Organic electroluminescent material containing tertiary aromatic amine structure and preparation method and application thereof
A triarylamine, electroluminescence technology, used in luminescent materials, chemical instruments and methods, circuits, etc.
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Embodiment 1
[0029] Synthesis of Example 1 Compound M101
[0030] The synthesis of step 1, diarylamine compound:
[0031]
[0032] Under nitrogen protection system, weigh 100mmol (20.9g) of ligand fluorenyl aromatic amine a and 110mmol (17.16g) of aryl halide b into the reaction system, add KOH solid 400mmol (22.4g), add dry dehydrated Toluene 500ml, under nitrogen protection, catalyst CuI 10mmol (1.9g), 1.10-phenanthroline 20mmol (3.6g), under nitrogen protection, reflux reaction for 5 hours, cooling after reaction, suction filtration, concentration, dichloromethane as solvent, Perform column chromatography on silica gel and concentrate to obtain 26.22 g of an off-white diamine product with a yield of more than 92% and an HPLC purity of more than 98%. It can be used directly for the next reaction.
[0033] Step 2, the synthesis of triarylamine compound (M101):
[0034]
[0035] Weigh 50mmol (14.25g) of diarylamine compound, 55mmol (17.66g) of carbazolyl halide, 75mmol (8.4g) of p...
Embodiment 2
[0037] Synthesis of Example 2 Compound M106
[0038] The synthesis of step 1, diarylamine compound:
[0039]
[0040] Under nitrogen protection system, weigh 100mmol (25.9g) of ligand fluorenyl aromatic amine a and 110mmol (28.60g) of aryl halide b into the reaction system, add KOH solid 400mmol (22.4g), add dry dehydrated Toluene 500ml, under nitrogen protection, catalyst CuI 10mmol (1.9g), 1.10-phenanthroline 20mmol (3.6g), under nitrogen protection, reflux reaction for 10 hours, cooling after reaction, suction filtration, concentration, dichloromethane as solvent, Perform column chromatography on silica gel and concentrate to obtain 39.51 g of off-white diamine product with a yield of 90% and a purity of more than 98% by HPLC. It can be used directly for the next reaction.
[0041] Step 2, the synthesis of triarylamine compound (M106):
[0042]
[0043] Weigh 50mmol (21.95g) of diarylamine compound, 55mmol (17.66g) of carbazolyl halide, 75mmol (8.4g) of potassium t...
Embodiment 3
[0046] Example 3 Synthesis of compound M109
[0047] The synthesis of step 1, diarylamine compound:
[0048]
[0049] Under nitrogen protection system, weigh 100mmol (28.5g) of ligand fluorenyl aromatic amine a and 110mmol (25.52g) of aryl halide b into the reaction system, add KOH solid 400mmol (22.4g), add dry dehydrated Toluene 500ml, under nitrogen protection, catalyst CuI 10mmol (1.9g), 1.10-phenanthroline 20mmol (3.6g), under nitrogen protection, reflux reaction for 8 hours, cooling after reaction, suction filtration, concentration, dichloromethane as solvent, Perform column chromatography on silica gel and concentrate to obtain 20.11 g of off-white diamine product with a yield of 92% and an HPLC purity greater than 98%. It can be used directly for the next reaction.
[0050] Step 2, the synthesis of triarylamine compound (M109):
[0051]
[0052] Weigh 50mmol (21.85g) of diarylamine compound, 55mmol (21.84g) of carbazolyl halide, 75mmol (8.4g) of potassium tert...
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