High-strength laminated fire-retarding conveyer belt coating rubber, and preparation method thereof

A covering layer and conveyor belt technology, which is applied in the field of high-strength laminated flame-retardant conveyor belt covering rubber and its preparation, can solve the problems of incapable of high mechanical properties, poor flexibility, poor toughness and softness, etc. It is difficult to balance mechanical strength and excellent flame retardant performance, improve flexibility and strength, and improve the effect of mechanical strength

Inactive Publication Date: 2012-06-27
WUXI BOTON TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Although the above-mentioned flame-retardant rubber materials have relatively moderate mechanical properties and flame-retardant properties, especially excellent flame-retardant properties, there are still some problems: polyvinyl chloride is a plastic product, although polyvinyl chloride and nitrile rubber are often blended The covering layer is made of rubber material, but its toughness and softness are still inferior to rubber materials, and the conveyor belt is easy to slip, deviate, and has poor flexibility; neoprene is used as the covering layer rubber material, which has poor processing performance and is easy to stick to the roller. , easy to scorch, and difficult to control the process during processing; while the above two traditional cover layer rubber materials meet the flame retardant properties, their mechanical properties are relatively low, both of which can only reach about 15MPa, which cannot satisfy the flame retardant properties. achieve higher mechanical properties
At the same time, the above two covering layer rubber reinforcement fillers are traditional carbon black fillers, and the cost is relatively high
[0005] Other halogen-free rubbers, such as commonly used styrene-butadiene rubber, natural rubber, polybutadiene rubber, etc., need to be filled with a large amount of flame retardants in order to achieve excellent flame retardancy, which is difficult to balance high mechanical strength

Method used

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  • High-strength laminated fire-retarding conveyer belt coating rubber, and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] On the double-roll mill, add 500g styrene-butadiene rubber (commercially available SBR1502) for mastication, and then add metal oxides: 15g nano-zinc oxide, 10g nano-magnesium oxide and 5g stearic acid, anti-aging agent: 2, 2, 4 - Trimethyl-1,2-dihydroquinoline polymer (RD) 5g, N-phenyl-N'-base p-phenylenediamine (4010NA) 10g, flame retardant: chlorinated paraffin 150g, dioxygen trioxide Antimony 40g and zinc borate 40g, reinforcing agent: surface modified silicon dioxide 250g, nano-magnesium hydroxide 100g, and finally add vulcanization accelerator 2-mercaptobenzothiazole (M) 10g, N-tert-butyl-2 -5 g of benzothiazole sulfenamide (NS) and 5 g of N-cyclohexyl-2-benzothiazyl sulfenamide (CZ), and 10 g of sulfur as the vulcanizing agent. Mix evenly on an open mill to obtain a cover layer glue; vulcanize the cover layer glue and the adhesive layer on a molded vulcanized plate at 150°C to obtain a product, and its properties are shown in Table 1.

[0034] The high-strength ...

Embodiment 2

[0036] On the double-roll mill, add 400g styrene-butadiene rubber (commercially available SBR1502), 100g cis-butadiene rubber (commercially available BR9000) for mastication, and then add activator metal oxides in sequence: nano-zinc oxide 15g, nano-magnesium oxide 10g and hard Fatty acid 5g, antioxidant: 2,2,4-trimethyl-1,2-dihydroquinoline polymer (RD) 5g, N-phenyl-N'-yl p-phenylenediamine (4010NA) 10g, Flame retardant: 140g chlorinated paraffin, 50g antimony trioxide and 60g zinc borate, reinforcing agent: 275g surface-modified silicon dioxide, 125g nano-magnesium hydroxide, and finally add vulcanization accelerator 2-mercaptobenzothiazole (M) 10g, N-tert-butyl-2-benzothiazolyl sulfenamide (NS) 5g and N-cyclohexyl-2-benzothiazolyl sulfenamide (CZ) 5g, the vulcanizing agent is sulfur 10g. Mix evenly on an open mill to obtain a cover layer rubber, and then vulcanize the cover layer rubber and the adhesive layer on a molded vulcanized board at 150°C to obtain a flame-retardant...

Embodiment 3

[0038] On the double-roll mill, add 300g styrene-butadiene rubber (commercially available SBR1502), 200g natural rubber (commercially available natural rubber 10#) for mastication, and then add activator metal oxides in turn: 20g nano-zinc oxide, 5g nano-magnesium oxide And stearic acid 5g, antioxidant: 2-mercaptobenzimidazole (MB) 5g, N-phenyl-N'-base p-phenylenediamine (4010NA) 10g, flame retardant: chlorinated paraffin 100g, dioxygen trioxide 60g of antimony and 75g of zinc borate, reinforcing agent: 275g of surface-modified silicon dioxide, 150g of nano-calcium carbonate, and finally add vulcanization accelerator 2-mercaptobenzothiazole (M) 5g, tetramethylthiuram disulfide (TMTD) 5g and N-cyclohexyl-2-benzothiazolyl sulfenamide (CZ) 5g, the vulcanizing agent is sulfur 10g. Mix evenly on an open mill to obtain a cover layer rubber, and then vulcanize the cover layer rubber and the adhesive layer on a molded vulcanized board at 150°C to obtain a flame-retardant conveyor belt...

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Abstract

The invention relates to high-strength laminated fire-retarding conveyer belt coating rubber and a preparation method thereof. The rubber has both high fire retardance and mechanical strength, and can be used as fire-retarding conveyer belt coating rubber. According to the method, substrate rubber is masticated in a double-roll open mill; stearic acid, an anti-aging agent, a fire retardant, metal oxide, a reinforcing agent, a vulcanization accelerator and a vulcanizing agent are added to the substrate sequentially; the mixture is uniformly mixed in the open mill, such that coating gum is obtained; the coating gum and a bonding layer are vulcanized on a molding vulcanization plate, such that a high-strength laminated fire-retarding conveyer belt coating rubber product is obtained. According to the invention, styrene butadiene rubber, natural rubber, cis-1,4-polybutadiene rubber or a mixture of the three is adopted as the substrate rubber. Compared to a traditional coating material, mechanical strength, flexibility and processing property of the coating rubber are improved, and cost is reduced.

Description

technical field [0001] The invention relates to a high-strength laminated flame-retardant conveyor belt covering layer rubber and a preparation method thereof, which has high flame-retardant performance and mechanical strength and can be used for the flame-retardant conveyor belt covering layer rubber. Background technique [0002] The conveyor belt is the main tool for transporting materials on the ground and transporting coal underground in coal mines. Since the traditional rubber conveyor belt is flammable, the material structure strength of the conveyor belt will drop sharply in case of fire and strong heat radiation, and the components will collapse. The conveyor belt has repeatedly caused major fire accidents and cannot meet the requirements of flame retardancy. The belt material must have flame retardant properties [Special Rubber Products, 2007, 28(5): 47-52]. [0003] After years of research and development, various countries in the world have formed a situation wh...

Claims

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Application Information

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IPC IPC(8): C08L9/06C08L7/00C08L9/00C08K13/06C08K9/06C08K3/22C08K3/38C08K3/36C08K3/26B65G15/32
Inventor 马晨田明张立群吴建国华晓晶
Owner WUXI BOTON TECH CO LTD
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