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Preparation method of Si substrate AlN template and preparation method of Si substrate GaN epitaxial structure

An epitaxial structure and substrate technology, which is applied in semiconductor/solid-state device manufacturing, electrical components, circuits, etc., can solve problems such as limited implantation depth, impact on device performance, and unproposed problems, achieving reduced radio frequency loss, multiple degrees of freedom, Improve the effect of characteristics

Active Publication Date: 2020-09-08
XIDIAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This patent does not propose to deal with the background carrier concentration in the III-nitride material, and the background carrier concentration in the III-nitride material is also an important part of the electromagnetic loss of the GaN device on the Si substrate.
Moreover, ion implantation is performed after the epitaxial growth of the AlGaN transition layer. Because the nitride layer is too thick, if the relative atomic mass of the implanted ions is greater than 5, the implantation depth is limited, so that it cannot be implanted at the AlN / Si interface. Therefore It is necessary to limit the implanted ion species to elements with a relative atomic weight less than 5, which reduces the number and selection of implanted ion species, and the ion implantation is performed after the epitaxial growth of the AlGaN transition layer, and the surface of the material will adsorb impurity ions. When continuing to epitaxially grow the GaN buffer layer and the subsequent device heterojunction structure, impurity ions will diffuse into the GaN buffer layer and device heterojunction structure, thereby affecting the performance of the device

Method used

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  • Preparation method of Si substrate AlN template and preparation method of Si substrate GaN epitaxial structure
  • Preparation method of Si substrate AlN template and preparation method of Si substrate GaN epitaxial structure
  • Preparation method of Si substrate AlN template and preparation method of Si substrate GaN epitaxial structure

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Embodiment 1

[0035] See figure 1 , Figure 2a-Figure 2c , figure 1 It is a schematic flow diagram of a method for preparing an AlN template on a Si substrate provided in an embodiment of the present invention; Figure 2a-Figure 2c It is a process schematic diagram of a method for preparing an AlN template on a Si substrate provided by an embodiment of the present invention. This embodiment provides a method for preparing an AlN template on a Si substrate. The method for preparing an AlN template on a Si substrate includes steps 1 to 3, wherein:

[0036] Step 1, such as Figure 2a As shown, the Si substrate 10 is selected.

[0037] Preferably, the resistivity of Si substrate 10 is 0.01-10000 Ω·cm.

[0038] Preferably, the crystal orientation of the Si substrate 10 is (111) crystal orientation.

[0039] Preferably, the thickness of the Si substrate 10 is 100-1500 μm, and the thickness of the Si substrate 10 is 100-1500 μm, which can ensure its heat dissipation effect. When the thickness ...

Embodiment 2

[0053] The present invention provides a specific preparation method of an Si substrate AlN template on the basis of the foregoing embodiments, and the specific preparation method of the Si substrate AlN template includes:

[0054] Step 1, such as Figure 2a As shown, the Si substrate 10 is selected.

[0055] Specifically, the Si substrate 1 has a thickness of 675 μm, a resistivity of 5000 Ω·cm, and a crystal orientation of (111).

[0056] Step 2, such as Figure 2b As shown, an AlN nucleation layer 20 is grown on a Si substrate 10 .

[0057] Specifically, a 200 nm AlN nucleation layer 20 is epitaxially grown on the selected Si substrate 10 by MOCVD.

[0058] Step 3, if Figure 2c As shown, ions are implanted into the Si substrate 10 through the AlN nucleation layer 20 .

[0059] Specifically, the Si substrate 10 on which the AlN nucleation layer 20 has been deposited is ion-implanted, the implanted ions are Ar, and the implanted dose is 1×10 14 cm -2 , the implanted ene...

Embodiment 3

[0061] The present invention provides another specific preparation method of an Si substrate AlN template on the basis of the above-mentioned embodiments, and the specific preparation method of the Si substrate AlN template includes:

[0062] Step 1, such as Figure 2a As shown, the Si substrate 10 is selected.

[0063] Specifically, the Si substrate 1 has a thickness of 675 μm, a resistivity of 5000 Ω·cm, and a crystal orientation of (111).

[0064] Step 2, such as Figure 2b As shown, an AlN nucleation layer 20 is grown on a Si substrate 10 .

[0065] Specifically, a 200 nm AlN nucleation layer 20 is epitaxially grown on the selected Si substrate 10 by MOCVD.

[0066] Step 3, if Figure 2c As shown, ions are implanted into the Si substrate 10 through the AlN nucleation layer 20 .

[0067] Specifically, the Si substrate 10 on which the AlN nucleation layer 20 has been deposited is ion-implanted, the implanted ions are N, and the implanted dose is 1×10 15 cm -2 , the in...

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Abstract

The invention discloses a preparation method of a Si substrate AlN template and a preparation method of a Si substrate GaN epitaxial structure. The preparation method of the Si substrate AlN templatecomprises the following steps: selecting a Si substrate; growing an AlN nucleating layer on the Si substrate; and injecting ions into the Si substrate through the AlN nucleating layer. After the AlN nucleating layer is prepared on the Si substrate, ion implantation on the Si substrate and injecting ions into the AlN nucleating layer are performed through the AlN nucleating layer, so that the typesof the ions injected in the mode can be expanded, the carrier concentration at the Si / AlN interface and the carrier concentration in the AlN nucleating layer can also be reduced, the radio frequencyloss of the Si substrate AlN template is reduced, the characteristics of a GaN microwave device manufactured by using the Si substrate AlN template are improved, and the application requirements of the GaN microwave device in the fields of aerospace, radar, mobile communication and the like are met. In addition, a GaN device epitaxial structure is prepared by using the Si substrate AlN template, and the design of the GaN device epitaxial structure has more degrees of freedom.

Description

technical field [0001] The invention belongs to the technical field of semiconductors, and in particular relates to a method for preparing an AlN template on a Si substrate and a method for preparing a GaN epitaxial structure on an Si substrate. Background technique [0002] The third-generation semiconductor material GaN has the advantages of wide band gap, high critical breakdown field strength, high electron mobility, and high saturation electron drift velocity. It has great development potential in the field of microwave and millimeter wave high-power electronic devices and can be widely used. In aerospace, radar, 5G communication and other fields. There are two types of GaN epitaxial wafers: homoepitaxy and heteroepitaxy. Due to the high cost of GaN homoepitaxy, the commonly used technology is heteroepitaxy. Commonly used substrates for GaN heteroepitaxy include sapphire, SiC and Si, etc. Compared with other substrates, Si substrates have larger size, lower cost and ar...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L21/02
CPCH01L21/02381H01L21/02458H01L21/0254H01L21/02664H01L21/02505H01L21/02002Y02P70/50H01L21/02271
Inventor 刘志宏刘俊伟张进成郝璐宋昆璐周弘赵胜雷张雅超张苇杭郝跃
Owner XIDIAN UNIV
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