Hair dye containing plant polyphenol functional material
A technology of functional materials and plant polyphenols, applied in medical preparations containing active ingredients, hair care, cosmetics, etc., to achieve strong adhesion, improve hair dyeing efficiency, and the effect of hair dyeing is stable and washable
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[0040] Preferably, the preparation method of gallic acid functionalized POSS nanoparticles protected by acetone at the mercapto end comprises:
[0041] Step 1, mixing mercapto-terminated acetone, phosphorus trichloride, and gallic acid, stirring in an ice-water bath for 5-8 hours to obtain acetone-protected gallic acid;
[0042] Step 2, reacting the product of the previous step with 2-aminoethanethiol under the action of a catalyst to obtain a gallic acid functionalized monomer protected by acetone at the mercapto end;
[0043] Step 3, reacting the gallic acid functionalized monomer protected by mercapto end acetone with POSS, and removing the mercapto end acetone protection;
[0044] Step 4, adding catalyst and tetrahydrofuran to the product of the previous step to form a polymerization system, and reacting in an inert gas for 10-12 hours after stirring to obtain target nanoparticles.
[0045] Preferably, the catalyst in step 2 is potassium iodide; in step 3, the gallic acid...
Embodiment 1
[0061] A hair dye containing plant polyphenol functional material, comprising agent A and agent B, the mass ratio of agent A and agent B is 1:1;
[0062] Agent A consists of the following: 5,6-dihydroxyindole 1%, oleic acid 6%, cetearyl alcohol 6%, hydroxypropyl methylcellulose 1.2%, propylene glycol 6%, isopropanol 6%, 1% sodium dodecylsulfonate, 5% gallic acid functionalized POSS nanoparticles protected by thiol-terminated acetone, 5% agar, 0.24% NaOH, the balance of deionized water, the total mass percentage of each component is 100%;
[0063] Agent B is composed of the following: 18% hydrogen peroxide, 8% oleyl alcohol, 8% propylene glycol, 8% isopropanol, 1% sodium dodecylsulfonate, 1% phosphoric acid, the balance of deionized water, each component The mass percentages add up to 100%;
[0064] The raw materials of gallic acid functionalized POSS nanoparticles protected by mercapto acetone include: 600 parts by weight of mercapto acetone, 20 parts by weight of phosphorus ...
Embodiment 2
[0066] A hair dye containing plant polyphenol functional material, comprising agent A and agent B, the mass ratio of agent A and agent B is 1:1;
[0067] Agent A consists of the following: 5,6-dihydroxyindole 5%, oleic acid 8%, cetearyl alcohol 8%, hydroxypropyl methylcellulose 1.4%, propylene glycol 9%, isopropanol 9%, 3% sodium dodecylsulfonate, 10% gallic acid functionalized POSS nanoparticles protected by mercapto acetone, 7% agar, 2% NaOH, the balance of deionized water, the total mass percentage of each component is 100%;
[0068] Agent B is composed of the following: 22% hydrogen peroxide, 12% oleic acid, 12% propylene glycol, 12% isopropanol, 3% sodium dodecylsulfonate, 3% phosphoric acid, the balance of deionized water, each component The mass percentages add up to 100%;
[0069] The raw materials of gallic acid functionalized POSS nanoparticles protected by mercapto acetone include: 600 parts by weight of mercapto acetone, 20 parts by weight of phosphorus trichlorid...
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