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Preparation method of stain-resistant real stone paint

A technology of preparation steps of real stone paint, which is applied in the field of preparation of stain-resistant real stone paint, can solve problems such as foam generation, cost increase, influence on paint product color, viscosity, mixing stability state properties, etc., and achieve high electronegativity , small polarizability, good anti-ultraviolet aging performance

Inactive Publication Date: 2019-08-16
梁荣付
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when the dispersant is used in a large amount, foam may be generated in the paint mixture, and a larger amount of defoamer needs to be added for defoaming, which increases the cost of formula preparation and affects paint products such as color, Properties in terms of viscosity, mixing stability state, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0028] Preparation of surface-modified titania nanoparticles:

[0029]Mix 200 mL of absolute ethanol with 100 mL of 2% perfluorooctyltriethoxysilane aqueous solution to obtain a siloxane solution, adjust the pH of the siloxane solution to .3 with 60% acetic acid by mass fraction, and Pour the siloxane solution into a beaker, stir and mix with a magnetic stirrer at a speed of 320r / min for 24 hours to obtain a hydrolyzed fluorosilane solution;

[0030] Prepare a titanium dioxide ethanol mixture with a mass concentration of 4 mg / mL, mix the titanium dioxide ethanol mixture with the hydrolyzed fluorosilane solution at a volume ratio of 4:1, place it in a beaker, and stir and mix with a magnetic stirrer at a speed of 400 r / min After 7 hours, place it in a high-speed centrifuge at a speed of 4200r / min for 10 minutes, remove the upper layer, separate and obtain the lower precipitate, put the lower precipitate in a vacuum drying oven with a set temperature of 85°C, and dry for 12 hour...

example 2

[0037] Preparation of surface-modified titania nanoparticles:

[0038] Mix 210 mL of absolute ethanol with 110 mL of 2% perfluorooctyltriethoxysilane aqueous solution to obtain a siloxane solution, adjust the pH of the siloxane solution to 3.2 with 60% acetic acid, and dissolve the silicon Pour the oxane solution into a beaker, stir and mix with a magnetic stirrer at a speed of 310r / min for 23h to obtain a hydrolyzed fluorosilane solution;

[0039] Prepare a titanium dioxide ethanol mixture with a mass concentration of 4mg / mL, mix the titanium dioxide ethanol mixture with the hydrolyzed fluorosilane solution at a volume ratio of 4:1, place it in a beaker, and stir and mix with a magnetic stirrer at a speed of 420r / min After 8 hours, place it in a high-speed centrifuge at a speed of 4300r / min for 11 minutes, remove the upper layer, separate and obtain the lower precipitate, put the lower precipitate in a vacuum drying oven with a set temperature of 83°C, and dry for 13 hours to...

example 3

[0046] Preparation of surface-modified titania nanoparticles:

[0047] Mix 220mL of absolute ethanol with 120mL of 2% perfluorooctyltriethoxysilane aqueous solution to obtain a siloxane solution, adjust the pH of the siloxane solution to 3.3 with 60% acetic acid, and dissolve the silicon Pour the oxane solution into a beaker, stir and mix with a magnetic stirrer at a speed of 320r / min for 24 hours to obtain a hydrolyzed fluorosilane solution;

[0048] Prepare a titanium dioxide ethanol mixture with a mass concentration of 4mg / mL, mix the titanium dioxide ethanol mixture with the hydrolyzed fluorosilane solution at a volume ratio of 4:1, place it in a beaker, and stir and mix with a magnetic stirrer at a speed of 450r / min After 8 hours, place it in a high-speed centrifuge at a speed of 4500r / min for 12 minutes, remove the upper layer, separate and obtain the lower precipitate, put the lower precipitate in a vacuum drying oven with a set temperature of 85°C, and dry for 14 hours...

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Abstract

The invention belongs to the technical field of coatings, and particularly relates to a preparation method of stain-resistant real stone paint. The carbon nano tubes and the argil are coated, so thatthe pigment in the color sand is not radiated by light rays; titanium dioxide also has the function of absorbing and converting ultraviolet rays, so that the stone-like paint has good ultraviolet aging resistance; a layer of fluorosilane molecules is formed on the surface of the titanium dioxide nanoparticles in the real stone paint coating; fluorine atoms in fluorosilane molecules of the coatinglayer are high in electronegativity, so that the bond energy of a single bond formed by the fluorosilane molecules and other elements is larger than that of a single bond formed by carbon atoms and other elements, and due to the fact that the carbon chains in the fluorosilane molecules are protected by the original space barrier effect, fluorosilane has good chemical stability and low surface freeenergy. The fluorosilane surface coating layer reduces the Van Der Waals' force of titanium dioxide nanoparticles on water and the effect of hydrogen bonds and greatly increases the contact angle ofthe surface of a paint film, so that the product shows super-hydrophobicity. The preparation method can obviously improve the stain resistance of the real stone paint, and has a wide application prospect.

Description

technical field [0001] The invention belongs to the technical field of coatings, and in particular relates to a preparation method of stain-resistant real stone paint. Background technique [0002] In view of the application status and existing problems of exterior wall decoration materials in our country, measures are taken to gradually limit the use of exterior wall decoration materials with high energy consumption, poor safety and environmental pollution, and give priority to the use of high-performance exterior wall coatings. Advocate the application of architectural coatings in decoration projects such as residential buildings, industrial buildings, public buildings and structures. The exterior wall decoration of multi-storey residential buildings, general industrial buildings and public buildings should use architectural coatings with a service life of more than 5 years, and high-rise buildings should have a service life of 5 years. Architectural coatings over 10 years...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D4/02C09D4/06C09D5/16C09D7/61C09D7/63
CPCC09D4/06C09D5/1668C09D5/1687
Inventor 梁荣付
Owner 梁荣付
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