a zns-sns 2 Preparation method of the complex

A zns-sns2, complex technology, applied in chemical instruments and methods, chemical/physical processes, physical/chemical process catalysts, etc., can solve the problems of complex complexes, large differences, etc., to ensure complex effect, nanoparticle size. small effect

Active Publication Date: 2021-11-26
HANGZHOU DIANZI UNIV
View PDF3 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, nano-ZnS synthesis conditions and two-dimensional nanosheet SnS 2 The difference is large, and there are certain difficulties in obtaining composites compatible with these two nanomaterials, so the present invention provides a mature and reliable method to prepare ZnS-SnS 2 Complex

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • a zns-sns <sub>2</sub> Preparation method of the complex
  • a zns-sns <sub>2</sub> Preparation method of the complex

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] ZnCl 2 , oleic acid amide, thiourea, and water are mixed according to the mass ratio of 1:1:2:60, placed in a hydrothermal reaction kettle for hydrothermal reaction, the hydrothermal reaction temperature is 160 ° C, and the constant temperature time is 8 hours; the hydrothermal reaction After the reaction, the solid-liquid mixture is subjected to solid-liquid centrifugation, the liquid product is poured out, the solid product is taken out, washed with deionized water for 3 times, and then dried at 70°C for 5 hours; the dried product is ground into powder to obtain nano ZnS; the above nano ZnS, SnCl 2 , thioacetamide, hydrazine hydrate and water are mixed according to the mass ratio of 10:1:2:1:50 to form a precursor solution, which is placed in a hydrothermal reaction kettle for hydrothermal reaction. The hydrothermal reaction temperature is 160°C, and the constant temperature time is 20 hours; centrifuge the solid-liquid mixture after the hydrothermal reaction, pour o...

Embodiment 2

[0020] ZnCl 2 , oleic acid amide, thiourea, and water are mixed according to the mass ratio of 1:2:4:60, placed in a hydrothermal reaction kettle for hydrothermal reaction, the hydrothermal reaction temperature is 200 ° C, and the constant temperature time is 12 hours; the hydrothermal reaction After the reaction, the solid-liquid mixture is subjected to solid-liquid centrifugation, the liquid product is poured out, the solid product is taken out, washed with deionized water for 3 times, and then dried at 80°C for 8 hours; the dried product is ground into powder to obtain nano ZnS; the above nano ZnS, SnCl 2 , thioacetamide, hydrazine hydrate and water are mixed according to the mass ratio of 10:2:4:4:50 to form a precursor solution, which is placed in a hydrothermal reaction kettle for hydrothermal reaction. The hydrothermal reaction temperature is 200 ° C, and the constant temperature time is 30 hours; the solid-liquid mixture after the hydrothermal reaction was subjected t...

Embodiment 3

[0023] ZnCl 2 , oleic acid amide, thiourea, and water are mixed according to the mass ratio of 1:1:3:60, placed in a hydrothermal reaction kettle for hydrothermal reaction, the hydrothermal reaction temperature is 180 ° C, and the constant temperature time is 10 hours; the hydrothermal reaction After the reaction, the solid-liquid mixture is subjected to solid-liquid centrifugation, the liquid product is poured out, the solid product is taken out, washed with deionized water for 3 times, and then dried at 80°C for 6 hours; the dried product is ground into powder to obtain nano ZnS; the above nano ZnS, SnCl 2 , thioacetamide, hydrazine hydrate and water are mixed according to the mass ratio of 10:2:3:3:50 to form a precursor solution, which is placed in a hydrothermal reaction kettle for hydrothermal reaction. The hydrothermal reaction temperature is 180°C, and the constant temperature time is 24 hours; centrifuge the solid-liquid mixture after the hydrothermal reaction, pour ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The present invention relates to a kind of ZnS-SnS 2 Method for the preparation of the complex. The inventive method will ZnCl 2 , oleic acid amide, thiourea, and water are mixed to form a precursor liquid, and placed in a hydrothermal reaction kettle for hydrothermal reaction to obtain nano-ZnS; nano-ZnS, SnCl 2 , thioacetamide, hydrazine hydrate and water are mixed to form a precursor solution, which is placed in a hydrothermal reactor for secondary hydrothermal reaction to obtain ZnS‑SnS 2 Complex. The method of the invention has the advantages of simple process, easy control and high production efficiency.

Description

technical field [0001] The present invention relates to a kind of ZnS-SnS 2 Method for the preparation of the complex. Background technique [0002] ZnS is a new type of photoelectric material, and it has been reported that nano-ZnS can be obtained by hydrothermal synthesis. This nano-ZnS has a large specific surface area and exhibits certain photoelectric conversion and catalytic properties. This nanostructure is also an ideal composite carrier, because of its large specific surface area, it can be easily composited with other nanoparticle materials. materials tend to have better photoelectric conversion and catalytic performance. SnS 2 It is a two-dimensional nanosheet material, and it has not been reported that ZnS-SnS can be obtained 2 Composite, the applicant found that the main reason is that ZnS is larger in size, which makes it difficult to combine with SnS 2 If the size of ZnS can be effectively reduced, it is expected to obtain ZnS-SnS 2 Complex. ZnS-SnS 2 ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): B01J27/04
CPCB01J27/04B01J35/004
Inventor 张峻黄国周
Owner HANGZHOU DIANZI UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap