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A kind of photoelectric material containing dimethyl anthracene structure and its application

A technology of optoelectronic materials, dimethyl anthracene, applied in luminescent materials, hydrocarbon production from oxygen-containing organic compounds, circuits, etc., can solve problems such as different problems, and achieve the effects of avoiding aggregation, reducing device voltage, and improving film formation.

Active Publication Date: 2020-04-21
JIANGSU SUNERA TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, for the collocation of OLED devices with different structures, the photoelectric functional materials used have strong selectivity, and the performance of the same material in devices with different structures may be completely different.

Method used

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  • A kind of photoelectric material containing dimethyl anthracene structure and its application
  • A kind of photoelectric material containing dimethyl anthracene structure and its application
  • A kind of photoelectric material containing dimethyl anthracene structure and its application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] The synthesis of embodiment 1 compound 2:

[0047]

[0048] synthetic route:

[0049]

[0050] In a 250ml four-necked flask, under nitrogen atmosphere, add 16.2g 4-(4-bromo-phenyl) dibenzofuran (0.05mol) and 1.44g Mg powder (0.06mol), 60ml tetrahydrofuran, heat to reflux for 4 hour, the reaction is complete, and the format reagent is generated;

[0051] Dissolve 11.1g of 10,10-dimethylanthrone (0.05mol) in 50ml of tetrahydrofuran, add the above-mentioned Grignard reagent dropwise, react at 60°C for 24 hours, a large amount of white precipitate is formed, and finally add saturated NHCl 4 Convert the Grignard salt into alcohol; after the reaction, extract with ether, dry and rotary evaporate, and purify on a silica gel column with a mixed solvent of petroleum ether: dichloromethane (3:2) to obtain a slightly yellow solid tertiary alcohol (85% yield) ; using DEI-MS to identify the compound, formula C 34 h 26 o 2 , detection value [M+1] + = 466.93, calculated va...

Embodiment 2

[0054] The synthesis of embodiment 2 compound 4:

[0055]

[0056] synthetic route:

[0057]

[0058] Prepared according to the synthetic method of compound 1 in Example 1, the difference is that 4-(4-bromo-phenyl) dibenzofuran is replaced by 6-(4-bromo-phenyl)naphthobenzofuran, and biphenyl instead of benzene;

[0059] Using DEI-MS to identify the compound, formula C 50 h 36 O, detection value [M+1] + =653.13, calculated value 652.28.

Embodiment 3

[0060] The synthesis of embodiment 3 compound 28:

[0061]

[0062] synthetic route:

[0063]

[0064] Prepared according to the synthetic method of compound 1 in Example 1, the difference is that 1-(4-bromo-phenyl)-9,9-dimethylfluorene is used instead of 4-(4-bromo-phenyl)dibenzofuran , replace benzene with biphenyl;

[0065] Using DEI-MS to identify the compound, formula C 49 h 40 , detection value [M+1] + =629.15, calculated value 628.31.

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Abstract

The invention discloses a photoelectric material containing dimethyl anthracene and its application. The compound has higher glass transition temperature and molecular thermal stability, suitable HOMO and LUMO energy levels, and higher Eg. Through device structure optimization, The photoelectric performance of the OLED device and the lifespan of the OLED device can be effectively improved.

Description

technical field [0001] The invention relates to the technical field of organic photoelectric materials, in particular to a compound material containing a dimethyl anthracene structure as a central skeleton and its application in the field of OLEDs. Background technique [0002] Organic electroluminescent (OLED: Organic Light Emission Diodes) device technology can be used to manufacture new display products and also can be used to make new lighting products, which is expected to replace the existing liquid crystal display and fluorescent lighting, and has a wide application prospect. [0003] The OLED light-emitting device is like a sandwich structure, including electrode material film layers, and organic functional materials sandwiched between different electrode film layers. Various functional materials are superimposed on each other according to the application to form an OLED light-emitting device. As a current device, when a voltage is applied to the electrodes at both e...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07D307/91C07D307/77C07D333/76C07D409/06C07D333/50C07D345/00C07C13/58C07C13/66C07C211/61C07C211/58C07C211/54C07D209/80C07D209/82C07D223/22C09K11/06H01L51/54H01L51/50C07C1/20C07C209/68
CPCC09K11/06C07C13/58C07C13/66C07C211/54C07C211/58C07C211/61C07D209/80C07D209/82C07D223/22C07D307/77C07D307/91C07D333/50C07D333/76C07D345/00C07D409/06C09K2211/1092C09K2211/1088C09K2211/1096C09K2211/1029C09K2211/1011C09K2211/1007H10K85/6576H10K85/6574H10K85/6572H10K50/15H10K50/18
Inventor 张兆超王立春李崇
Owner JIANGSU SUNERA TECH CO LTD
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