Method for hydrothermally preparing adsorption material for heavy metal in wastewater
A technology for adsorbing materials and heavy metals, which is applied in water/sewage treatment, chemical instruments and methods, adsorbed water/sewage treatment, etc. It can solve the problems of low synthesis yield and high synthesis cost of zeolite molecular sieves, and the reaction is also easy to control and produce. Low cost, low cost effect
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Embodiment 1
[0030] Mix and dissolve potassium metaaluminate and potassium hydroxide in water according to 1.6:1.2, then add silica sol, the amount of silica sol is 3 times that of the mixture of potassium metaaluminate and potassium hydroxide, and stir for 30 minutes, and then get the primary mixed liquid. Put the primary mixed solution into a stainless steel reaction kettle lined with a polytetrafluoroethylene kettle, and react at a temperature of 150°C for 38 hours; filter the product after the reaction, use suction filtration for filtration, and then wash with distilled water , and washed 4 to 6 times until pH = 7 to 7.5, and then dried at a temperature of 40° C. to obtain a primary solid. The secondary solid is added to the solution containing ammonium chloride, and the solution is stirred under heating conditions, the concentration of ammonium chloride is 1.5mol / L, the heating is water bath heating, and the temperature of the water bath heating is 90 ℃. The stirred solution is filt...
Embodiment 2
[0032] Mix and dissolve potassium metaaluminate and potassium hydroxide in water according to 1.8:1.4, then add silica sol, the amount of silica sol is 3 times that of the mixture of potassium metaaluminate and potassium hydroxide, and stir for 35 minutes, and then get the primary mixed liquid. Put the primary mixed solution into a stainless steel reaction kettle lined with a polytetrafluoroethylene kettle, and react at a temperature of 180°C for 40 hours; filter the product after the reaction, use suction filtration for filtration, and then wash with distilled water , and washed 4 to 6 times until pH = 7 to 7.5, and then dried at a temperature of 40° C. to obtain a primary solid. The secondary solid is added to the solution containing ammonium chloride, and the solution is stirred under heating conditions, the concentration of ammonium chloride is 1.5mol / L, the heating is water bath heating, and the temperature of the water bath heating is 90 ℃. The stirred solution is filt...
Embodiment 3
[0034] Mix and dissolve potassium metaaluminate and potassium hydroxide in water according to 2:1.5, then add silica sol, the amount of silica sol added is 3 times that of the mixture of potassium metaaluminate and potassium hydroxide, and stir for 40 minutes, and then obtain primary mixed liquid. Put the primary mixed solution into a stainless steel reaction kettle lined with a polytetrafluoroethylene kettle, and react at a temperature of 200°C for 42 hours; filter the product after the reaction, use suction filtration for filtration, and then wash with distilled water , and washed 4 to 6 times until pH = 7 to 7.5, and then dried at a temperature of 40° C. to obtain a primary solid. The secondary solid is added to the solution containing ammonium chloride, and the solution is stirred under heating conditions, the concentration of ammonium chloride is 1.5mol / L, the heating is water bath heating, and the temperature of the water bath heating is 90 ℃. The stirred solution is f...
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