Salt-tolerant agricultural nutritional type super absorbent resin and preparation method thereof
A superabsorbent resin and nutrient-based technology, applied in chemical instruments and methods, applications, agriculture, etc., can solve problems such as poor salt tolerance and inability to provide nutrients for crop growth, achieve strong water-locking performance, and improve soil buffering capacity, growth-promoting effect
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Embodiment 1
[0016] In the present embodiment, the percentage by weight of raw materials is: 4% xanthan gum, 5% guar gum, 4% sodium humate, 8% monoammonium phosphate, 40% acrylic acid, 12% sodium hydroxide, 11% reinforcing agent %, initiator 7%, crosslinking agent 9%.
[0017] The preparation method of salt-tolerant agricultural nutritional superabsorbent resin, the steps are as follows:
[0018] 1) Prepare a sodium hydroxide solution with a mass concentration of 35%, and neutralize acrylic acid, and the neutralization degree is 65% for later use;
[0019] 2) Add xanthan gum and guar gum to the reaction vessel, and pass through nitrogen protection, heat in a water bath, activate at 60°C for 2 hours, cool at 50°C, add a mixture of humic acid and monoammonium phosphate, and then neutralize well The acrylic acid, reinforcing agent, initiator, and crosslinking agent were added in a water bath, and nitrogen gas was introduced at the same time, the reaction temperature was controlled at 50°C, t...
Embodiment 2
[0024] In the present embodiment, the percentage by weight of raw materials is: 4% xanthan gum, 5% guar gum, 6% sodium humate, 7% monoammonium phosphate, 38% acrylic acid, 13% sodium hydroxide, 10% reinforcing agent %, initiator 8%, crosslinking agent 9%.
[0025] The preparation method of salt-tolerant agricultural nutritional superabsorbent resin, the steps are as follows:
[0026] 1) Prepare a sodium hydroxide solution with a mass concentration of 30%, and neutralize acrylic acid, and the neutralization degree is 65% for later use;
[0027] 2) Add xanthan gum and guar gum to the reaction vessel, and pass through nitrogen protection, heat in a water bath, activate at 60°C for 1.5 hours, cool at 40°C, add a mixture of humic acid and monoammonium phosphate, and then neutralize well The acrylic acid, reinforcing agent, initiator, and crosslinking agent were added in a water bath, and nitrogen gas was introduced at the same time, the reaction temperature was controlled at 70°C,...
Embodiment 3
[0032] In the present embodiment, the percentage by weight of raw materials is: 6% xanthan gum, 5% guar gum, 7% sodium humate, 8% monoammonium phosphate, 31% acrylic acid, 12% sodium hydroxide, 12% reinforcing agent %, initiator 8%, crosslinking agent 11%.
[0033] The preparation method of salt-tolerant agricultural nutritional superabsorbent resin, the steps are as follows:
[0034] 1) Prepare a sodium hydroxide solution with a mass concentration of 25%, and neutralize acrylic acid, with a neutralization degree of 70% for subsequent use;
[0035] 2) Add xanthan gum and guar gum to the reaction vessel, and pass through nitrogen protection, heat in a water bath, activate at 70°C for 1 hour, cool at 45°C, add a mixture of humic acid and monoammonium phosphate, and then neutralize well The acrylic acid, reinforcing agent, initiator, and crosslinking agent were added in a water bath, and nitrogen gas was introduced at the same time, the reaction temperature was controlled at 65°...
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