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Iridium complex, preparation method thereof and electroluminescent device applying iridium complex

A technology of iridium complexes and complexes, applied in the fields of electroluminescence devices and organic electroluminescence devices, can solve the problems of efficiency roll-off and efficiency reduction, and achieve the effects of convenient design and production, stable chemical properties and high luminous efficiency

Inactive Publication Date: 2016-07-20
AAC MICROTECH CHANGZHOU +1
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  • Abstract
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  • Claims
  • Application Information

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Problems solved by technology

In addition, in the current commonly used materials, the hole mobility of hole transport materials is much higher than that of electron transport materials, and the commonly used host materials are mainly hole transport, which will lead to a large number of redundant holes. Aggregation of holes at the interface between the light-emitting layer and the electron-transporting layer
These factors can lead to reduced efficiency and severe efficiency roll-off
Studies have shown that if the iridium complex has a high electron transport ability, it can effectively increase the transport and distribution of electrons in the light-emitting layer, broaden the electron-hole area, balance the number of electron-hole pairs, and greatly improve the device. efficiency, the reduced efficiency of the roll-off

Method used

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[0020] The present invention will be described in further detail below in conjunction with the accompanying drawings and embodiments. The terms used in the present invention, unless otherwise specified, generally have the meanings commonly understood by those skilled in the art.

[0021] The iridium complexes of the present invention have used iridium trichloride, 4,6-bistrifluoromethylpyridine-3-boronic acid, 4,6-bistrifluoromethylpyridine-4-boronic acid, 2- Bromopyridine derivatives, 2-bromopyrimidine derivatives, 2-bromopyrazine derivatives and 2-bromotriazine derivatives, etc., the synthesis method is similar. It contains two main ligands and a tetrakis (4-fluorophenyl)phosphonimide auxiliary ligand, the main ligand is 2-(4,6-bistrifluoromethylpyridinyl)pyridine, 2- (4,6-bistrifluoromethylpyridinyl)pyrimidine, 2-(4,6-bistrifluoromethylpyridinyl)pyrazine and 2-(4,6-bistrifluoromethylpyridinyl)yltriazine For any one of the derivatives, add the above mixed solution into the...

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Abstract

The invention relates to an iridium complex, a preparation method thereof and an electroluminescent device applying the iridium complex. The iridium complex with tetra(4-fluorophenyl)phosphine imide as an ancillary ligand is characterized in that main ligands in molecules of the series of iridium complex are any one of 2-(4,6-bis(trifluoromethyl)pyridine)yl pyridine, 2-(4,6-bis(trifluoromethyl)pyridine)yl pyrimidine, 2-(4,6-bis(trifluoromethyl)pyridine)yl pyrazine and 2-(4,6-bis(trifluoromethyl)pyridine)yl triazine derivatives. The iridium complex, the preparation method and the electroluminescent device have the beneficial effects that the novel iridium complex has the advantages of high luminous efficiency, high electron mobility, stable chemical properties, easiness in sublimation and purification, and the like as well as excellent device properties; and the luminous intensity and efficiency of the complex can be regulated in the wavelength range of green light by modifying the molecular structures of the main ligands, thereby providing convenience for design and production of organic electroluminescent displays and lighting sources.

Description

【Technical field】 [0001] The invention relates to the technical field of organic electroluminescent devices, in particular to a class of iridium complexes, a preparation method thereof and an electroluminescent device using the iridium complexes. 【Background technique】 [0002] Against the background of increasing global energy demand and worrying ecological environment, governments of various countries have vigorously developed sustainable energy-saving technologies and industries based on high technology. Organic electroluminescent devices (OLEDs) have attracted much attention because of their advantages such as wide viewing angle, high brightness, low energy consumption and flexible devices, and are known as the key technology that will dominate the future display world. In recent years, a large number of studies have shown that among many complexes of heavy metal elements, iridium complexes are considered to be the most ideal choice of phosphorescent materials for OLEDs....

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07F15/00C09K11/06H01L51/54
CPCC07F15/0033C09K11/06C09K2211/185H10K85/342C09K2211/1029H10K50/11H10K2101/10H10K71/311H10K50/15H10K50/16H10K85/631H10K85/654H10K85/6572H10K2102/103
Inventor 郑佑轩潘毅王毅左景林徐秋蕾
Owner AAC MICROTECH CHANGZHOU
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