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Electrode plate for lithium ion battery and manufacturing method thereof

A lithium-ion battery and electrode sheet technology, which is applied to battery electrodes, circuits, electrical components, etc., can solve the problems of difficulty in ensuring the uniformity of carbon nanotube dispersion, difficulty in controlling the dispersion effect of conductive agents, and unsuitable for industrialized production. It is convenient for industrial production, good filling effect and low production cost.

Inactive Publication Date: 2010-05-19
CHONGQING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The main disadvantages of this patent are: special dispersion of carbon nanotubes and carbon fibers is required, and it is difficult to ensure the uniformity of dispersion of carbon nanotubes by means of ultrasonic dispersion and stirring, and the uniformity of dispersion of carbon nanotubes will directly affect lithium The electrochemical capacity of the ion battery, the method of the invention has many steps, the dispersion effect of the conductive agent is difficult to control, and is not suitable for industrialized production
However, the research on multilayer graphene as a conductive agent for lithium-ion batteries has not yet been reported in domestic and foreign journals and patent materials.

Method used

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  • Electrode plate for lithium ion battery and manufacturing method thereof
  • Electrode plate for lithium ion battery and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A kind of component and the mass percent thereof of lithium-ion battery electrode pole piece are:

[0037] Positive electrode active material 90wt.%

[0038] Conductive agent 5wt%

[0039] Binder 5wt%

[0040] Among them: the positive electrode active material is layered lithium cobalt oxide, that is, the chemical formula is LiCoO 2 The conductive agent is multi-layer graphene; the binder is polytetrafluoroethylene (PTFE).

[0041] The concrete steps of a kind of lithium-ion battery electrode pole sheet manufacturing method are as follows:

[0042] (1) material preparation

[0043] Prepare raw materials according to the mass ratio of positive electrode active material: conductive agent: binder is 90:5:5, wherein: wherein: the positive electrode active material is a layered compound, and its chemical formula is LiCoO 2 ; The conductive agent is multi-layer graphene; the binder is polytetrafluoroethylene;

[0044] (2) Preparation of electrode slurry

[0045]After s...

Embodiment 2

[0050] A kind of component and the mass percent thereof of lithium-ion battery electrode pole piece are:

[0051] Positive active material 75wt.%

[0052] Conductive agent 15wt%

[0053] Binder 10wt%

[0054] Among them: the positive active material is olivine-type lithium iron phosphate oxide, and its chemical formula is LiFePO 4 ; The conductive agent is multi-layer graphene; the binder is polytetrafluoroethylene.

[0055] A kind of specific steps of the method for making electrode pole piece of lithium ion battery, the same as embodiment 1, wherein:

[0056] In step (1), the mass ratio of positive electrode active material: conductive agent: binder is 75:15:10;

[0057] Among them: the positive active material is olivine-type lithium iron phosphate oxide, and its chemical formula is LiFePO 4 ; The conductive agent is multi-layer graphene; the binder is polytetrafluoroethylene;

[0058] In the (2) step, the mass (g) of the conductive agent: the ratio of the dispersant ...

Embodiment 3

[0060] A kind of component and the mass percent thereof of lithium-ion battery electrode pole piece are:

[0061] Positive active material 98wt.%

[0062] Conductive agent 1wt%

[0063] Binder 1wt%

[0064] Among them: the positive active material is spinel lithium manganese oxide, that is, the chemical formula is LiMn 2 o 4 ; The conductive agent is a mixture of multilayer graphene and carbon black, and the mass ratio of the two is 1:1; the binder is polytetrafluoroethylene (PTFE).

[0065] A kind of specific steps of the method for making electrode pole piece of lithium ion battery, the same as embodiment 1, wherein:

[0066] In step (1), the mass ratio of positive electrode active material: conductive agent: binder is 98:1:1, wherein: the positive electrode active material is spinel lithium manganese oxide, and its chemical formula is LiMn 2 o 4 ; The conductive agent is a mixture of multilayer graphene and carbon black, and the mass ratio of the two is 1:1; the binde...

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Abstract

The invention discloses an electrode plate for a lithium ion battery and a manufacturing method thereof, and particularly relates to the electrode plate for the lithium ion battery taking multi-layer graphene as a conductive agent and a manufacturing method thereof. The electrode plate of the invention consists of a positive electrode or negative electrode active substance, the conductive agent and an adhesive. The method comprises the steps of: using the positive electrode or negative electrode active substance, the conductive agent and the adhesive as raw materials to obtain electrode slurry through stirring and dispersing, and then obtaining the electrode plate through coating, drying and tabletting. The conductive agent adopted by the invention has the advantages of high dispersivity, high electric conductivity, good filling effect and the like; and the method has the advantages of simplicity, low production cost and convenient popularization and application. The method can remarkably improve the electric conductivity, electrochemical capacity and enhance charge-discharge capability of electrode materials by multiples, so the method can be widely applied to the preparation of electrode plates of lithium ion batteries.

Description

technical field [0001] The invention belongs to the technical field of carbon materials and chemical power sources, and in particular relates to lithium-ion battery electrode pole pieces using multilayer graphene as a conductive agent and a manufacturing method thereof. Background technique [0002] As a new type of green secondary battery with high specific energy, lithium-ion battery occupies a leading position in the market of mobile phones, notebook computers, cameras, etc., and has become the main power source of small civilian electronic products. With the research and development of high-power lithium-ion battery packs, the application of lithium-ion batteries is rapidly expanding to fields such as electric vehicles, space satellites, military communications, and aviation and navigation. [0003] In fact, the conductivity of lithium-ion battery cathode materials is very poor, and its conductivity is in the range of 10 -4 -10 -9 Between S / cm. In order to enhance the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/62H01M4/1393H01M4/133
CPCY02E60/12Y02E60/122Y02E60/10
Inventor 李新禄杜坤黄佳木张育新
Owner CHONGQING UNIV
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