Self emission type photosensitive resin composition, color filter manufactured using thereof and image display device having the same
A photosensitive resin and self-illuminating technology, applied in optics, instruments, optical filters, etc., can solve the problems of reduced light efficiency and poor photosensitive characteristics, and achieve the effect of excellent brightness characteristics
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manufacture example 1
[0092] Production example 1. Synthesis of photoluminescent green quantum dot particle A with CdSe (core) / ZnS (shell) structure
[0093]CdO (0.4mmol), zinc acetate (4mmol), oleic acid (Oleic acid) (5.5mL) and 1-octadecene (1-Octadecene) (20mL) were added into the reactor together, heated It was made to react at 150 degreeC. Then, in order to remove acetic acid generated by substituting zinc for oleic acid, the reactant was left to stand under a vacuum of 100 mTorr for 20 minutes. Then, after applying heat at 310° C. to obtain a transparent mixture, which was maintained at 310° C. for 20 minutes, 0.4 mmol of Se powder and 2.3 mmol of S powder were dissolved in 3 mL of trioctylphosphine. The resulting Se and S solutions were quickly injected into the Cd(OA) 2 and Zn(OA) 2 solution in the reactor. After the mixture thus obtained was grown at 310° C. for 5 minutes, the growth was interrupted using an ice bath. Then, the quantum dots were precipitated with ethanol and separate...
manufacture example 2-1
[0094] Production Example 2-1. Synthesis of Alkali-Soluble Resin (D1)
[0095] Prepare a flask equipped with a stirrer, a thermometer reflux cooling tube, a dropping funnel, and a nitrogen introduction tube, and on the other hand, put 40 parts by weight of N-benzylmaleimide, 10 parts by weight of tricyclodecanyl methacrylate, and acrylic acid 50 parts by weight, 4 parts by weight of m-tert-butylperoxy-2-ethylhexanoate, 20 parts by weight of propylene glycol monomethyl ether acetate (hereinafter referred to as "PGMEA"), 20 parts by weight of propylene glycol monomethyl ether After the parts, stir and mix, prepare the monomer dropping funnel, add 6 weight parts of n-dodecane mercaptan, PGMEA24 weight parts and stir and mix, prepare the chain transfer agent dropping funnel.
[0096] Then, 395 parts by weight of PGMEA was introduced into the flask, and the atmosphere in the flask was replaced with nitrogen from air, and then the temperature of the flask was raised to 90° C. whil...
manufacture example 2-2
[0097] Production Example 2-2: Synthesis of Alkali-soluble Resin (D2)
[0098] Prepare a flask equipped with a stirrer, a thermometer reflux cooling tube, a dropping funnel, and a nitrogen introduction tube, and on the other hand, put 40 parts by weight of N-benzylmaleimide, 10 parts by weight of tricyclodecanyl methacrylate, and acrylic acid 50 parts by weight, 4 parts by weight of m-tert-butylperoxy-2-ethylhexanoate, 20 parts by weight of propylene glycol monomethyl ether acetate (hereinafter referred to as "PGMEA"), 20 parts by weight of propylene glycol monomethyl ether After the parts, stir and mix, prepare the monomer dropping funnel, add 6 weight parts of n-dodecane mercaptan, PGMEA24 weight parts and stir and mix, prepare the chain transfer agent dropping funnel.
[0099] Then, 395 parts by weight of PGMEA was introduced into the flask, and the atmosphere in the flask was replaced with nitrogen from air, and then the temperature of the flask was raised to 90° C. whil...
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