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Modified high ignition point transformer oil and preparation method thereof

A transformer oil, high ignition point technology, applied in the petroleum industry, lubricating composition, etc., can solve the problems of inability to form a wide range of applications, high cost, insulating oil cooling performance, insulation and other performance and oxidation resistance can not meet the requirements, and achieve important Practical significance and commercial value, strong fire performance and low price

Active Publication Date: 2022-06-21
STATE GRID HUNAN ELECTRIC POWER +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In order to solve the above problems, some scholars have successively developed polychlorinated biphenyl (PCB)-based insulating oil, silicone oil, synthetic ester (pentaerythritol ester), alpha oil, beta oil, polyalphaolefin, HMWH oil (polymer carbon Hydrogenated oil), vegetable insulating oil and other non-flammable or non-fuel products, but because these insulating oils either cannot meet the requirements of cooling performance, insulation performance and oxidation resistance, etc., or are high in cost, and need to be used at present. Transformation of mineral insulating oil transformers, otherwise there is a great risk, so it is impossible to form a wide range of applications

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A modified high ignition point transformer oil of the present invention comprises the following components by mass fraction: 91% mineral insulating oil, 8% modified nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant, 1% liquid flame retardant agent toluene diphenyl phosphate. Among them, the modified nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant is prepared by modifying the surfactant oleic acid.

[0026] The mass fraction of nano-magnesium hydroxide and nano-aluminum hydroxide is 100%, the mass fraction of nano-magnesium hydroxide is 70%, and the mass fraction of nano-aluminum hydroxide is 30%.

[0027] In the nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant of this embodiment, the particle size of the nano-magnesium hydroxide is in the range of 20 nm to 50 nm, and the particle size of the nano aluminum hydroxide is in the range of 30 nm to 60 nm.

[0028] In this embodiment, the mineral in...

Embodiment 2

[0035] A modified high ignition point transformer oil of the present invention comprises the following components by mass fraction: 93% mineral insulating oil, 6.5% modified nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant, 0.5% toluene diphenyl phosphate ester. Among them, the modified nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant is prepared by modifying the surfactant oleic acid.

[0036] The mass fraction of nano-magnesium hydroxide and nano-aluminum hydroxide is 100%, the mass fraction of nano-magnesium hydroxide is 80%, and the mass fraction of nano-aluminum hydroxide is 20%.

[0037] In the nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant of this embodiment, the particle size of the nano-magnesium hydroxide is in the range of 20 nm to 50 nm, and the particle size of the nano aluminum hydroxide is in the range of 30 nm to 60 nm.

[0038] In this embodiment, the mineral insulating oil is nap...

Embodiment 3

[0045] A modified high ignition point transformer oil of the present invention comprises the following components by mass fraction: 92% mineral insulating oil, 7% modified nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant, 1% toluene diphenyl phosphate ester. Among them, the modified nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant is prepared by modifying the surfactant oleic acid.

[0046] The mass fraction of nano-magnesium hydroxide and nano-aluminum hydroxide is 100%, the mass fraction of nano-magnesium hydroxide is 70%, and the mass fraction of nano-aluminum hydroxide is 30%.

[0047] In the nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant of this embodiment, the particle size of the nano-magnesium hydroxide is in the range of 20 nm to 50 nm, and the particle size of the nano aluminum hydroxide is in the range of 30 nm to 60 nm.

[0048] In this embodiment, the mineral insulating oil is naphthe...

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Abstract

The invention discloses a modified high ignition point transformer oil and a preparation method thereof. The modified high ignition point transformer oil is mainly composed of mineral insulating oil, modified nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant and toluene diphenyl phosphate Composed of ester, the modified nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant is mainly prepared by modifying nano-magnesium hydroxide and nano-aluminum hydroxide through oleic acid. The preparation method includes (1) preparing a modified nano-magnesium hydroxide / nano-aluminum hydroxide composite flame retardant, (2) adding the composite flame retardant, and (3) adding toluene diphenyl phosphate. The modified high ignition point transformer oil of the present invention not only has the characteristics of excellent heat dissipation performance, insulation performance and low price of mineral insulating oil, but also has the characteristics of high fire resistance and fire prevention performance, and can be replaced without any modification to the existing transformer The original conventional low ignition point mineral insulating oil can be widely used and promoted, and has important practical significance and commercial value.

Description

technical field [0001] The invention belongs to the technical field of insulating oil, and relates to a modified high ignition point transformer oil and a preparation method thereof, in particular to a nano flame retardant modified high ignition point transformer oil and a preparation method thereof. Background technique [0002] At present, transformers are basically oil-immersed transformers, and the most widely used transformer oil is mineral insulating oil, because mineral insulating oil has the advantages of excellent electrical insulation, cooling performance and low cost. However, due to the low ignition point of mineral insulating oil, the transformer is prone to fire when a serious failure occurs, and the probability of fire is 5% to 15%. Therefore, it is urgent to develop high ignition point transformer oil to solve the above problems. [0003] In order to solve the above problems, some scholars have successively developed insulating oil, silicone oil, synthetic e...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10M169/04C10N40/16
CPCC10M169/045C10M2201/062C10M2223/04C10M2207/126C10M2207/021
Inventor 魏加强黄颖万涛周挺黄海波龚尚昆周舟吴俊杰徐松刘奕奕
Owner STATE GRID HUNAN ELECTRIC POWER
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