Opposite solid particle jet distributor online coke cleaning device

A solid particle, opposed technology, which is applied in the direction of cleaning heat transfer devices, non-rotating equipment cleaning, lighting and heating equipment, etc., can solve the problems of deterioration of the operating conditions of the reaction system, reduction of catalyst reaction performance, and increase of reactor operating pressure. Achieve the effect of strengthening gas-solid mixing effect, stabilizing reaction performance and maintaining consumption level

Active Publication Date: 2020-09-04
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The technical problem to be solved by the present invention is that in the cooler of the ammoxidation production acrylonitrile reaction system existing in the prior art, the existing single-nozzle solid particle spray distributor has uneven particle distribution and sticky particles in some of the cooler tubes. It is difficult to remove the accumulated coke, which leads to an increase in channel resistance, an increase in the operating pressure of the reactor, a deterioration in the operating condition of the reaction system, a decrease in the catalyst reaction performance, an increase in device consumption, a shortened operation period, and an increase in operating costs due to non-recovery of solid particles To solve the problem, provide a new online coke cleaning device with opposed solid particle jet distributor

Method used

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  • Opposite solid particle jet distributor online coke cleaning device
  • Opposite solid particle jet distributor online coke cleaning device
  • Opposite solid particle jet distributor online coke cleaning device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Using the on-line decoking device for recycling solid particles of the present invention, a spray distributor is installed in the upper head of the cooler. The spray distributor is composed of 4 opposed nozzles. The pressure drop of the reaction gas cooler is 4kPa at the beginning of the start-up. Gas nitrogen is the driving force. The spherical iron ball particles with an average diameter of 5mm are transported to the opposed solid particle spray distributor through the solid particle feeder. After the distributor is sprayed, the solid particles are distributed to the spraying speed of 90m / s. In each tube of the ammoxidation reaction gas cooler, the coking material in the tube is cleared. When the acrylonitrile unit runs continuously for 24 months, the pressure drop of the cooler is 4.2kPa, which stabilizes the resistance and The operating pressure of the reaction system and the acrylonitrile unit yield of the catalyst remain unchanged, maintaining the consumption level ...

Embodiment 2~9

[0035] Operate according to the conditions and steps of Example 1, but change the type of inert gas, the average diameter of solid particles, the type of solid particles, the shape of solid particles, the ejection speed of solid particles, the type of distributor, the number of installations, The type and quantity of gas-solid separators, the operating conditions such as the ratio of the opening diameter of the protective plate to the inner diameter of the tube, the specific process operating conditions and the pressure drop of the reaction gas cooler after the device is running, the change in the single collection of acrylonitrile of the catalyst, and the operation of the device See Table 1 and Table 2 for the results of period, cooler tube sheet and tube scouring and wear.

[0036] Table 1 Comparison of process conditions between comparative examples and examples

[0037]

[0038]

[0039] Table 2 Comparison of device operation results between comparative examples and examples

[...

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Abstract

The invention relates to an opposed type solid particle spraying distributor online coke cleaning device. The device main solves the problem in the prior art of the hard removing of coke accumulated in gas cooler tubes. The device includes a solid particle storage tank, an ammonia oxidation reaction gas cooler, a solid particle unloading device, a solid particle spraying distributor and gas-solidseparators; the ammonia oxidation reaction gas cooler includes a hollow upper head and a heat exchange section distributed with the tubes; the upper part of the heat exchange section is provided witha protection plate; the solid particle spraying distributor is placed in the upper head along an axial direction; a solid particle distributor is arranged in an opposed manner at least by more than two nozzles which are in opposed arrangement or inclined at a certain angle; the inlet of inert gas communicates with the solid particle spraying distributor after being parallel with the outlet of thesolid particle storage tank; and the outlet of the cooler is provided with at least one gas-solid separator to recycle solid particles. Thus, the problem can be well solved, so that the device can beused for online coke removing industrial devices.

Description

Technical field [0001] The invention relates to an on-line cleaning device for an opposed solid particle spray distributor. [0002] technical background [0003] In the field of the production of acrylonitrile by ammoxidation of propylene, the high temperature reaction gas generated by the reaction contains easily polymerizable compounds such as acrylonitrile, hydrocyanic acid, acrolein, etc., and the polymerization reaction is likely to occur during the cooling process of the reaction gas, and the resulting polymer The catalyst dust from the fluidized bed reactor adheres and accumulates in the tube of the reaction gas cooler. With the extension of the operating time, the scale layer on the inner wall of the tube gradually increases, and the channel in the tube gradually decreases, which causes the tube to be blocked. , Increase the pipeline resistance. When the scale reaches a certain thickness, the operating pressure of the reaction system will increase significantly, worsening ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): F28G1/12
CPCF28G1/12
Inventor 王清立顾军民张斌
Owner CHINA PETROLEUM & CHEM CORP
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