Heat-sensitive material, electrode and preparation method thereof, and lithium secondary battery
A heat-sensitive material and electrode technology, applied in secondary batteries, secondary battery repair/maintenance, battery electrodes, etc., can solve problems such as thermal runaway, eliminate the possibility of fire or even explosion, improve safety performance, The effect of broad application prospects
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[0047] The embodiment of the present invention also provides a method for preparing an electrode, which includes the following steps:
[0048] S1. Provide heat-sensitive materials, organic solvents and binders. The heat-sensitive materials are the heat-sensitive materials provided by the embodiments of the present invention;
[0049] S2. Mixing the heat-sensitive material with an organic solvent and a binder to obtain a slurry;
[0050] S3. Providing an electrode base, the electrode base includes a current collector and an active layer laminated on the surface of the current collector, coating the slurry on the surface of the electrode base, and drying to obtain an electrode.
[0051] Specifically, in S1, the heat-sensitive material is the heat-sensitive material provided by the embodiment of the present invention, which may only contain polythiophene or its derivatives, or may additionally be added with a conductive agent and / or a lithium source. The content and specific sel...
Embodiment 1
[0063] This embodiment provides a method for preparing a heat-sensitive material and a lithium secondary battery, the steps are as follows:
[0064] (11) Mix poly-3-decylthiophene, Super P and lithium oxide according to a mass ratio of 90:7:3 to obtain a thermosensitive material;
[0065] (12) Mix and stir the heat-sensitive material obtained in step (11) with N-methylpyrrolidone and polyvinylidene fluoride, and the mass ratio of heat-sensitive material to N-methylpyrrolidone and polyvinylidene fluoride is 70:29:1 , get slurry;
[0066] (13) Provide a positive electrode substrate, the positive electrode substrate is a conventional positive electrode sheet in the field, apply the slurry obtained in step (12) on the front and back of the positive electrode sheet, and dry at 50 ° C to form a thickness of 1μm heat-sensitive material layer to obtain positive electrode;
[0067] (14) Assemble the positive electrode obtained in step (13) with a conventional negative electrode, sepa...
Embodiment 2
[0069] This embodiment is basically the same as Embodiment 1, except that the thickness of the heat-sensitive material layer formed is 3 μm.
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