obtain composite graphene cellulose material powder;

[0065] Step 2) dissolving 15g of methyl amyl alcohol in 1500mL water, then dissolving 145g of the graphene cellulose material obtained in step (1) in the above-mentioned water, fully stirring to obtain a graphene / cellulose composite slurry;

[0066] In step 4), the thickness of the graphene / cellulose composite coating is 8 μm.

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Abstract

The invention discloses a diaphragm containing a graphene / cellulose composite material, and a preparation method thereof. The diaphragm comprises a diaphragm base layer, a graphene / cellulose compositematerial layer on the surface, facing a positive electrode, of the diaphragm base layer, and another graphene / cellulose composite material layer on the surface, facing a negative electrode, of the diaphragm base layer, wherein the graphene / cellulose composite material layers comprise graphene, cellulose and other auxiliary agents. In use, the diaphragm containing the graphene / cellulose compositematerial has the characteristics of low thickness, high imbibition rate and low resistance, and enables a lithium ion battery to have high capacity and long service life; and the graphene component ofthe diaphragm can effectively form a heat transmission network and diffuse heat in time when the phenomenon of local overheating occurs, so the heat resistance of the diaphragm is improved, and the safety performance of the battery is improved. The preparation method for the diaphragm is simple in process, mild in reaction conditions, short in production cycle, and capable of realizing large-scale industrial production.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and in particular relates to a diaphragm containing graphene / cellulose composite material and a preparation method thereof. Background technique [0002] Lithium-ion batteries generally use materials containing lithium elements as electrodes, which are representatives of modern high-performance batteries. It is favored by researchers for its small size, light weight, high working voltage, high specific energy, long cycle life, and no pollution. It can be widely used in various fields of aerospace, electronic devices and daily life. Lithium-ion batteries currently in use are generally composed of positive and negative electrodes, electrolytes and separators. The separator is one of the key inner components of the lithium-ion battery, which mainly relies on the movement of lithium ions between the positive and negative electrodes to work. During the charging and discharging process...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M2/14H01M2/16H01M10/0525
CPCH01M10/0525H01M50/403H01M50/409H01M50/411H01M50/44H01M50/449Y02E60/10
Inventor 周建军胡志宇李林方芳
Owner BEIJING NORMAL UNIVERSITY
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