Pressure-sensitive adhesive sheet
一种粘着片、粘着剂层的技术,应用在胶粘剂、薄膜/薄片状的粘合剂、运输和包装等方向,能够解决耐候性低、变白、外观变差等问题,达到耐候性优良的效果
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Embodiment 1
[0092] Using a two-screw extrusion kneader (manufactured by TECHNOVEL, KZW25TWIN-30MG-STM), 88% by mass of an ethylene-methacrylic acid copolymer (manufactured by Mitsui DuPont Polychemical Co., Ltd., NUCRELN0903HC) as a polyolefin resin was prepared as A mixture of 10% by mass of styrene-butadiene-styrene resin (manufactured by JSR Corporation, TR2250) and 2.0% by mass of carbon black (manufactured by Asahi Carbon Black Co., Ltd., SUNBLACK200) as a pigment, Make mixes. Next, a film having a film thickness of 100 μm was produced from the kneaded sheet using an extrusion tester (Toyo Seiki Seisakusho Co., Ltd., Labo Plastomill 30C150). The obtained film was used as a base material of an adhesive sheet. Here, the formulation composition of the constituent materials of the substrate is shown in Table 1 (the same applies hereinafter).
[0093] Both sides of high-quality paper are laminated with polyethylene resin, and one side is peeled with a silicone-based release agent. A co...
Embodiment 2
[0096] Using a two-screw extrusion kneader (manufactured by TECHNOVEL, KZW25TWIN-30MG-STM), 60% by mass of ethylene-methacrylic acid copolymer (manufactured by Mitsui DuPont Polychemical Co., Ltd., NUCRELN0903HC) and benzene as an olefin resin were mixed. A mixture of 10% by mass of styrene-butadiene-styrene resin (manufactured by JSR Corporation, TR2250) of vinyl resin and 30.0% by mass of carbon black (manufactured by Asahi Tan Corporation, SUNBLACK200) as a pigment was prepared. Practice film. The pressure-sensitive adhesive sheet was produced in the same manner as in Example 1 except that this kneaded sheet was used.
Embodiment 3
[0098] Using a two-screw extrusion kneader (manufactured by TECHNOVEL, KZW25TWIN-30MG-STM), 50% by mass of ethylene-methacrylic acid copolymer (manufactured by Mitsui DuPont Polychemical Co., Ltd., NUCRELN0903HC) and benzene as an olefin resin were mixed. A mixture of 48% by mass of styrene-butadiene-styrene resin (manufactured by JSR Corporation, TR2250) and 2.0% by mass of carbon black (manufactured by Asahi Tan Corporation, SUNBLACK200) as a pigment was prepared as a blend. Practice film. Except having used this kneading sheet, it carried out similarly to Example 1, and produced the adhesive sheet.
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