Ester-based compound, composition containing same, method for preparing same, and resin composition containing same
一种树脂组合物、化合物的技术,应用在有机化学等方向,能够解决使用限制、相容性差、没有太多进展等问题,达到优异耐迁移性和耐挥发性、优异耐应力性、优异拉伸强度和伸长率的效果
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preparation Embodiment 1
[0042] Preparation Example 1: Preparation of Diisononyl Terephthalate
[0043] Into a 4-neck 3-liter reactor equipped with cooler, water stripping unit, condenser, decanter, reflux pump, temperature controller, stirrer, etc., 498.4 g of purified terephthalic acid (PIA), 1172.1 g Isononanol (KH Neochem) (the molar ratio of terephthalic acid:isononanol is 1:3) and 1.54 g of a titanium-based catalyst (TIPT, tetraisopropyl titanate) as a catalyst (based on 100 parts by weight The terephthalic acid is 0.3 parts by weight), and the temperature is slowly raised to about 170°C. Water began to be generated around 170°C, and the ester reaction was carried out at a reaction temperature of about 220°C under atmospheric pressure for about 4.5 hours while continuously feeding nitrogen, and when the acid value reached 0.01, the reaction was stopped.
[0044] After stopping the reaction, extractive distillation under reduced pressure was carried out for 0.5 hours to 4 hours to remove unreact...
Embodiment 1
[0046] In the reactor that is provided with stirrer, condenser and decanter, add 2000g diisononyl terephthalate and 340g n-butanol (based on 100 parts by weight DINIP being 17 weight parts) obtained in Preparation Example 1 parts), and then the resultant was subjected to a transesterification reaction at a reaction temperature of 160° C. for 2 hours under a nitrogen atmosphere, thereby preparing An ester-based plasticizer composition of butyl isononyl ester (BINTP) and 61.0% by weight diisononyl terephthalate (DINTP).
[0047] The reaction product was mixed distillation to remove butanol and 2-ethylhexanol and prepare the final ester-based plasticizer composition.
Embodiment 2
[0049] In addition to using 2000 g of diisononyl terephthalate and 340 g of isobutanol to finally prepare 5.0 wt % of diisobutyl terephthalate, 37.0 wt % of Except for the ester-based plasticizer composition of diisononyl terephthalate, the transesterification reaction was performed in the same manner as in Example 1.
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