Optical film and display device comprising same
A display device and optical film technology, which is applied in optics, optical elements, nonlinear optics, etc., and can solve the problems of poor viewing angle characteristics of optical films
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[0433] Hereinafter, the specification will be described in detail with reference to examples. However, the embodiments according to the present specification can be modified into various other forms, and the scope of the present specification should not be construed as being limited to the embodiments described below. The examples of this specification are provided to more fully describe this specification to those of ordinary skill in the art.
[0434] Examples and Comparative Examples
[0435] As the binder resin, AD-701 (LG Chem.) (solid content 15.5%) was used, and a certain amount of dye was dissolved in methyl ethyl ketone (MEK) so that the amount of dye or pigment became relative to The solid content of 100 parts by weight of the binder resin is 0.2 to 1.5 parts by weight, and as a result, a composition for forming an optical film is prepared. Specific types and amounts of dyes or pigments are described in Table 1 below.
[0436] Binder resin AD-701 (LG Chem.) accord...
preparation example
[0443]
[0444]
[0445] Synthesis of compound 1_1
[0446] Benzaldehyde (20.0 g) was introduced into the pyrrole solvent and stirred well. Thereto was slowly introduced trifluoroacetic acid (0.10 eq.). After confirming the completion of the reaction, the resultant was extracted with dichloromethane and aqueous sodium bicarbonate solution. The extracted organic layer was dried with sodium sulfate, and then a silica gel column was used to obtain purified and isolated compound 1_1 (15.5 g, yield 37.0%).
[0447] Synthesis of compound 1_2
[0448] Compound 1_1 (15.5 g) was well stirred and dissolved in tetrahydrofuran solvent. The reaction solution was cooled to -78°C using dry ice and acetone, and N-bromosuccinimide (NBS) (2.0 equivalents) was slowly introduced thereto in a solid state while maintaining the temperature. Upon completion of the reaction, the reaction solution was cooled to 0° C. using ice water, and then 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) (...
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