Image forming apparatus, image forming method and process cartridge
An image and developing device technology, applied in the direction of corona discharge device, electric recording process using charge pattern, electric recording process using charge pattern, etc. Sexual variation and other issues
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[0611] Hereinafter, examples of the present invention will be described, but the present invention is not limited by the following examples.
[0612] In the following examples and comparative examples, "softening point of polyester resin", "glass transition temperature (Tg) of polyester resin", "softening point of rosin", "acid value of polyester resin and rosin" , "hydroxyl value of polyester resin", "content of low molecular weight components with a molecular weight of 500 or less", "SP value of rosin" and "degree of modification of (meth)acrylic acid of rosin" were measured by the following methods.
[0613]
[0614] Using a flow tester (manufactured by Shimadzu Corporation, CFT-500D), 1 g of each polyester-based adhesive resin as a sample was heated at a temperature increase rate of 6° C. / min, and a load of 1.96 MPa was applied from a plunger at the same time. Extrude it from a nozzle with a diameter of 1mm and a length of 1mm, make a curve of the plunger drop of...
Synthetic example 1
[0644] -Refinement of Rosin-
[0645] Add 1,000g of tall oil rosin to a 2,000mL distillation flask equipped with a fractionating tube, reflux condenser, and receiving vessel, and carry out distillation under a reduced pressure of 1kPa, collecting distilled components at 195°C to 250°C as the main fraction . Hereinafter, tall oil rosin used for purification is referred to as unrefined rosin, and rosin collected as a main fraction is referred to as refined rosin.
[0646] Using a coffee grinder (National MK-61M), each 20 g of rosin was pulverized for 5 seconds, and 0.5 g of what passed through a 1 mm sieve was metered into a vial (20 mL) for headspace. Headspace gas was sampled, and impurities in unrefined rosin and refined rosin were analyzed by headspace GC-MS in the following manner. The results are shown in Table 1A.
[0647]
[0648] A. Headspace sampler (manufactured by Agilent, HP7694)
[0649] ·Sample temperature: 200℃
[0650] ·Ring temperature: 200...
Synthetic example 2
[0680] -Synthesis of Acrylic Modified Rosin A-
[0681] 6084g (18mol) of refined rosin (SP value: 76.8°C) and 907.9g (12.6mol) of acrylic acid were added to a 10L volumetric flask equipped with a fractionation tube, a reflux condenser and a receiving vessel, and within 8 hours the temperature was reduced from Raise the temperature from 160°C to 220°C, react at 220°C for 2 hours, and then distill under a reduced pressure of 5.3kPa to obtain acrylic acid-modified rosin A. The SP value of the obtained acrylic-modified rosin A was 110.4° C., and the degree of acrylic modification was 100.
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