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Red mud modification method, modified product and its application in adsorption of brilliant blue dye

A technology of modified compounds and blue dyes, applied in chemical instruments and methods, adsorption water/sewage treatment, other chemical processes, etc., can solve problems such as environment, safety and waste of resources, occupation of land resources, hidden dangers of ecological environment, etc. To achieve the effect of convenient material acquisition, large specific surface area and high use value

Active Publication Date: 2016-10-05
青岛中科煜成安全技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the annual increase of alumina production in my country and the gradual decrease of bauxite grade, the annual production of red mud will continue to increase. The long-term accumulation of a large amount of red mud not only occupies land resources, but also brings many ecological and environmental problems. and security risks
How to solve the environmental, safety and resource waste problems caused by its large stockpiling is currently a hot topic in academic and industrial research.

Method used

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  • Red mud modification method, modified product and its application in adsorption of brilliant blue dye
  • Red mud modification method, modified product and its application in adsorption of brilliant blue dye
  • Red mud modification method, modified product and its application in adsorption of brilliant blue dye

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The red mud is washed to neutral, dried, ball milled and passed through a 200-mesh sieve; according to the molar ratio of Mg:(Al+Fe)=3:1, the magnesium oxide and red mud are evenly mixed, and roasted at 550°C for 4h. Obtain LDO, obtain the required adsorbent material through ball milling and passing through a 200-mesh sieve, which is denoted as adsorbent I.

Embodiment 2

[0030] The red mud is washed to neutral, dried, ball milled and passed through a 200-mesh sieve; according to the molar ratio of Mg:(Al+Fe)=3:1, the magnesium oxide and red mud are evenly mixed, and roasted at 550°C for 4h. Obtain LDO, through ball milling, pass 200 mesh sieves; Configure saturated sodium carbonate solution according to the mass ratio of LDO:sodium carbonate=3:1, put LDO into sodium carbonate solution, fully stir 10h, carbonate anion and free water Introduce its interlayer structure and synthesize LDH as another adsorbent material, denoted as Adsorbent II.

[0031] 2. Application of brilliant blue dye adsorption:

[0032] 1) Preparation of brilliant blue dye simulated wastewater:

[0033] Weigh reactive brilliant blue dyes and dissolve them in a certain amount of water, prepare simulated wastewater with a concentration of 20, 50, 100, 200, and 400 mg / L, and weigh 50 ml of simulated wastewater for each set of samples.

[0034] 2) Preparation of contrast adsor...

Embodiment 3

[0043] Add 0.1-1g of adsorbent II to 50mg / L brilliant blue dye, shake at 27°C for 120min, then take the supernatant and centrifuge at 4000rpm for 10min, and use UV-visible spectrophotometer to measure its Absorbance, and calculate its removal rate. With the increase of LDH addition, the removal rate of LDH to Brilliant Blue increased from 54.2% to 89.0%.

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Abstract

The invention relates to a red mud modification method, a modified product and its application in absorbing brilliant blue dye, and the red mud modification method, the steps of which include pretreatment and LDO synthesis. The beneficial effects of the present invention are: by reusing the red mud, an LDO adsorbent with a larger specific surface area and capable of accommodating a large amount of anionic dyes is prepared, the preparation process requires less additional materials, the process is simple, and the success rate is high. And LDO has a high adsorption and removal rate for simulated wastewater. For 50mg / L brilliant blue dye simulated wastewater, the removal rate of 0.1gLDO can reach more than 98%, which is far higher than the highest removal rate of red mud38 %, 22% of roasted red mud and 89% of LDH; especially for 400mg / L simulated wastewater, the highest adsorption capacity of LDO can reach 170mg / g, which has a high use value.

Description

technical field [0001] The invention belongs to the research field of adsorbent materials, and in particular relates to a red mud modification method, a modified product and its application in absorbing brilliant blue dyes. Background technique [0002] Red mud (Red Mud, referred to as RM) is the waste residue produced in the alumina production process. Because of its red appearance, it is called red mud. At present, an average of 1-2 tons (dry weight) of red mud is discharged for every 1 ton of alumina produced. In recent years, my country's alumina industry has developed rapidly. According to the annual report released by Aluminum Corporation of China, my country's alumina production in 2011 was 38.81 million tons, accounting for about 30% of the world's total output, and the red mud produced was more than 40 million tons. ; At present, the comprehensive utilization rate of red mud in my country is only 4%, and the cumulative stockpiles have reached 250 million tons. With...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/08B01J20/30C02F1/28C02F103/30
Inventor 钱翌陈希磊贾垂轩
Owner 青岛中科煜成安全技术有限公司
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