Preparation method of stain-resistant real stone paint
A technology of preparation steps of real stone paint, which is applied in the field of preparation of stain-resistant real stone paint, can solve problems such as foam generation, cost increase, influence on paint product color, viscosity, mixing stability state properties, etc., and achieve high electronegativity , small polarizability, good anti-ultraviolet aging performance
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example 1
[0028] Preparation of surface-modified titania nanoparticles:
[0029]Mix 200 mL of absolute ethanol with 100 mL of 2% perfluorooctyltriethoxysilane aqueous solution to obtain a siloxane solution, adjust the pH of the siloxane solution to .3 with 60% acetic acid by mass fraction, and Pour the siloxane solution into a beaker, stir and mix with a magnetic stirrer at a speed of 320r / min for 24 hours to obtain a hydrolyzed fluorosilane solution;
[0030] Prepare a titanium dioxide ethanol mixture with a mass concentration of 4 mg / mL, mix the titanium dioxide ethanol mixture with the hydrolyzed fluorosilane solution at a volume ratio of 4:1, place it in a beaker, and stir and mix with a magnetic stirrer at a speed of 400 r / min After 7 hours, place it in a high-speed centrifuge at a speed of 4200r / min for 10 minutes, remove the upper layer, separate and obtain the lower precipitate, put the lower precipitate in a vacuum drying oven with a set temperature of 85°C, and dry for 12 hour...
example 2
[0037] Preparation of surface-modified titania nanoparticles:
[0038] Mix 210 mL of absolute ethanol with 110 mL of 2% perfluorooctyltriethoxysilane aqueous solution to obtain a siloxane solution, adjust the pH of the siloxane solution to 3.2 with 60% acetic acid, and dissolve the silicon Pour the oxane solution into a beaker, stir and mix with a magnetic stirrer at a speed of 310r / min for 23h to obtain a hydrolyzed fluorosilane solution;
[0039] Prepare a titanium dioxide ethanol mixture with a mass concentration of 4mg / mL, mix the titanium dioxide ethanol mixture with the hydrolyzed fluorosilane solution at a volume ratio of 4:1, place it in a beaker, and stir and mix with a magnetic stirrer at a speed of 420r / min After 8 hours, place it in a high-speed centrifuge at a speed of 4300r / min for 11 minutes, remove the upper layer, separate and obtain the lower precipitate, put the lower precipitate in a vacuum drying oven with a set temperature of 83°C, and dry for 13 hours to...
example 3
[0046] Preparation of surface-modified titania nanoparticles:
[0047] Mix 220mL of absolute ethanol with 120mL of 2% perfluorooctyltriethoxysilane aqueous solution to obtain a siloxane solution, adjust the pH of the siloxane solution to 3.3 with 60% acetic acid, and dissolve the silicon Pour the oxane solution into a beaker, stir and mix with a magnetic stirrer at a speed of 320r / min for 24 hours to obtain a hydrolyzed fluorosilane solution;
[0048] Prepare a titanium dioxide ethanol mixture with a mass concentration of 4mg / mL, mix the titanium dioxide ethanol mixture with the hydrolyzed fluorosilane solution at a volume ratio of 4:1, place it in a beaker, and stir and mix with a magnetic stirrer at a speed of 450r / min After 8 hours, place it in a high-speed centrifuge at a speed of 4500r / min for 12 minutes, remove the upper layer, separate and obtain the lower precipitate, put the lower precipitate in a vacuum drying oven with a set temperature of 85°C, and dry for 14 hours...
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