Method for removing sulfamethazine by using iron-manganese bimetal organic framework/modified reduced graphene oxide composite material

A technology of sulfamethazine and organic framework, which is applied in the field of water treatment, can solve the problems of poor treatment effect and long reaction time, and achieve efficient removal effect

Pending Publication Date: 2022-07-22
HUNAN UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

At the same time, in the actual research process of the inventors of the present application, it is also found that if the iron-manganese bimetallic organic framework is directly loaded on the reduced graphite oxide, the resulting composite material is still difficult to efficiently activate peroxodisulfate, so it is difficult to quickly and effectively The degradation of sulfamethazine in wastewater still has defects such as long reaction time and poor treatment effect, resulting in the iron-manganese bimetallic organic framework / reduced graphene oxide composite material still cannot be widely used to activate peroxodisulfate to achieve Effective Degradation of Sulfamethazine Wastewater

Method used

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  • Method for removing sulfamethazine by using iron-manganese bimetal organic framework/modified reduced graphene oxide composite material
  • Method for removing sulfamethazine by using iron-manganese bimetal organic framework/modified reduced graphene oxide composite material
  • Method for removing sulfamethazine by using iron-manganese bimetal organic framework/modified reduced graphene oxide composite material

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Embodiment 1

[0036] A method for removing sulfamethazine using iron-manganese bimetallic organic framework / modified reduced graphene oxide composite material, specifically utilizing iron-manganese bimetallic organic framework / modified reduced graphene oxide composite material to activate peroxodisulfate The sulfamethazine solution is degraded, and this example mainly investigates the influence of different modified reduced graphene oxide contents on the catalytic performance of the composite material, including the following steps:

[0037] According to the addition amount of 50 mg / L iron-manganese bimetallic organic framework / modified reduced graphene oxide composites (BOF@S-rGO(2%), BOF@N-rGO(2%), BOF@S-rGO, BOF @N-rGO, BOF@S-rGO (6%), BOF@N-rGO (6%), BOF@S-rGO (10%), BOF@N-rGO (10%)) and 0.1mM Sodium sulfate (Na 2 S 2 O 8 ), were respectively added to the sulfamethazine water body with an initial pH value of 5.54 and an initial concentration of 18 μM, and the obtained reaction system...

Embodiment 2

[0057] A method for removing sulfamethazine using iron-manganese bimetallic organic framework / modified reduced graphene oxide composite material, specifically utilizing iron-manganese bimetallic organic framework / modified reduced graphene oxide composite material to activate peroxodisulfate The degradation treatment of the sulfamethazine solution includes the following steps:

[0058] The iron-manganese bimetallic organic framework / modified reduced graphene oxide composites (BOF@S-rGO, BOF@N-rGO) prepared in Example 1 according to the addition amount of 75mg / L and 0.05mM sodium peroxodisulfate (Na 2 S 2 O 8 ), were respectively added to the sulfamethazine water body with an initial pH value of 5.54 and an initial concentration of 10 μM, and the obtained reaction system was placed in a constant temperature shaker for vibration treatment, wherein the temperature of the constant temperature vibration treatment was 25 ° C, and the rotating speed was 250 rpm, The reaction time wa...

Embodiment 3

[0071] A method for removing sulfamethazine using iron-manganese bimetallic organic framework / modified reduced graphene oxide composite material, specifically utilizing iron-manganese bimetallic organic framework / modified reduced graphene oxide composite material to activate peroxodisulfate The degradation treatment of sulfamethazine solution (BOF@S-rGO / PDS, BOF@N-rGO / PDS) includes the following steps:

[0072] The iron-manganese bimetallic organic framework / modified reduced graphene oxide composites (BOF@S-rGO, BOF@N-rGO) prepared in Example 1 according to the addition amount of 75mg / L and 0.05mM sodium peroxodisulfate (Na 2 S 2 O 8 ), were respectively added to the sulfamethazine water body with an initial pH value of 5.54 and an initial concentration of 10 μM, and the obtained reaction system was placed in a constant temperature shaker for vibration treatment, wherein the temperature of the constant temperature vibration treatment was 25 ° C, and the rotating speed was 250...

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Abstract

The invention discloses a method for removing sulfadimidine by using an iron-manganese bimetal organic framework/modified reduced graphene oxide composite material, which is characterized in that the iron-manganese bimetal organic framework/modified reduced graphene oxide composite material is used for activating peroxydisulfate to degrade sulfadimidine wastewater. Wherein the iron-manganese bimetal organic framework/modified reduced graphene oxide composite material comprises an iron-manganese bimetal organic framework, modified reduced graphene oxide is loaded on the iron-manganese bimetal organic framework, and the modified reduced graphene oxide is sulfur-doped reduced graphene oxide or nitrogen-doped reduced graphene oxide. The method has the advantages of being simple in process, short in reaction time, small in oxidant adding amount, good in removal effect, wide in pH application range, environmentally friendly, free of secondary pollution and the like, sulfamethazine in the wastewater can be effectively removed, and the method has high use value and good application prospects.

Description

technical field [0001] The invention belongs to the technical field of water treatment, and in particular relates to a method for removing sulfamethazine by utilizing an iron-manganese bimetallic organic framework / modified reduced graphene oxide composite material. Background technique [0002] In the past century, a large number of antibiotics have been discovered, synthesized and used in clinical due to their excellent bacteriostatic and bactericidal effects. Among them, sulfamethazine (SMT) is a major sulfonamide antibiotic with functional Mission-SO 2 NH 2 -, commonly used to control infectious diseases and promote animal growth. About 90% of SMT is excreted into the environment in the form of animal feces because the drug cannot be completely absorbed by the animal's stomach. With the use of SMT, the SMT contained in the environment is increasing, which will cause the following hazards: poisoning aquatic organisms, interfering with human endocrine, increasing the ris...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/72B01J31/22B01J37/10C02F101/38C02F101/34
CPCC02F1/722C02F1/725B01J31/1691B01J31/2239B01J37/10B01J2531/72B01J2531/842C02F2101/40C02F2101/38C02F2101/34C02F2305/023
Inventor 楚东东董浩然李杨菊肖钧洋侯秀珍相淑雪董琪霞
Owner HUNAN UNIV
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