Three component polyurethane binder system
A technology of adhesives and organic adhesives, applied in polyurea/polyurethane adhesives, non-polymer adhesive additives, adhesive types, etc.
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[0014] One solution to these mold performance problems was clearly found in an adhesive composition that uses a three-component approach to provide a polyurethane cold box (PUCB) adhesive system. In such a system, the Part I component includes the polyol base resin and a suitable set of supplements, the Part II component includes the polyisocyanate with a suitable set of supplements, and the Part III component includes the alkyl silicate Compounds such as tetraethyl orthosilicate (TEOS), alkyl silicate oligomers, and optionally aminosilanes.
[0015] TEOS, also known as tetraethoxysilane, is also identified by CAS registry number 78-10-4. Structurally, it has four ethyl groups attached to the oxygen atoms in the orthosilicate core. 99.999% pure TEOS is commercially available from Sigma-Aldrich and other sources.
[0016] Bipedalaminosilanes are characterized by the following general structure:
[0017] (R 1 O) 3 -Si-R 2 -NH-R 2 -Si-(OR 1 ) 3
[0018] where R 1 is an...
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