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Method for preparing palm kernel shell activated carbon by catalytic activation

A catalytic activation and palm shell technology, applied in the field of activated carbon, can solve the shortage of raw materials and other problems, and achieve the effect of reusing, cost saving and huge economic benefits

Inactive Publication Date: 2013-07-24
INST OF CHEM IND OF FOREST PROD CHINESE ACAD OF FORESTRY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Purpose of the invention: the purpose of this invention is to propose a method for preparing palm shell activated carbon by catalytic activation, so as to solve the problem of shortage of raw materials in the production of activated carbon

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Example 1: Put 100g of raw material palm shell into a crucible and carry out anaerobic carbonization in a muffle furnace at 450°C for 1h, then take 10g of carbonized material and 5ml of potassium carbonate solution with a mass percentage concentration of 2% for immersion, and then carbonize The mass ratio of material and potassium carbonate impregnation is 100:1. After drying, it is placed in a tube furnace for activation for 1 hour at 850 ° C and a water vapor velocity of 1 g / min. Finally, it is washed and dried to obtain the product. Its methylene blue The adsorption value is 240 mg / g, and the iodine adsorption value is 1164 mg / g.

Embodiment 2

[0026] Embodiment 2: put 100g raw material into the crucible and carry out anaerobic carbonization in muffle furnace at 450 ℃ for 90min, then get 10g carbonized material and 5ml mass percent concentration and be 1.4% potassium carbonate solution impregnation, now carbonized material and The mass ratio of potassium carbonate in the impregnation solution is 100:0.7. After drying, place it in a tube furnace for activation for 1.5 hours at 850°C and a water vapor velocity of 1.5g / min, and finally wash and dry to obtain the product , its methylene blue adsorption value is 278mg / g, iodine adsorption value is 1268mg / g.

Embodiment 3

[0027] Embodiment 3: put 100g raw material into the crucible and carry out anaerobic carbonization in muffle furnace at 550 ℃ for 30min, then get 10g carbonized material and 5ml mass percent concentration and be 5% potassium carbonate solution impregnation, now carbonized material and The mass ratio of potassium carbonate in the impregnating solution is 100:2.5. After drying, place it in a tube furnace for activation for 0.5h at 950°C and a water vapor velocity of 2g / min, and finally wash and dry to obtain the product. Its methylene blue adsorption value is 245 mg / g, and iodine adsorption value is 1180 mg / g.

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PUM

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Abstract

The invention discloses a method for preparing palm kernel shell activated carbon by catalytic activation. The method comprises a carbonizing process, an activating process and a washing process; specifically, the method comprises the following steps: the carbonizing process of heating and carbonizing under the oxygen-isolating condition by using dried palm kernel shell as the material; an impregnating process of mixing the carbonized material with a potassium carbonate solution, so that the catalyst potassium carbonate solution is sufficiently impregnated into the carbonized material, wherein the mass percent concentration of the potassium carbonate solution is 1%-5%; and a weight ratio of the carbonized material to the potassium carbonate is 100:(0.5-3); the activating process of drying the moisture in the impregnated product and placing the dried impregnated product in activating equipment, and ventilating water vapor for activating; and the washing process of washing and drying the activated product to obtain the activated carbon. The method for preparing palm kernel shell activated carbon by catalytic activation can be used for saving the production cost and improving the catalytic effect of the potassium carbonate. And the adsorption value of the activated carbon methylene blue and iodine is respectively 240mg / g-285mg / g and 150mg / g-1300mg / g.

Description

Technical field: [0001] The invention belongs to the technical field of activated carbon and relates to the preparation of activated carbon, in particular to a method for preparing palm shell activated carbon by catalytic activation. Background technique: [0002] Activated carbon is a kind of material with developed pore structure, huge specific surface area and strong adsorption capacity prepared from carbonaceous materials such as wood and coal. It is widely used in environmental protection, national defense, chemical industry, food, medicine, textile and other fields. . In recent years, the shortage of coal and sawdust resources has become increasingly serious. Therefore, it is an important task for the development of my country's and the world's activated carbon industry to continuously develop raw materials for activated carbon production, explore new process conditions, and increase new varieties. Palm is an important economic crop. It is planted in many countries in...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B31/10C01B32/336
Inventor 邓先伦郭昊朱光真王国栋
Owner INST OF CHEM IND OF FOREST PROD CHINESE ACAD OF FORESTRY
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