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A thermally activated delayed fluorescent material and an organic electroluminescent device

A technology of thermally activated delayed and fluorescent materials, applied in luminescent materials, electro-solid devices, organic chemistry, etc., can solve the problem of low efficiency of the luminescent layer, and achieve the effects of high radiation transition rate, good stability and short lifespan

Active Publication Date: 2018-06-22
KUNSHAN GO VISIONOX OPTO ELECTRONICS CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] For this reason, the present invention aims at the problem of the low efficiency of the light-emitting layer of the existing OLED, and provides a thermally activated delayed fluorescent material whose singlet-triplet energy gap (ΔE ST ) is very small, the triplet excitons can be transformed into singlet excitons to emit light through reverse intersystem jumping (RIST), which can improve the efficiency and stability of OLED devices

Method used

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  • A thermally activated delayed fluorescent material and an organic electroluminescent device
  • A thermally activated delayed fluorescent material and an organic electroluminescent device
  • A thermally activated delayed fluorescent material and an organic electroluminescent device

Examples

Experimental program
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Effect test

Embodiment 1

[0068] Synthetic method of the structural compound shown in formula (1-1): under nitrogen range, 3,6-dibromo-9-fluorenone (5mmol), phenoxazine (18mmol), Pd 2 (dba) 3 (0.8mmol), NaOtBu (30mmol) and tBu3P·HBF4 (0.8mmol) were put into 100mL toluene and stirred at 105°C overnight. The reaction was quenched by adding 10 mL of cold water to the mixture. After the mixture was cooled to room temperature, it was vacuum filtered and then purified by column chromatography to obtain the product with the structure shown in formula (1-1). The product was dried in vacuum, yield: 80%.

[0069] The molecular weight obtained by mass spectrometry: 542.58.

[0070] The relative molecular mass percentages of each element obtained by elemental analysis: C: 81.90%; H: 4.09%; N: 5.16%; O: 8.85%.

Embodiment 2

[0072] Synthetic method of the structural compound shown in formula (1-2): the reactant phenoxazine is replaced by phenothiazine, through the same synthetic method as in Example 1, the structural compound shown in formula (1-2) is obtained, and the yield is 91% .

[0073] The molecular weight obtained by mass spectrometry: 574.71.

[0074] The relative molecular mass percentages of each element obtained by elemental analysis: C: 77.32%; H: 3.86%; N: 4.87%; O: 2.78%; S: 11.16%.

Embodiment 3

[0076] Synthesis method of the compound with the structure shown in formula (1-3): the reactant phenoxazine is replaced by 9,9-dimethylacridine, and the structure shown in formula (1-3) is obtained through the same synthesis method as in Example 1 Compound, yield 87%.

[0077] The molecular weight obtained by mass spectrometry: 594.74.

[0078] The relative molecular mass percentages of each element obtained by elemental analysis: C: 86.84%; H: 5.76%; N: 4.71%; O: 2.69%.

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Abstract

The invention relates to a thermally activated delayed fluorescent material, which has the general formula of the structure shown in formula (I) or formula (II), wherein D is phenoxazinyl, phenothiazinyl, 9,9-dimethylacridine Base, 9-methylphenazinyl, 9-phenylphenazinyl, 4-phenoxazinyl-1-phenyl, 4-phenothiazinyl-1-phenyl, 4-(9,9-two Methyl)acridinyl-1-phenyl, 4-(9-methyl)phenazinyl-1-phenyl, 4-(9-phenyl)phenazinyl-1-phenyl, 3,5- A kind of dicarbazolyl-1-phenyl. The invention also relates to an organic electroluminescence device, which comprises a luminescent layer, and the luminescent dye of the luminescent layer is the thermally activated delayed fluorescent material. The singlet-triplet energy gap (ΔEST) of thermally activated delayed fluorescent materials is very small, and the triplet excitons can be transformed into singlet excitons to emit light through reverse intersystem jumping (RIST), which can improve the efficiency and stability of OLED devices. sex.

Description

technical field [0001] The invention relates to the field of organic electroluminescent devices, in particular to a thermally activated delayed fluorescent material that can be used in a light-emitting layer and an organic electroluminescent device with the thermally activated delayed fluorescent material. Background technique [0002] Organic Light Emitting Diode (OLED) is a current-driven light-emitting device that uses organic materials as active materials. Specifically, organic semiconductor materials and organic light-emitting materials are driven by electric fields through carrier injection and Composite technology that leads to luminescence. Unlike inorganic materials, organic materials have the characteristics of low synthesis cost, adjustable function, flexibility, and good film-forming properties. Moreover, devices based on organic materials are generally simple in fabrication process, easy to be prepared in a large area, and are environmentally friendly, and can ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07D265/38C07D279/22C07D219/02C07D241/46C07D413/14C07D209/86C07D417/14C07D409/14C09K11/06C09B19/00C09B21/00C09B15/00C09B17/02C09B57/00H01L51/54
CPCC09K11/06C07D209/86C07D219/02C07D241/46C07D265/38C07D279/22C07D409/14C07D413/14C07D417/14C09B15/00C09B17/02C09B19/00C09B21/00C09B57/00C09K2211/1029C09K2211/1011C09K2211/1007C09K2211/1033C09K2211/1037C09K2211/1044C09K2211/1092H10K85/615H10K85/657H10K85/6576H10K85/6572
Inventor 段炼张云阁刘嵩赵菲
Owner KUNSHAN GO VISIONOX OPTO ELECTRONICS CO LTD
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