Water foaming inorganic hybrid melamine polyurethane rigid foam material and manufacturing method thereof

A hybrid melamine polyurethane and hybrid melamine technology are applied in the field of water-foaming polyurethane rigid foam materials and their manufacturing fields, which can solve the problems of high system viscosity, high thermal conductivity, poor fluidity and the like, and achieve improved high temperature resistance and flame retardancy. The effect of improved performance and excellent flame retardant performance

Active Publication Date: 2018-04-17
CHANGZHOU JUMBO ENERGY SAVING TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, ordinary all-water foamed rigid polyurethane foam has many shortcomings, such as too high viscosity, poor fluidity, uneven foaming, resulting in coarse cells, large thermal conductivity, and brittle foam, etc.

Method used

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  • Water foaming inorganic hybrid melamine polyurethane rigid foam material and manufacturing method thereof
  • Water foaming inorganic hybrid melamine polyurethane rigid foam material and manufacturing method thereof
  • Water foaming inorganic hybrid melamine polyurethane rigid foam material and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] Water-foamed inorganic hybrid melamine polyurethane rigid foam material, which is a rigid foam material formed by foaming inorganic hybrid melamine polyurethane combined polyether and polymerized isocyanate. Inorganic hybrid melamine polyurethane combined polyether, in parts by weight ratio, The formula is as follows:

[0046]

[0047] The emulsifier is hard foam silicone oil.

[0048] The composite catalyst is potassium acetate and pentamethyldiethylenetriamine.

[0049] The flame retardant is phosphate, and the phosphate is tris(1-chloro-2-propyl) phosphate, and the viscosity of the phosphate is 290 Pa·s.

[0050] The inorganic hybrid melamine resin polyol is specifically boron hybrid melamine resin propylene glycol, and its molecular structure and preparation method are as follows:

[0051]

[0052] Raw material ratio:

[0053]

[0054]

[0055] (1) Etherification reaction

[0056] Add hexamethylol melamine and methanol into the reaction kettle according to the above ratio, add...

Embodiment 2

[0073] Water-foamed inorganic hybrid melamine polyurethane rigid foam material, which is a rigid foam material formed by foaming inorganic hybrid melamine polyurethane combined polyether and polymeric isocyanate, and is characterized by:

[0074] Water-foamed inorganic hybrid melamine polyurethane rigid foam material, which is a rigid foam material formed by foaming inorganic hybrid melamine polyurethane combined polyether and polymeric isocyanate, and is characterized by:

[0075] The inorganic hybrid melamine polyurethane combined polyether has the following formula in parts by weight ratio:

[0076]

[0077] The emulsifier is hard foam silicone oil.

[0078] The composite catalyst is pentamethyldiethylenetriamine, 1,3,5-tris(dimethylaminopropyl)hexahydrotriazine, trimethyl-N-2 hydroxypropyl hexanoic acid and dilauric acid. Butyl tin.

[0079] The flame retardant is phosphate, and the phosphate is tris(2,3-dichloropropyl) phosphate, and the viscosity of the phosphate is 285 Pa·s.

[0...

Embodiment 3

[0103] Water-foamed inorganic hybrid melamine polyurethane rigid foam material, which is a rigid foam material formed by foaming inorganic hybrid melamine polyurethane combined polyether and polymeric isocyanate, and is characterized by:

[0104] Water-foamed inorganic hybrid melamine polyurethane rigid foam material, which is a rigid foam material formed by foaming inorganic hybrid melamine polyurethane combined polyether and polymeric isocyanate, and is characterized by:

[0105] The inorganic hybrid melamine polyurethane combined polyether has the following formula in parts by weight ratio:

[0106]

[0107] The emulsifier is hard foam silicone oil.

[0108] The composite catalyst is 1,3,5-tris(dimethylaminopropyl)hexahydrotriazine, triethylenediamine and N,N-dimethylaniline.

[0109] The flame retardant is phosphate, and the phosphate is tris(1-chloro-2-propyl) phosphate and tris(2,3-dichloropropyl) phosphate, and the viscosity of the phosphate is 269 Pa·s.

[0110] The inorganic hyb...

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Abstract

A water-blown rigid inorganic hybrid melamine polyurethane foam material and a preparation method therefor, relating to the technical field of production of flame-retardant polyurethane energy-saving materials and building energy conservation. An environmentally-friendly all-water-blown rigid inorganic hybrid melamine polyurethane foam material with B1-grade flame retardation performance according to the present invention is prepared with high-temperature-resistant inorganic hybrid melamine resin polyol or an inorganic hybrid polyol etherified melamine resin, an emulgator, a composite catalyst, a phosphate flame retardant, and a foamer, water or water glass for example, as main raw materials, and by carrying out dispersion by stirring, separately preparing premixed polyether, and then subjecting the premixed polyether to foaming on a sheet making machine, a coating machine, and a casting machine with isocyanate (MDI). The rigid foaming material according to the present invention is free of lower-boiling-point hydrocarbon compound chlorofluorocarbon and hydrochloroflurocarbon compounds, undergoes foaming in virtue of water, and does not destroy the ozone layer nor produce the greenhouse effect, so that the material is environmentally friendly; the flame-retardant property is improved by at least 20%; the material has excellent flame-retardant property while guaranteeing physical properties and has an oxygen index of more than 30%.

Description

Technical field [0001] The invention belongs to the technical field of flame-retardant polyurethane energy-saving material production and building energy-saving technology, and particularly relates to a water-foamed polyurethane rigid foam material and a manufacturing method thereof. Background technique [0002] my country is a big country with complex climatic characteristics, such as the severely cold northeast region and the middle reaches of the Yangtze River with hot summers and cold winters. This makes the energy consumption of building materials in my country very large. The energy consumption of winter warmth in the northern region accounts for 27.3% of the country's total energy consumption. However, due to the problems of materials, technology and craftsmanship, the heating energy per unit area of ​​traditional buildings in my country is 2-3 times that of developed countries with similar climate conditions in the world. The "Medium and Long-term Special Plan for Energ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G18/32C08K5/521C08J9/08C08G101/00
CPCC08G18/3897C08J9/08C08J2203/02C08J2375/12C08K5/521C08G2110/0025C08G2110/0083C08G18/32
Inventor 王洪波李强
Owner CHANGZHOU JUMBO ENERGY SAVING TECH CO LTD
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