A kind of water-repellent wrapping paper based on nano plant fiber and preparation method thereof
A plant fiber and nano-cellulose technology, applied in packaging paper, wrapping paper, using microbial/enzymatic cellulose treatment, etc., can solve the problems of plant fiber paper water repellency and rareness, and achieve a small size range and a preparation method Simple, Manipulable Effects
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Embodiment 1
[0026] (1) The rice straw was dried in the sun, beaten thoroughly, immersed in 20g / L sodium hydroxide solution, heated and boiled for activation for 20 minutes, adjusted to neutral pH, and taken out to obtain pretreated rice straw.
[0027] (2) Place the pretreated rice straw in a biological enzyme solution containing 1% cellulase and 2% xylanase, stir it ultrasonically for 10 min at a power of 100W, and add acetic acid and molybdenum at a volume ratio of 3:1 Acid and inorganic acid mixed solution, continue to ultrasonically stir for 10min under 100W power, take it out, filter it with an ultrafiltration membrane with a pore size of 100nm, wash with water, and obtain nano-plant fibers, according to the material ratio of nano-plant fibers and hydrogen peroxide solution is 0.1g : 3ml, add dropwise hydrogen peroxide solution, and bleach at 40°C for 30min to obtain a solution containing nano-plant fibers.
[0028] (3) Add fillers, cationic starch, bentonite and sticky chemicals to ...
Embodiment 2
[0030] (1) Dry the rice straw, beat it fully, dip it in 30g / L sodium hydroxide solution, heat and boil to activate for 30min, adjust the pH value to neutral, take it out, and obtain the pretreated rice straw.
[0031] (2) Place the pretreated rice straw in a bio-enzyme solution containing 2% cellulase and 3% xylanase, stir it ultrasonically for 20min at a power of 150W, and add dropwise acetic acid and molybdenum at a volume ratio of 4:1 Acid and inorganic acid mixed solution, continue to ultrasonically stir for 20min under 150W power, take out, filter with an ultrafiltration membrane with a pore size of 100nm, and wash with water to obtain nano-plant fibers, according to the material ratio of nano-plant fibers and hydrogen peroxide solution is 0.1g : 5ml, hydrogen peroxide solution was added dropwise, and bleached at 60°C for 30min to obtain a solution containing nano-plant fibers.
[0032] (3) Add fillers, cationic starch, bentonite and sticky chemicals to the solution conta...
Embodiment 3
[0034] (1) The rice straw was dried in the sun, beaten thoroughly, immersed in 25g / L sodium hydroxide solution, heated and boiled for activation for 25 minutes, adjusted to neutral pH, and taken out to obtain pretreated rice straw.
[0035] (2) Place the pretreated rice straw in a bio-enzyme solution containing 1.5% cellulase and 2.5% xylanase, ultrasonically stir for 15 minutes at a power of 110W, and add dropwise acetic acid and molybdenum at a volume ratio of 3.5:1 Acid and inorganic acid mixed solution, continue to ultrasonically stir for 15min under 130W power, take out, filter with an ultrafiltration membrane with a pore size of 100nm, and wash with water to obtain nano-plant fibers, according to the material ratio of nano-plant fibers and hydrogen peroxide solution is 0.1g : 4ml, hydrogen peroxide solution was added dropwise, and bleached at 50°C for 30min to obtain a solution containing nano-plant fibers.
[0036] (3) Add fillers, cationic starch, bentonite and sticky ...
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