Fluorene-containing organic compound and application thereof
An organic compound, electromechanical technology, applied in the field of OLED applications and compound materials, can solve problems such as differences, and achieve the effects of improving current efficiency and lifetime, distribution balance, improving exciton utilization and high fluorescence radiation efficiency.
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Embodiment 1
[0087] Embodiment 1: the synthesis of compound 1:
[0088] synthetic route:
[0089]
[0090] In a 250ml three-neck flask, under the protection of nitrogen, add 0.01mol raw material A1, 0.012mol raw material B1, 150ml toluene and stir to mix, then add 5×10 -5 mol Pd 2 (dba) 3 , 5×10 -5 mol tri-tert-butylphosphine, 0.03mol sodium tert-butoxide, heated to 105°C, refluxed for 24 hours, sampling plate, showed no bromide remaining, and the reaction was complete; naturally cooled to room temperature, filtered, and the filtrate was rotary evaporated until there was no fraction , through a neutral silica gel column to obtain the target product, with a HPLC purity of 98.9% and a yield of 64.7%;
[0091] Elemental analysis structure (molecular formula C 58 h 42 N 2 ): theoretical value C, 90.83; H, 5.52; N, 3.65; test value: C, 90.84; H, 5.50; N, 3.65.
[0092] HPLC-MS: The molecular weight of the material is 766.33, and the measured molecular weight is 766.36.
Embodiment 2
[0093] Embodiment 2: the synthesis of compound 9:
[0094] synthetic route:
[0095]
[0096] In a 250ml three-neck flask, under the protection of nitrogen, add 0.01mol raw material A1, 0.012mol raw material B2, 150ml toluene and stir to mix, then add 5×10 -5 mol Pd 2 (dba) 3 , 5×10 -5 mol tri-tert-butylphosphine, 0.03mol sodium tert-butoxide, heated to 105°C, refluxed for 24 hours, sampling plate, showed no bromide remaining, and the reaction was complete; naturally cooled to room temperature, filtered, and the filtrate was rotary evaporated until there was no fraction , through a neutral silica gel column to obtain the target product, with a HPLC purity of 99.5% and a yield of 67.3%;
[0097] Elemental analysis structure (molecular formula C 61 h 46 N 2 O): Theoretical value C, 90.78; H, 5.75; N, 3.47; O, 2.17; Test value: C, 90.76; H, 5.76; N, 3.48.
[0098] HPLC-MS: The molecular weight of the material is 806.366, and the measured molecular weight is 806.39.
Embodiment 3
[0099] Embodiment 3: the synthesis of compound 14:
[0100] synthetic route:
[0101]
[0102] In a 250ml three-neck flask, under the protection of nitrogen, add 0.01mol raw material A1, 0.012mol raw material B3, 150ml toluene and stir to mix, then add 5×10 -5 mol Pd 2 (dba) 3 , 5×10 -5 mol tri-tert-butylphosphine, 0.03mol sodium tert-butoxide, heated to 105°C, refluxed for 24 hours, sampling plate, showed no bromide remaining, and the reaction was complete; naturally cooled to room temperature, filtered, and the filtrate was rotary evaporated until there was no fraction , through a neutral silica gel column to obtain the target product, with a HPLC purity of 99.4% and a yield of 65.8%;
[0103] Elemental analysis structure (molecular formula C 64 h 47 N 3 ): theoretical value C, 89.58; H, 5.52; N, 4.90; test value: C, 89.59; H, 5.51; N, 4.90.
[0104] HPLC-MS: The molecular weight of the material is 857.38, and the measured molecular weight is 857.69.
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