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Preparation method of triptycene polymer (DTP)/cadmium zinc sulfide (Cd0.5Zn0.5S) composite photocatalyst

A technology of zinc cadmium sulfide and tripterene, applied in organic compound/hydride/coordination complex catalysts, physical/chemical process catalysts, chemical instruments and methods, etc., can solve the problem that the photocatalytic hydrogen production activity has not been thoroughly studied, etc. problem, to achieve the effect of easy control of preparation conditions, simple preparation method and high catalytic efficiency

Active Publication Date: 2018-11-30
CHANGZHOU UNIV
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Problems solved by technology

[0004] Literature survey found that DTP-Cd 0.5 Zn 0.5 The photocatalytic hydrogen production activity of S nanocomposites has not been thoroughly investigated

Method used

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  • Preparation method of triptycene polymer (DTP)/cadmium zinc sulfide (Cd0.5Zn0.5S) composite photocatalyst
  • Preparation method of triptycene polymer (DTP)/cadmium zinc sulfide (Cd0.5Zn0.5S) composite photocatalyst
  • Preparation method of triptycene polymer (DTP)/cadmium zinc sulfide (Cd0.5Zn0.5S) composite photocatalyst

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Embodiment 1

[0031] (1)Cd 0.5 Zn 0.5 Preparation of S

[0032] Na 2 S (1.5608g, 20mmol) was dissolved in 40mL deionized water, and Cd(OAc) was added 2 2H 2 O (2.305g, 10mmol) and Zn(OAc) 2 2H 2 O (1.8348g, 10mmol) in 40mL of aqueous solution was stirred at room temperature for 24h. Then, the product was filtered, washed several times with deionized water, and dried in an oven at 80 °C for 5 h.

[0033] (2) Preparation of DTP

[0034] a: Place triptene (1.25g, 5mmol) in a three-necked flask, add concentrated HNO 3 50 mL, the mixture was heated and stirred at 75° C. for 24 h, and condensed under reflux. The reaction solution was a brown solution, which was cooled to room temperature, then poured into H 2 O (1000 mL) was stirred for 30 min. The precipitate was collected, washed with distilled water, and dried in air. The crude product was purified with dichloromethane / petroleum ether (1:1) as the eluent to give the white solid products 2,6,14-trinitrotriptene (2a) and 2,7,14-trin...

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Abstract

The invention relates to preparation of a triptycene polymer (DTP) / cadmium zinc sulfide (Cd0.5Zn0.5S) composite photocatalyst. The preparation comprises the following steps: preparation of a triptycene polymer (DTP), preparation of cadmium zinc sulfide (Cd0.5Zn0.5S) and preparation of the triptycene polymer (DTP)-doped cadmium zinc sulfide (DTP@Cd0.5Zn0.5S) composite photocatalyst. The preparationdisclosed by the invention has the beneficial effects that the preparation method is simple, the preparation conditions are easy to control, and the prepared triptycene polymer (DTP)-doped cadmium zinc sulfide (Cd0.5Zn0.5S) composite catalyst has the advantages of no secondary pollution and high photocatalytic efficiency, and has certain application value.

Description

technical field [0001] The invention belongs to the technical field of preparation and application of nanomaterials, and relates to a method for preparing tripterene polymer DTP / zinc cadmium sulfide Cd 0.5 Zn 0.5 The preparation method of the S composite photocatalyst also belongs to the field of organic chemical synthesis. Background technique [0002] The production of hydrogen from water by visible light irradiation by using semiconductor materials under sunlight irradiation provides us with a promising method of harnessing solar energy, which has gradually attracted the attention of scientists. Designing and preparing photocatalysts driven by visible light with high activity and good stability, so that they can fully absorb sunlight, has become an important research topic. where Cd 1-x Zn x Binary metal sulfides such as S have the ability to change the ratio of Cd / Zn, thereby changing the band gap of the binary metal sulfide, making it more compatible with the band g...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J31/26C01B3/04
CPCC01B3/042B01J31/26C01B2203/1041C01B2203/0277B01J35/39Y02E60/36
Inventor 梁倩崔赛楠李忠玉
Owner CHANGZHOU UNIV
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