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Method for hydrothermally preparing adsorption material for heavy metal in wastewater

A technology for adsorbing materials and heavy metals, which is applied in water/sewage treatment, chemical instruments and methods, adsorbed water/sewage treatment, etc. It can solve the problems of low synthesis yield and high synthesis cost of zeolite molecular sieves, and the reaction is also easy to control and produce. Low cost, low cost effect

Inactive Publication Date: 2017-12-08
长沙埃比林环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, the synthesis cost of existing zeolite molecular sieves is relatively high, and the synthesis yield of zeolite molecular sieves is also low. Therefore, it is necessary to explore new and green molecular sieve synthesis routes, devote ourselves to reducing the synthesis cost of molecular sieve materials, and find new breakthroughs in molecular sieve synthesis. Promote the application of molecular sieves in industrial fields

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Mix and dissolve potassium metaaluminate and potassium hydroxide in water according to 1.6:1.2, then add silica sol, the amount of silica sol is 3 times that of the mixture of potassium metaaluminate and potassium hydroxide, and stir for 30 minutes, and then get the primary mixed liquid. Put the primary mixed solution into a stainless steel reaction kettle lined with a polytetrafluoroethylene kettle, and react at a temperature of 150°C for 38 hours; filter the product after the reaction, use suction filtration for filtration, and then wash with distilled water , and washed 4 to 6 times until pH = 7 to 7.5, and then dried at a temperature of 40° C. to obtain a primary solid. The secondary solid is added to the solution containing ammonium chloride, and the solution is stirred under heating conditions, the concentration of ammonium chloride is 1.5mol / L, the heating is water bath heating, and the temperature of the water bath heating is 90 ℃. The stirred solution is filt...

Embodiment 2

[0032] Mix and dissolve potassium metaaluminate and potassium hydroxide in water according to 1.8:1.4, then add silica sol, the amount of silica sol is 3 times that of the mixture of potassium metaaluminate and potassium hydroxide, and stir for 35 minutes, and then get the primary mixed liquid. Put the primary mixed solution into a stainless steel reaction kettle lined with a polytetrafluoroethylene kettle, and react at a temperature of 180°C for 40 hours; filter the product after the reaction, use suction filtration for filtration, and then wash with distilled water , and washed 4 to 6 times until pH = 7 to 7.5, and then dried at a temperature of 40° C. to obtain a primary solid. The secondary solid is added to the solution containing ammonium chloride, and the solution is stirred under heating conditions, the concentration of ammonium chloride is 1.5mol / L, the heating is water bath heating, and the temperature of the water bath heating is 90 ℃. The stirred solution is filt...

Embodiment 3

[0034] Mix and dissolve potassium metaaluminate and potassium hydroxide in water according to 2:1.5, then add silica sol, the amount of silica sol added is 3 times that of the mixture of potassium metaaluminate and potassium hydroxide, and stir for 40 minutes, and then obtain primary mixed liquid. Put the primary mixed solution into a stainless steel reaction kettle lined with a polytetrafluoroethylene kettle, and react at a temperature of 200°C for 42 hours; filter the product after the reaction, use suction filtration for filtration, and then wash with distilled water , and washed 4 to 6 times until pH = 7 to 7.5, and then dried at a temperature of 40° C. to obtain a primary solid. The secondary solid is added to the solution containing ammonium chloride, and the solution is stirred under heating conditions, the concentration of ammonium chloride is 1.5mol / L, the heating is water bath heating, and the temperature of the water bath heating is 90 ℃. The stirred solution is f...

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PUM

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Abstract

The invention discloses a method for hydrothermally preparing an adsorption material for a heavy metal in wastewater. The method comprises the following steps of mixing and dissolving potassium metaaluminate and potassium hydroxide in water, then adding silica sol, agitating for a period of time, and then obtaining primary mixed liquor; putting the primary mixed liquor into a stainless steel reaction kettle, and reacting for a period of time at a certain temperature; filtering, washing and oven-drying a product after the reaction is finished, so as to obtain a primary solid; adding the primary solid into a solution containing ammonium chloride, and agitating the solution in a heating condition; filtering the agitated solution, so as to obtain a final solid; cooling the final solid; drying the cooled final solid; grinding the dried final solid, and then obtaining a zeolite adsorption material. The method is simple in preparation process and is green and environment-friendly; the reaction condition is easily reached; the energy consumption is low and the zeolite adsorption material is high in purity and good in adsorption effect.

Description

technical field [0001] The invention relates to the field of environmental protection, in particular to a method for hydrothermally preparing an adsorption material for heavy metals in wastewater. Background technique [0002] With the continuous development of human society, while economic development brings benefits, it also produces a lot of pollution. The rapid increase of industrial "three wastes" and the increase of vehicle exhaust emissions have become increasingly serious pollution of soil, water and plants in the human living environment, which has become a prominent ecological problem in the coordinated development of economy, society and environment. Heavy metals are generally not biodegradable, and once they enter water or soil, they are difficult to remove. They can enter the human body through the food chain and cause many diseases (such as cancer, etc.). [0003] Adsorption is an effective physical and chemical water treatment method, which is often used to p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/30B01J20/18C02F1/28B01J19/02C02F101/20
CPCB01J19/02B01J20/18B01J20/183B01J2220/4806C02F1/281C02F2101/20
Inventor 不公告发明人
Owner 长沙埃比林环保科技有限公司
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