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High-temperature and high-pressure hydrogenation method for castor oil

A high temperature and high pressure, castor oil technology, applied in the direction of fatty acid hydrogenation, etc., can solve the problems of unstable product quality, waste of production cost, low equipment utilization rate, etc., to shorten the hydrogenation reaction time, reduce equipment loss, and improve production efficiency. Effect

Active Publication Date: 2011-09-21
SHANDONG TIANXING BIOTECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the hydrogenation process of castor oil has an operating temperature of 100°C and a pressure of less than 1.5Mpa. The defects of this operating process are that the reaction time is long, 15-16 hours, the utilization rate of equipment is low, and the product quality is unstable. , its iodine value is sometimes as high as 30-40g / 100g, and the longer the reaction time, the hydroxyl value will decrease, and cause waste of production cost, high production cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] Pump the refined castor oil heated to 100°C into the hydrogenation reactor, vacuumize the reactor with vacuum equipment and heat it to 125°C, dehydrate the castor oil in the reactor, and then add nickel hydrogenation catalyst , the amount of catalyst added is 0.9‰ of the weight of castor oil, hydrogen is passed into the reactor, and the amount of hydrogen that is passed into is 65m per ton of castor oil 3 , the pressure in the reactor is 2Mpa, and the temperature is 130°C. After 7 hours of hydrogenation reaction, unreacted hydrogen is discharged, and then the catalyst in the hydrogenated castor oil is removed by filtration to obtain hydrogenated castor oil.

Embodiment 2

[0013] Pump the refined castor oil heated to 110°C into the hydrogenation reactor, vacuumize the reactor with vacuum equipment and heat it to 135°C, dehydrate the castor oil in the reactor, and then add nickel hydrogenation catalyst , the amount of catalyst added is 1.1‰ of the weight of castor oil, hydrogen is passed into the reactor, and the amount of hydrogen passed into is 80m per ton of castor oil 3 , the pressure in the reactor is 2.5Mpa, and the temperature is 150°C. After 5 hours of hydrogenation reaction, unreacted hydrogen is discharged, and then the catalyst in the hydrogenated castor oil is removed by filtration to obtain hydrogenated castor oil.

Embodiment 3

[0015] Add 9901 nickel hydrogenation catalyst in the reaction kettle with refined castor oil, the amount of catalyst added is 1.0‰ of castor oil weight, then feed hydrogen into the reaction kettle, the amount of hydrogen is 75m per ton of castor oil 3 , the pressure in the reactor is 2.3Mpa, and the temperature is 140°C. After 6 hours of hydrogenation reaction, unreacted hydrogen is discharged, and then filtered to remove the catalyst in the hydrogenated castor oil to obtain hydrogenated castor oil.

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Abstract

The invention belongs to the hydrogenation technology of castor oil, and more particularly relates to a high-temperature and high-pressure hydrogenation method of the castor oil. The high-temperature and high-pressure hydrogenation method of the castor oil adopts a high-temperature and high-pressure hydrogenation method with the reaction pressure of 2 to 2.5MPa and the temperature of 130 to 150 DEG C; the technique solves the problems in the prior operating technique, shortens the reaction time, with the whole acidolysis time being 7 to 8 hours, improves the utilization ratio of the equipment, and stabilizes and improves the product quality, with the iodine value of less than 3.0g / 100g. Meanwhile, the high-temperature and high-pressure hydrogenation method of the castor oil also greatly reduces the production cost, saves electricity and labor cost by 50 percent, halves the equipment depreciation and doubles the production efficiency.

Description

technical field [0001] The invention belongs to the hydrogenation technology of castor oil, in particular to a high-temperature and high-pressure hydrogenation method of castor oil. Background technique [0002] Castor oil is one of the world's top ten oil crops and one of the four major inedible oil crops. The oil content of castor bean is 46% to 55%, the oil content of the kernel can reach more than 70%, and the oil output per 100kg is 42 to 45kg. Castor oil is a non-drying oil, which does not solidify at -18°C, and does not deteriorate or burn at high temperatures of 500°C to 600°C. The main component of castor oil is glyceride of ricinoleic acid, which contains three ethylenic bonds, three ester bonds and three hydroxyl groups in its molecular structure. The functional groups in the molecular structure of castor oil determine that it can undergo various chemical reactions. Generate a variety of derivative products. [0003] Hydrogenated castor oil is one of the derivat...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C11C3/12
Inventor 怀进步
Owner SHANDONG TIANXING BIOTECH
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