Functional copper sulfide composition and functional fiber prepared from same

一种功能性纤维、硫化铜的技术,应用在硫化铜、硫酸铜、氯化铜等方向,能够解决导电性纤维无法同时满足抗菌治愈伤口、纤维颜色改变、传导性、耐洗涤性耐清洗性、耐久性耐湿性、耐碱性降低等问题,达到静电去除特性优秀、防止皮肤老化、耐碱性优秀的效果

Active Publication Date: 2017-09-26
RETEND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The method of preparing conductive fibers by mixing carbon black or metal powder with polymer has the following disadvantages: not only can carbon black or metal powder not form a uniform mixture with polymer, but also in the process of fiberization by spinning, The strength, elongation, and thermal properties of the fiber are greatly reduced
[0013] However, the above-mentioned documents relate to the technology of imparting electrical conductivity by coordinating the fiber with copper sulfide. The conductive fiber prepared by the above-mentioned method has partially improved conductivity, but when it is repeatedly washed or used for a long time, it is not compatible with the fiber. The copper sulfide bonded on the surface is detached, so that the fiber color is seriously changed, and the conductivity, washing resistance, cleaning resistance, durability, moisture resistance, alkali resistance, etc. are sharply reduced
[0014] Moreover, the above-mentioned conductive fibers cannot simultaneously satisfy antibacterial, deodorant, far-infrared radiation, wound healing, skin aging prevention, heat storage and heat preservation, electromagnetic wave shielding, static removal, etc. problems in the field of clothing, industry and military supplies

Method used

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  • Functional copper sulfide composition and functional fiber prepared from same
  • Functional copper sulfide composition and functional fiber prepared from same

Examples

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preparation example Construction

[0056] The present invention relates to a method for preparing functional fibers, which includes: the step of preparing a functional copper sulfide composition, the above-mentioned functional copper sulfide composition comprising 10-40% by weight of copper salt, 1-10% by weight of metal salt, 5-30 weight percent reducing agent, 5-30 weight percent sulfide, 1-5 weight percent catalyst, 1-10 weight percent polyvalent ammonium, 1-10 weight percent basic compound and 1-5 weight percent Percentage of pH regulator; the step of introducing functional groups, importing more than one fiber selected from vegetable fibers, animal fibers, synthetic fibers and regenerated fibers selected from thiol groups, thiocarbonyl groups, thiourea groups, and azole groups More than one functional group in amino group, cyano group and amide group; Coordination bond bonding step, the fiber introduced with functional group is processed by the above composition to bond with copper sulfide on the surface of...

Embodiment 1

[0084] By mixing 35% by weight of copper sulfate (II) pentahydrate, 5% by weight of silver nitrate, 20% by weight of ferrous sulfate, 20% by weight of sodium thiosulfate, 3% by weight of magnesium chloride, 7% by weight of three sub Methyldiamine, 7% by weight of sodium hydroxide and 3% by weight of citric acid were used to prepare a functional copper sulfide composition.

[0085] In an aqueous solution containing a silane coupling agent prepared by reacting imidazole and 3-mercaptopropyltrimethoxysilane, polyamide fibers were dipped and reacted at a temperature of 50°C for 60 minutes to prepare surface-treated polyamide fibers .

[0086] As a result of comparing the fiber weight before and after introducing the functional group to the surface of the fiber, the content of the functional group was 2.3% by weight based on the total fiber weight.

[0087] In an aqueous solution containing 60 parts by weight of the above-mentioned functional copper sulfide composition, 100 parts ...

Embodiment 2

[0091] Except by mixing 35% by weight of copper sulfate (II) pentahydrate, 5% by weight of silver nitrate, 20% by weight of ferrous sulfate, 22.5% by weight of sodium thiosulfate, 0.5% by weight of magnesium chloride, 7% by weight of Trimethylenediamine, 7% by weight of sodium hydroxide and 3% by weight of citric acid were used to prepare the functional copper sulfide composition, and the same method as in Example 1 was used to prepare functional polyamide fibers.

[0092] The content of copper sulfide was 9.8% by weight and the content of silver sulfide was 1.5% by weight relative to the total fiber weight.

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Abstract

The present invention relates to a functional copper sulfide composition and a functional fiber prepared from same, and more particularly, to a functional copper sulfide composition comprising a copper salt, a metal salt, a reducing agent, a sulfur compound, a catalyst, a polyvalent amine, an alkaline compound, and a pH adjusting agent, and a functional fiber prepared by treating a fiber with the composition. The present invention may provide a functional fiber which maintains the color thereof and has excellent conductivity, laundering resistance, washing resistance, durability, moisture resistance, alkali resistance, etc., even after repeated washings or long-term usage. Moreover, the functional fiber according to the present invention is excellent in terms of antibacterial and deodorizing properties, emission of far infrared radiation, scar treatment, skin aging prevention, heat storage and heat insulation, radiation shielding, and static removal, and may thus be widely used in clothing applications such as clothes, socks, gloves, bands, abdominal supports, masks, hats, bandages, scarves, hospital gowns, etc., industrial applications such as bedding, burn pads, industrial filters, fillers, etc., and military applications.

Description

technical field [0001] The present invention relates to a functional copper sulfide composition and a functional fiber prepared therefrom, in more detail, to a composition comprising copper salt, metal salt, reducing agent, sulfide, catalyst, polyvalent ammonium, basic compound and pH regulator A functional copper sulfide composition and a functional fiber prepared by treating the composition in a fiber. Background technique [0002] Most synthetic fibers and natural fibers generate static electricity due to friction between fibers or between fibers and the skin. lead to various problems. [0003] In order to solve the problem of static electricity generated in fibers, research and development are underway to treat fibers with antistatic agents or to impart conductivity to fibers. [0004] The method of treating fibers with an antistatic agent has the advantages of low cost and simple process, but has the disadvantage that the antistatic effect is significantly reduced dur...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F1/09D01F1/10
CPCD01F1/09D01F1/10D01F1/103D01F1/106D06M11/53D06M11/56D06M13/332C01G3/05C01G3/10C01G3/12C07C211/09C07C211/13G01N21/3581
Inventor 李圭尚李奉熙
Owner RETEND CO LTD
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