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A kind of high-performance structural adhesive and its preparation method and construction method

A structural adhesive and high-performance technology, applied in the field of bridge structural adhesives, can solve the problems of low weather resistance and durability of structural adhesives, weak waterproof and anti-corrosion performance of structural adhesives, degradation of structural adhesive performance, etc., to improve dispersion and overall Good resistance, weather resistance and durability, and the effect of improving the compressive and tensile strength

Active Publication Date: 2022-02-15
GUANGXI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] For structural adhesives used as a connecting agent between the reinforcement material and the reinforced structure, there are mainly the following problems: (1) The mechanical properties of structural adhesives are not high, especially the bonding performance
According to the actual engineering research, in the current strengthening methods such as pasting carbon fiber cloth, pasting carbon fiber plate, pasting prestressed carbon fiber plate and pasting steel plate, before the mechanical properties of the reinforced material are fully exerted, the reinforcement system is due to the failure of the structural adhesive. damage, resulting in a great waste of reinforcement material strength
(2) The weather resistance and durability of structural adhesives are not high
According to the actual engineering research, in the pasting method of structural adhesive reinforcement projects, due to static and dynamic loads and external environmental factors, the service life and performance of structural adhesives are far from the designed service life, resulting in early maintenance of the reinforcement system and replacement, the construction is troublesome, the cost is high, and the impact on the structure is relatively large
(3) There are many air bubbles in the structural adhesive, and it is not easy to discharge
Bubbles in the structural adhesive will reduce the mechanical properties and durability of the structural adhesive, weaken the reinforcement effect, provide a channel for external corrosive environmental factors to enter the structure, and threaten the safety and durability of the structure
(4) The waterproof and anti-corrosion performance of the structural adhesive is weak, and it cannot provide effective protection for the steel bars inside the structure
Since the working environment of the structural adhesive is usually in the wild, it is greatly affected by external factors such as ultraviolet rays, rain and snow. The weak waterproof and anti-corrosion performance of the structural adhesive will cause the performance of the structural adhesive to degrade or even fail, and at least affect the durability of the reinforced structure and the reinforced system. security, and seriously threaten the security of the structure
(5) The fluidity of the structural adhesive is poor, and the on-site configuration and construction of the structural adhesive are troublesome
At present, the production of structural adhesives commonly used in the market needs to go through multiple technological processes, which consumes high time, material, labor and material costs.
The poor fluidity of structural adhesives also increases the difficulty of making and constructing structural adhesives
[0004] For structural adhesives used as sealing materials, there are mainly the following problems: (1) The mechanical properties of structural adhesives are not high, especially the bonding performance
(2) The weather resistance and durability of structural adhesives are not high
According to the actual engineering research, in the reinforcement project using structural adhesive as the sealing material, due to the effect of static and dynamic loads and the influence of external environmental factors, the service life and performance of the structural adhesive are far from the designed service life, resulting in the advance of the reinforcement system. Maintenance and replacement, troublesome construction, high cost, and relatively large impact on the structure
In structures where structural adhesives are often used as sealing materials, the closed parts often crack again shortly after reinforcement, causing external corrosion factors to enter the structure, threatening the safety and durability of the structure
(3) There are many air bubbles in the structural adhesive, and it is not easy to discharge
Bubbles in the structural adhesive will reduce the mechanical properties and durability of the structural adhesive, weaken the reinforcement effect, provide a channel for external corrosive environmental factors to enter the structure, and threaten the safety and durability of the structure
(4) The waterproof and anti-corrosion performance of the structural adhesive is weak, and it cannot provide effective protection for the steel bars inside the structure
Since the working environment of the structural adhesive is usually in the wild, it is greatly affected by external factors such as ultraviolet rays, rain and snow. The weak waterproof and anti-corrosion performance of the structural adhesive will cause the performance of the structural adhesive to degrade or even fail, and at least affect the durability of the reinforced structure and the reinforced system. security, and seriously threaten the security of the structure
(5) The fluidity of the structural adhesive is poor, and the on-site configuration and construction of the structural adhesive are troublesome
At present, the production of structural adhesives commonly used in the market needs to go through multiple technological processes, which consumes high time, material, labor and material costs.
The poor fluidity of the structural adhesive will lead to incomplete sealing of micro cracks, which will affect the reinforcement effect and increase the difficulty of the production and construction of the structural adhesive

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The weighing raw materials are 100 parts of E-44 epoxy resin, 40 parts of 5000 mesh silicon powder, 10 parts of nano calcium carbonate, 3 parts of micron carbon fiber and 5 parts of sodium water glass with a density of 1.44g / cm³ and a density of 1.44g / cm³ The mixed solution of sodium silicate and potassium silicate prepared by 5 parts of potassium silicate in cm³ is put into the mixer container in sequence and mixed into a colloid, and stirred at a constant temperature at a speed of 1000 rpm until uniformly dispersed, so that the mixer The colloid in the container became viscous, and it was placed in a closed container to vacuumize and degas the air for 5 minutes to prepare the A mixture.

