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Oily water-soluble quenching liquid and preparation method thereof

A water-soluble, quenching liquid technology, applied in the direction of quenching agent, manufacturing tools, heat treatment equipment, etc., can solve the problems of fire hazards, easy to pollute the environment, difficult to handle waste residues, etc., to eliminate fire hazards, wide application range, low cost of use low effect

Inactive Publication Date: 2020-04-14
沙索(广州)工业介质科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] For quenching and cooling of high hardenability materials or alloy materials with small size, water quenching is prone to quenching cracks, which cannot meet the requirements of industrial production, so mineral oil is still used as the quenching medium
At present, mineral oil accounts for about 40% of heat treatment cooling. The advantages of mineral oil are good process adaptability, stable product quality, and no quenching cracks or brittle fractures; the disadvantage is that the environmental pollution is relatively serious, which is easy to cause fire. The process is easy to pollute the environment, and the fume environment is not conducive to the health of workers
The specific performance is as follows: (1) The oily fume produced at the entrance of the quenching and lead pot will cause poor air quality at the operation site and affect the physical and mental health of the operators. Even if the method of electrostatic oil fume removal is used, it is difficult to meet the air emission requirements; (2) The covering agent at the entrance of the lead pot is polluted by the quenching oil brought in from the surface of the steel wire, and the waste slag generated is difficult to handle. The thinner the steel wire, the more ends, and the faster the speed, the more waste slag will be generated, which is difficult to handle under the current environmental protection pressure.
(3) When the steel wire at about 900°C is quenched in oil, it is easy to produce open flames. When the cooling capacity of the quenching oil is insufficient, it is easy to cause a fire, which can damage equipment and burn the factory building, and cause casualties; There is a fire hazard when the cover agent at the entrance of the lead pot is contaminated with quenching oil

Method used

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  • Oily water-soluble quenching liquid and preparation method thereof

Examples

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Effect test

Embodiment 1

[0014] The oil-like water-soluble quenching liquid of the present invention includes 10% polyvinylpyrrolidone, 5% complex amine, 2% dicarboxylic acid, 1% boric acid, 0.5% defoamer, 1% sodium nitrite, and the rest is deionized water .

[0015] The preparation method of the above-mentioned oily water-soluble quenching liquid is as follows: dissolve the complex amine, add dicarboxylic acid, mix evenly at a temperature of 40-70°C, continue to add sodium nitrite, and then put in polyvinylpyrrolidone and defoamer in turn , stir and mix evenly at 100 rpm, and control the pH of the entire mixed liquid system at 9.5.

Embodiment 2

[0017] The oil-like water-soluble quenching liquid of the present invention comprises 15% of polyvinylpyrrolidone, 10% of compound amine, 2% of dicarboxylic acid, 1.5% of boric acid, 0.5% of defoamer, 1.2% of sodium nitrite, and the rest is deionized water .

[0018] The preparation method of the above-mentioned oily water-soluble quenching liquid is as follows: dissolve the complex amine, add dicarboxylic acid, mix evenly at a temperature of 40-70°C, continue to add sodium nitrite, and then put in polyvinylpyrrolidone and defoamer in turn , stirred and mixed evenly at 150 rpm, and the pH of the entire mixed liquid system was controlled at 9.0.

Embodiment 3

[0020] The oil-like water-soluble quenching liquid of the present invention includes 5% polyvinylpyrrolidone, 5% complex amine, 1.5% dicarboxylic acid, 0.7% boric acid, 0.5% defoamer, 1% sodium nitrite, and the rest is deionized water .

[0021] The preparation method of the above-mentioned oily water-soluble quenching liquid is as follows: dissolve the complex amine, add dicarboxylic acid, mix evenly at a temperature of 40-70°C, continue to add sodium nitrite, and then put in polyvinylpyrrolidone and defoamer in turn , stirred and mixed evenly at a rotating speed of 50 rpm, and the pH of the entire mixed liquid system was controlled at 9.0.

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Abstract

The invention discloses an oily water-soluble quenching liquid and a preparation method thereof. The liquid comprises the following components of, in percentage by mass, 5%-15% of polyvinylpyrrolidone, 5%-10% of complex amine, 1%-5% of polycarboxylic acid, 1%-5% of boric acid, 0%-2% of defoamer, 0%-2% of corrosion inhibitor, and the balance deionized water. The method comprises the following stepsthat firstly, the complex amine is dissolved, the polycarboxylic acid is added, the mixture is uniformly mixed at the temperature of 40-70 DEG C, the corrosion inhibitor is continuously added, then the polyvinylpyrrolidone and the defoamer are sequentially added, and uniform stirring is conducted. According to the oily water-soluble quenching liquid, the application range is wider, different cooling speeds can be obtained by adjusting the concentration, the oily water-soluble quenching liquid has smaller deformation compared with other polymers, and can be used for quenching and cooling a high hardenability material or a small size alloy material, so that mineral oil for quenching is replaced, fire hazards are eliminated, and safety is higher.

Description

technical field [0001] The invention belongs to the technical field of heat treatment cooling medium, and in particular relates to an oil-like water-soluble quenching liquid and a preparation method thereof. Background technique [0002] For quenching and cooling of high hardenability materials or alloy materials with small size, water quenching is prone to quenching cracks, which cannot meet the requirements of industrial production, so mineral oil is still used as the quenching medium. At present, mineral oil accounts for about 40% of heat treatment cooling. The advantages of mineral oil are good process adaptability, stable product quality, and no quenching cracks or brittle fractures; the disadvantage is that the environmental pollution is relatively serious, which is easy to cause fire. It is easy to pollute the environment during the process, and the fume environment is not conducive to the health of workers. The specific performance is as follows: (1) The oily fume p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21D1/60
CPCC21D1/60
Inventor 韩军潘永清
Owner 沙索(广州)工业介质科技有限公司
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