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A kind of triethylenetetramine modified resin film and preparation method thereof

A technology of triethylenetetramine and resin film, which is applied in the field of polymer materials, can solve the problems of difficult production, low production efficiency and high production cost, and achieve the effects of less equipment, increased area and improved quality

Active Publication Date: 2021-01-22
上海棚发膜结构有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] The purpose of the present invention is to solve the problems of high production difficulty, low production efficiency and high production cost in the prior art, and propose a triethylenetetramine modified resin film and its preparation method

Method used

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  • A kind of triethylenetetramine modified resin film and preparation method thereof
  • A kind of triethylenetetramine modified resin film and preparation method thereof

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Embodiment Construction

[0017] The present invention will be further explained below in conjunction with specific embodiments.

[0018] Embodiments 1 to 11, based on 100 parts of terephthalic acid: 150 parts of ethylene glycol, 30 parts of dicyclohexylcarbodiimide, 0.02 parts of 1-hydroxybenzotriazole, and 10 parts of nano silicon dioxide , mixed catalyst is 0.04 part, and take terephthalic acid and triethylenetetramine according to the weight ratio of terephthalic acid and triethylenetetramine in table 1, then carry out the preparation of resin film according to the following steps: first weigh After the terephthalic acid, dicyclohexylcarbodiimide, 1-hydroxybenzotriazole and ethylene glycol are stirred evenly, they are added to the reaction kettle for reaction, and then triethylenetetramine and nano silicon dioxide are added into the reaction kettle, continue to stir until the mixture is uniform, then add the mixed catalyst to carry out the polymerization reaction, and obtain the polymerization reac...

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Abstract

The invention provides a triethylene tetramine modified resin film and a preparation method thereof, and relates to the technical field of high molecular materials. The high-contractility environment-friendly resin film comprises the following raw materials: terephthalic acid, triethylene tetramine, glycol, dicyclohexylcarbodiimide, 1-hydroxybenzotriazole, nanometer silicon dioxide and a mixed catalyst, wherein the mass ratio of the terephthalic acid to the triethylene tetramine is 100:(15-30); the preparation method comprises the following steps: S1, preparing the raw materials; S2, performing esterification, acid activation and polymerization reaction; S4, performing extrusion, quick chilling, preheating and biaxial stretching, so as to obtain the triethylene tetramine modified resin film. The resin film is high in hot-shrinkage rate and good in wear resistance, and the preparation method is simple, high in efficiency and low in cost.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a triethylenetetramine-modified resin film and a preparation method thereof. Background technique [0002] Heat shrinkable film is widely used in the construction industry and packaging industry due to its certain shrinkage, but the shrinkage characteristics of the heat shrinkable film currently used are not ideal. In order to improve the shrinkage characteristics of the heat shrinkable film, many researchers use a multilayer structure. The mode of extruding is realized, as Chinese Patent Authorization Announcement No.: CN100484757C, discloses a kind of high-barrier high-shrinkage film with polyvinyl alcohol as the middle layer and its preparation method. The structure of the film in this patent is 3 to 7 layers, with Achieve high barrier and high shrinkage characteristics; Chinese patent authorization announcement number: CN 102285173B, discloses a low-density high-shr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G63/183C08G63/685C08G63/85C08G63/86C08J5/18C08L67/02
CPCC08G63/183C08G63/6856C08G63/85C08G63/866C08J5/18C08J2367/02
Inventor 李燕新
Owner 上海棚发膜结构有限公司
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