Phosphorescent compound and preparation method and application thereof
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0061] The preparation steps of phosphorescent compound 1 are:
[0062]
[0063] 1) Under nitrogen protection system, weigh A-001 (60mmol), IrC1 3 ·3H 2 O (25mmol) was put into the reaction system, a mixed solution of 150mL ethylene glycol ether and 70mL purified water was added, under nitrogen protection, the temperature was raised to 140°C and stirred for 24 hours. The reaction was monitored by TLC, and the temperature was lowered until the reaction of the raw materials was completed. Direct suction filtration gave a yellow solid, which was washed with 100 mL of ethanol and then with 100 mL of petroleum ether, and dried to obtain intermediate B-001 (10.7 g, yield 69%).
[0064] 2) Under a nitrogen protection system, weigh the intermediate B-001 (8mmol), add silver trifluoromethanesulfonate (24mmol), then add 100mL of dichloromethane to the system, add 40mL of isopropanol, and react at room temperature for 24 Hour. TLC monitoring showed that the reaction of the raw mat...
Embodiment 2
[0069] The preparation steps of phosphorescent compound 10 are:
[0070]
[0071] 1) Under nitrogen protection system, weigh A-010 (60mmol), IrC1 3 ·3H 2 O (25mmol) was put into the reaction system, a mixed solution of 150mL ethylene glycol ether and 70mL purified water was added, under nitrogen protection, the temperature was raised to 140°C and stirred for 24 hours. The reaction was monitored by TLC, and the temperature was lowered until the reaction of the raw materials was completed. Direct suction filtration gave a yellow solid, which was washed with 100 mL of ethanol and then with 100 mL of petroleum ether, and dried to obtain intermediate B-010 (19.4 g, yield 80%).
[0072] 2) Under nitrogen protection system, weigh intermediate B-010 (8mmol), add silver trifluoromethanesulfonate (24mmol), then add 100mL of dichloromethane to the system, add 40mL of isopropanol, under nitrogen protection, React at room temperature for 24 hours. TLC monitoring showed that the reac...
Embodiment 3
[0077] The preparation steps of phosphorescent compound 28 are:
[0078]
[0079] 1) Under nitrogen protection system, weigh A-028 (60mmol), IrC1 3 ·3H 2 O (25mmol) was put into the reaction system, a mixed solution of 150mL ethylene glycol ether and 70mL purified water was added, under nitrogen protection, the temperature was raised to 140°C and stirred for 24 hours. The reaction was monitored by TLC, and the temperature was lowered until the reaction of the raw materials was completed. Direct suction filtration gave a yellow solid, which was first washed with 80 mL of ethanol, then washed with 120 mL of petroleum ether, and dried to obtain intermediate B-028 (10.0 g, yield 77%).
[0080] 2) Under a nitrogen protection system, weigh the intermediate B-028 (8mmol), add silver trifluoromethanesulfonate (24mmol), then add 100mL of dichloromethane to the system, add 40mL of isopropanol, and react at room temperature for 24 Hour. TLC monitoring showed that the reaction of t...
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com