Method for coal desulfurization catalyzed by microwave

A microwave catalysis and coal technology, which is applied in the field of coal desulfurization, can solve the problems of desulfurization technology that does not destroy the coal matrix structure, has no high desulfurization efficiency, and is limited in the scope of application, so as to improve the quality of coal and the scope of use, and achieve good promotion and application value. , the effect of improving utilization

Inactive Publication Date: 2008-08-27
NANJING UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The invention with the application number 97116584.X discloses a deep physical desulfurization method for coal. After the coal is crushed, it is separated by emulsification and high-shear stirring to obtain low-sulfur coal. However, only inorganic sulfur can be removed, and the desulfurization rate is not high. High problem; the application number is 03137590.1, which discloses a new process for reducing the sulfur content of coke and a corresponding series of sulfur removal agents, which is a method of using metal compounds to convert solid sulfur in coal into volatile sulfur compounds to achieve The purpose of the method, but there is still a method with a limited desulfurization rate; the application number is 200420002579.7, which introduces a microwave desulfurization and nitrogen removal device. Nitrogen removal, but this method must completely destroy the coal structure before it can be used, and its scope of application is relatively limited
[0005] Although the above technical solutions have made some progress in the desulfurization effect, there is currently no desulfurization technology that has a high desulfurization efficiency and does not damage the coal matrix structure, and there is generally a problem of high input costs

Method used

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  • Method for coal desulfurization catalyzed by microwave
  • Method for coal desulfurization catalyzed by microwave
  • Method for coal desulfurization catalyzed by microwave

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] After pulverizing 40 grams of raw coal (respectively Shandong Guohong coal powder, Shandong Xuecheng Shanjiacun fat coal, live chicken and rabbit coal) (particle size is less than 0.3mm); add to 60 grams of water and stir for 2 minutes to obtain a relatively uniform dispersion system; then Add 100 milliliters of 4 moles per liter of alkali solution (optional sodium hydroxide, potassium hydroxide) and transfer to a 250 milliliter Erlenmeyer flask, put it in a microwave oven for 6 minutes of microwave thermal desulfurization reaction, and carry out microwave radiation catalysis; take it out and use A small amount of water is washed and filtered, and the amount of water added is 20 milliliters each time, and washed until the filtrate pH value is less than 9. The filter cake is soaked with 5 moles per liter of hydrochloric acid for 5 minutes, heated and boiled for 15 minutes, then left to cool; finally filtered and dried. In this example, a microwave oven is used for microw...

Embodiment 2

[0030] Embodiment 2: heating condition experiment

[0031] According to the method described in Example 1, the difference is that one of them is heated by microwave for 6 minutes, and the other two experiments are heated in other ways, and the temperature of the system is kept at 80 and 90 ° C for 24 hours. Other treatment methods and reactions The conditions are the same.

[0032] Comparison of catalytic effects between microwave and other heating methods: (coal sample: fat coal from Shanjia Village, Xuecheng, Shandong)

[0033] means

Embodiment 3

[0034] Embodiment 3: microwave treatment time experiment

[0035] The treatment was carried out according to the method described in Example 1, except that the microwave treatment time was set to 2, 3, 4, 5, 6, 7, and 8 minutes respectively, and other treatment methods and reaction conditions were the same.

[0036] Comparison of microwave time effects: (Coal sample: Fat coal from Shanjia Village, Xuecheng, Shandong)

[0037] time / min

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Abstract

The invention discloses a coal desulfurization method which utilizes microwave to catalyze, which comprises the following steps: utilizing water to be dissolvent, leading coal and auxiliary agent mixture to form more even disperse system through physically stirring, and doing a thermal desulfurization reaction under the catalytic action of microwave. The method has the advantages that firstly, the method has excellent desulfurization efficiency under the premise without damaging coal quality structure, secondly, the method has high reaction efficiency and excellent statute of limitation, thirdly, the method has simple operation, whose auxiliary agent is easy to get, and the method has wide popularization using value.

Description

technical field [0001] The invention relates to a coal desulfurization method, in particular to a coal desulfurization method utilizing microwave catalysis. Background technique [0002] With the rapid development of the international economy, energy and environmental issues have become increasingly prominent. On the one hand, the high consumption of energy has brought high demand for resources, but at the same time, a large amount of resources in the world are wasted due to quality problems, and the energy shortage is imminent; on the other hand, the massive use of energy has caused the deterioration of environmental problems, While seriously affecting economic development, it also greatly threatens the living environment of human beings. The above problems are clearly reflected in coal, an important energy resource in my country. In China, due to the excessive emission of sulfur dioxide to the atmosphere due to the massive combustion of coal, my country's total sulfur di...

Claims

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Application Information

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IPC IPC(8): C10L9/02
Inventor 胡柏星何其慧蔡军傅家伟施源
Owner NANJING UNIV
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