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A kind of PBT permanent antistatic material and its preparation method and application

An antistatic and conductive technology, which is applied in the field of PBT permanent antistatic materials and its preparation, can solve problems such as hazards, poor low-temperature impact toughness, and difficulty in controlling static electricity

Active Publication Date: 2017-12-15
东莞市富旺塑胶制品有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polybutylene terephthalate (PBT) is a thermoplastic engineering plastic, which has been widely used in electronic appliances, home appliances, automobile industry and other fields, but due to its poor low-temperature impact toughness and high notch sensitivity at room temperature, No flame retardant effect and anti-static resistivity up to 10 -15-20 The shortcomings of high insulating materials such as Ω have great restrictions on the application of electronic products, and it is seriously difficult to control the hazards of static electricity: during use, it may cause heavy losses to human body discharge or products of various industries and disasters such as ignition and explosion, but at present In the past 20-30 years, various industries in China have used traditional (carbon-based) electrostatic conductive products in the application, such as (carbon-based) acetylene black, graphene, carbon fiber and other blended materials. In the process of turnover transportation, the carbon-based dust on the surface is micron-level after friction, collision and scratches: instant take-off and electrification enters the microelectronic components, causing defects such as easy circuit breakage of products in the electronic system due to electrostatic breakdown. With the continuous development of electronic technology, Innovation and new electrostatic materials are changing with each passing day. Carbon-based (black) materials are replaced by natural-color electrostatic materials. This project develops a PBT electrostatic material and its preparation method and application (natural color) to adjust the color without affecting the material (physics, mechanics) Equal performance, clean and beautiful appearance, permanent stable volume resistance and surface resistance, moderate price, simple process, and incomparable with traditional (carbon series) electrostatic materials in quality and cleanliness, breaking the reliance on imported white electrostatic materials for several years and High-priced and monopoly products, involving independent innovation in this field PBT composite electrostatic material is an important key point that needs to be solved urgently

Method used

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  • A kind of PBT permanent antistatic material and its preparation method and application

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Effect test

Embodiment 1

[0048] In this embodiment, the PBT antistatic material is prepared from the following raw materials:

[0049] PBT80%

[0050] Flame retardant conductive static dissipative masterbatch 20%

[0051] Among them, the flame retardant conductive static dissipative masterbatch is prepared from the following raw materials:

[0052]

[0053] The preparation method of PBT antistatic material is as follows:

[0054] A. Add polyaniline, polythiophene, silicone, conductive material and polyethylene into the mixer, the stirring speed is 20r / min, and blend and dope for 30min to obtain the mixed material; add the mixed material to the twin-screw extruder Medium-extrusion granulation, the preheating temperature in the screw area of ​​the extruder is 180°C, and the screw speed is 320r / min, to obtain a flame-retardant, conductive and static-dissipative masterbatch;

[0055] B. Blending PBT and flame retardant conductive static dissipative masterbatch, the stirring rate during blending is 1...

Embodiment 2

[0057] In this embodiment, the PBT antistatic material is prepared from the following raw materials:

[0058] PBT75%

[0059] Flame retardant conductive static dissipative masterbatch 25%

[0060] Among them, the flame retardant conductive static dissipative masterbatch is prepared from the following raw materials:

[0061]

[0062] The preparation method of PBT antistatic material is as follows:

[0063] A. Add polyaniline, polythiophene, silicone, conductive material and polyethylene into the mixer, the stirring speed is 90r / min, and blend and dope for 10min to obtain the mixed material; add the mixed material to the twin-screw extruder Medium-extrusion granulation, the preheating temperature in the screw area of ​​the extruder is 250°C, and the screw speed is 190r / min, to obtain a flame-retardant, conductive and static-dissipative masterbatch;

[0064] B. Blending PBT and flame retardant conductive static dissipative masterbatch, the stirring rate during blending is 2...

Embodiment 3

[0066] In this embodiment, the PBT antistatic material is prepared from the following raw materials:

[0067] PBT95%

[0068] Flame retardant conductive static dissipative masterbatch 5%;

[0069] Among them, the flame retardant conductive static dissipative masterbatch is prepared from the following raw materials:

[0070]

[0071] The preparation method of PBT antistatic material is as follows:

[0072] A. Add polyaniline, polythiophene, silicone, conductive material and polyethylene into the mixer, the stirring speed is 50r / min, and blend and dope for 15min to obtain the mixed material; add the mixed material to the twin-screw extruder Medium-extrusion granulation, the preheating temperature in the screw area of ​​the extruder is 200°C, and the screw speed is 220r / min, to obtain a flame-retardant, conductive and static-dissipative masterbatch;

[0073] B. Blending PBT and flame-retardant, conductive and static-dissipative masterbatch, the stirring rate during blending...

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Abstract

The present invention provides a PBT permanent antistatic material and a preparation method and application thereof, and the PBT antistatic material is prepared from 5-25% of flame-retardant electrostatic-conductive dissipative masterbatch and 75-95% of PBT. In the method, the flame-retardant electrostatic-conductive dissipative masterbatch and the PBT are blended and extruded to obtain the PBT antistatic material, the PBT antistatic material reaches high oxygen index flame retardant V0 level, the volume resistivity is 10<6-8> Omega, the surface resistivity is 10<6-9> Omega, and the electrostatic decay time is greater than 10s, so that breakdown and serious harm due to static electricity of products in the various fields can be solved, and the PBT permanent antistatic material is non-dependence on temperature and humidity, is widely used in intelligent micro-electronics, electrical appliances, electrostatic sheet packaging, wires and cables, optical photovoltaic solar energy, machinery, medical equipment, electrostatic textiles of clothing and shoes, fire protection, military electrostatic equipment, electrostatic explosion-proof industry, gas electrostatic protection safety, firework electrostatic protection safety, petroleum and chemical energy and gas station electrostatic protection, and other fields.

Description

technical field [0001] The invention belongs to the field of preparation of flame-retardant and conductive static materials, and relates to a PBT antistatic material and its preparation method and application, in particular to a PBT permanent antistatic material and its preparation method and application. Background technique [0002] Polybutylene terephthalate (PBT) is a thermoplastic engineering plastic, which has been widely used in electronic appliances, home appliances, automobile industry and other fields, but due to its poor low-temperature impact toughness and high notch sensitivity at room temperature, No flame retardant effect and anti-static resistivity up to 10 -15-20 The shortcomings of high insulating materials such as Ω have great restrictions on the application of electronic products, and it is seriously difficult to control the hazards of static electricity: during use, it may cause heavy losses to human body discharge or products of various industries and d...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/02C08L79/02C08L65/00C08K3/22C08K3/34C08K3/16C08J3/22B29C47/92B29C48/92
CPCB29C48/92B29C2948/9259B29C2948/92704C08J3/226C08J5/18C08J2367/02C08J2465/00C08J2479/02C08L67/02C08L2201/02C08L2201/04C08L2203/16C08L2203/20C08L2205/035C08L79/02C08L65/00C08K3/2279C08K3/34C08K3/16
Inventor 孔作万王来富汪志祥
Owner 东莞市富旺塑胶制品有限公司
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