[0027]The weighing raw materials are 30 parts of aromatic amine, 20 parts of polyamide, 20 parts of 5000-mesh silicon micropowder and 1 part of carbon fiber, and put them into another stirrer container in order to mix them, and stir them at a constant temperature at 400 rpm. To light...

Embodiment 2

[0029] The weighing raw materials are 100 parts of E-44 epoxy resin, 40 parts of 5000 mesh silicon powder, 20 parts of nano calcium carbonate, 4 parts of micron carbon fiber and 10 parts of sodium water glass with a density of 1.44g / cm³ and a density of 1.44g / cm³ The mixed solution of sodium silicate and potassium silicate prepared by 10 parts of potassium water glass in cm³. Put them into the mixer container in order to mix into a colloid, stir at a constant temperature of 1000 rpm until uniformly dispersed, make the colloid in the mixer container viscous, and place it in a closed container to vacuumize and debubble for 5 minutes A mixture was prepared.

[0030] The weighing raw materials are 30 parts of aromatic amine, 20 parts of polyamide, 20 parts of 5000-mesh silicon micropowder, and 2 parts of micron carbon fiber. Put them into another agitator container in sequence, and stir at 400 rpm at constant temperature until slightly yellow and viscous. Thick, placed in a close...

Embodiment 3

[0032] The weighing raw materials are 100 parts of E-44 epoxy resin, 80 parts of 5000 mesh silicon powder, 30 parts of nano-calcium carbonate, 3 parts of carbon fiber and 10 parts of sodium water glass with a density of 1.44g / cm³ and a density of 1.44g / cm³ The mixed solution of sodium silicate and potassium silicate prepared by 10 parts of potassium water glass in cm³. Put them into the mixer container in order to mix into a colloid, and stir at a constant temperature at a speed of 1000 rpm until the dispersion is uniform, so that the colloid in the stirring container becomes viscous, and put it in a closed container to vacuumize and debubble for 5 minutes. A mixture is obtained.

[0033] The weighing raw materials are 30 parts of aromatic amine, 20 parts of polyamide, 40 parts of 5000-mesh silicon micropowder and 1 part of carbon fiber, put them into another stirring container in sequence, and stir at 400 rpm at constant temperature until slightly yellow and viscous Shape, p...

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Abstract

The high-performance structural adhesive of the present invention and its preparation method and construction method, by mixing and stirring 100 components of E-44 epoxy resin, 5-30 components of potassium silicate and sodium silicate mixed solution, and 20-180 components of silicon micropowder , nano calcium carbonate 5-30 component, micron carbon fiber 1-4 component to prepare A mixture, by mixing and stirring the polyamide 20 component, the aromatic amine 30 component, the silicon micropowder 20-60 component and the micron carbon fiber 1-2 Components make a B mixture. Take the A mixture and the B mixture with a mass ratio of 2:1, stir and place them in a closed container to vacuum and de-air bubbles to obtain a high-performance structural adhesive. The high-performance structural adhesive has high bonding strength, weather resistance and durability. , The structural adhesive has the advantages of less air bubbles, excellent waterproof and anti-corrosion effects, strong fluidity, green environmental protection, and convenient construction. It has a good market prospect and is suitable for promotion.

Description

technical field [0001] The invention relates to the technical field of bridge structural adhesives, in particular to a high-performance structural adhesive and its preparation method and construction method. Background technique [0002] Bridges are the key nodes of the transportation network and play a vital role in ensuring the efficient operation of traffic. Concrete bridges occupy an important position and a considerable proportion of bridges in our country. During the operation period of concrete bridges, under the influence of factors such as load and external environment, bridges will suffer from diseases, among which cracks are typical and common, which will not only change the stress distribution of the structure, but also cause external corrosion factors to enter the bridge structure It will exacerbate the deterioration of materials and threaten the safety and durability of bridges. According to the cause and development degree of cracks, the treatment methods ma...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J163/00C09J177/00C09J11/04C08G59/50E01D22/00
CPCC09J163/00C09J11/04C08G59/5033E01D22/00C08K2201/011C08K2003/265C08L77/00C08K13/04C08K7/06C08K3/34C08K3/36C08K3/26
Inventor 谢开仲何俊泓王红伟
Owner GUANGXI UNIV
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