Liquid slow-release agent for sex pheromone of barber borer and its preparation method
A pheromone and sustained-release technology, applied in the field of pesticides, can solve the problems of inability to use mechanical intubation, a lot of manpower and time, and inability to adapt to plant protection mechanization, and achieve the effect of saving raw materials, high initial content, and saving reagent costs.
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Embodiment 1
[0043] The bariatric sex pheromone liquid sustained release agent of the present embodiment is prepared by the following method:
[0044] Take the biodegradable polymer PLA ( J9604E) 4.5g, add 42ml of dichloromethane (55.6g), stir and dissolve at 12°C, then add 1g of sex pheromone, add 1g of oily anti-UV agent, 1g of butyl hydroxyanisole BHA, and then add 1wt% hydroxyanisole Add 1 g of water-based anti-UV agent to 90 ml (90 g) of an aqueous solution of propyl methylcellulose, and slowly raise the temperature of the resulting mixture to 32° C., and stir for 2.5 h at a stirring speed of 300 rpm / min.
Embodiment 2
[0046] The bariatric sex pheromone liquid sustained release agent of the present embodiment is prepared by the following method:
[0047] Take 4.5g of biodegradable polymer PBS (Bionolle 3001), add 42ml of dichloromethane (55.6g), stir and dissolve at 12°C, then add 1g of sex pheromone, add 1g of oily anti-UV agent, 1g of butyl hydroxyl Anisole BHA, then add 90ml (90g) of 1wt% hydroxypropyl methylcellulose aqueous solution, add 1g of water-based anti-UV agent, slowly heat up the resulting mixture to 32°C, and stir for 2.5h at a stirring speed of 300rpm / min .
Embodiment 3
[0057] Evaluate the effect and performance of the bariatric sex pheromone liquid slow-release agent or barbarian sex pheromone microspheres prepared in Example 1-2 and Comparative Example 1-2.
[0058] 1. Indoor and outdoor release test
[0059] 1. Indoor release test
[0060] Experimental method 1: Spray evenly the liquid slow-release agent of the bariatric sex pheromone or the bariatric sex pheromone microspheres on a special board of a certain specification, place it in a fume hood with a constant wind speed (wind speed is about 8km / h), and set it at 0 , 7, 14, 21, 28, 35, 42, 49, and 56 days use GC-MS to measure the residual amount of sex pheromone in barworm, determine the release stability and duration of release of sex pheromone in barworm, and refer to the method of residue test Vlieger J. J. de (2008). The experiments were carried out at 20°C and 30°C, respectively.
[0061] Experimental method 2: Spray evenly the liquid sustained-release agent of the sex pheromone...
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