Host material and organic electroluminescent device comprising same
A main material and luminescent technology, which is applied in the manufacture of electric solid devices, semiconductor devices, semiconductor/solid state devices, etc., can solve the problems of lack of materials and achieve high luminous efficiency
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Embodiment 1
[0097] Embodiment 1: the synthesis of compound 1-18
[0098] (1) Synthesis of intermediate 1-1-2
[0099]
[0100] Compound 1-18-2 (7.9g, 23.7mmol), 1-18-1 (6.53g, 21.6mmol), tetrakis (triphenylphosphine) palladium (1.2g, 1.0mmol), potassium carbonate (7.5g, 59 mmol), 90 mL of toluene, 30 mL of ethanol, and 30 mL of distilled water were added to the reaction vessel, and the reaction was stirred at 120° C. for 4 hours. After the reaction was complete, methanol was added dropwise to the mixture, and the resulting solid was filtered. The resulting solid was recrystallized and purified by column chromatography to obtain compound 1-18-3 (5.4 g, yield: 53%). LC-MS: M / Z 469.13 (M + ).
[0101] (2) Synthesis of Compound 1-18
[0102] Compound A (10.1g, 23.7mmol), 1-18-3 (10.2g, 21.6mmol), tetrakis (triphenylphosphine) palladium (1.2g, 1.0mmol), potassium carbonate (7.5g, 59mmol), 90mL Toluene, 30 mL of ethanol, and 30 mL of distilled water were added to the reaction vessel, a...
Embodiment 2
[0103] Embodiment 2: the synthesis of compound 1-39
[0104]
[0105] Compound 1-39 was synthesized with reference to the method of Example 1, and the synthesis of compound 1-18 was referred to for other steps to obtain compound 1-39 (8.9 g, yield: 67%). LC-MS: M / Z616.19 (M + ).
Embodiment 3
[0106] Embodiment 3: the synthesis of compound 2-83
[0107]
[0108] Compound 2-83 was synthesized with reference to the method of Example 1, and the synthesis of compound 1-18 was referred to for other steps to obtain compound 2-83 (11.1 g, yield: 63%). LC-MS: M / Z817.28 (M + ).
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