Bauxite-containing heavy oil hydrogenation catalyst, and preparation and application thereof
A heavy oil hydrogenation and catalyst technology, which is applied in the direction of organic compound/hydride/coordination complex catalyst, physical/chemical process catalyst, petroleum industry, etc., can solve the problems of poor stability and dispersion performance, and achieve good mixing ability, good The effect of heavy oil hydrogenation catalytic activity and good catalytic effect
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Embodiment 1
[0028] Weigh 38g of diesel oil, add 1.0g of organic bentonite (Jiangsu Huate New Material Co., Ltd., the mass fraction of organic matter is 20-35%), and homogenize with a shearing machine. Add 1.0 g of analytically pure oleic acid, then heat and stir on an 80° C. oil bath for 1 h. The obtained homogeneous mixed oil was cooled to room temperature, 0.5 g of PEG 600, 0.2 g of sodium dodecylbenzenesulfonate, and 0.5 g of analytically pure ethylene glycol were added to homogenize at room temperature to obtain dispersion medium A.
Embodiment 2
[0030] Weigh 42 g of kerosene, add 1.0 g of organic bentonite (Jiangsu Huate New Material Co., Ltd., the mass fraction of organic matter is 20-35%), and homogenize with a shearing machine. Add 1.2g of analytically pure oleic acid, heat to 70°C and stir for 2h. After cooling to room temperature, 0.2 g of sodium oleate, 0.4 g of PEG2000, and 1.0 g of analytically pure ethanol were added. Stir evenly at high speed to obtain dispersion medium B.
Embodiment 3
[0032] Take bauxite powder whose average particle size is less than 20 μm, weigh 3.0 g and place it in a test tube. Weigh 5.0g of dispersion medium A into the same test tube, stir and vibrate with a glass rod, wait for the powder to infiltrate evenly, and let it stand for 24 hours without obvious sedimentation. Catalyst C1 is obtained.
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