Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Laser-raman spectrum gas analyzer

A laser Raman spectroscopy and gas analyzer technology, applied in material excitation analysis, laser, Raman scattering, etc., can solve problems such as failure to meet application requirements, and achieve the effect of improving stability and improving collection efficiency

Active Publication Date: 2016-10-05
嘉兴镭光仪器科技有限公司
View PDF7 Cites 20 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] At present, the optimal detection sensitivity achieved by these technological inventions for enhancing the Raman scattering signal of gases is 1ppm, which is still not up to the application requirements of ppb level, such as the detection of volatile organic compounds (volatile organic compounds, VOC)

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Laser-raman spectrum gas analyzer
  • Laser-raman spectrum gas analyzer
  • Laser-raman spectrum gas analyzer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0066] attached figure 1 A laser Raman spectroscopic gas analyzer using backscattering collection method provided for Embodiment 1 of the present invention, including a laser module 1, a small-sized mirror 3, a gas sample chamber 4, a photodetector 5, and a piezoelectric ceramic A control module 7 , a scattered light collection device 10 , an optical fiber bundle 11 and a spectrometer 12 .

[0067] Among them, see attached figure 2 , as a specific implementation of the laser module 7 , including a laser 13 , a Faraday laser isolator 14 , a bandpass filter 15 , a lens 16 , a pinhole filter 17 and a lens 18 . Laser 13 emits laser beam 2a, can adopt any kind of laser, as gas laser, semiconductor laser, solid-state laser etc., adopted a semiconductor-pumped solid-state (DPSS) single longitudinal mode green laser in the present embodiment, its output laser beam is a single longitudinal mode, wavelength λ laser =532nm; Faraday laser isolator 14 is used to isolate the reflected l...

Embodiment 2

[0093] attached Figure 10 A laser Raman spectroscopic gas analyzer using a forward scattering collection method provided for Embodiment 2 of the present invention, including a laser module 1, a mirror 35, a gas sample chamber 4, a photodetector 5, and a piezoelectric ceramic control module 7. Dichroic mirror 34 , scattered light collection device 10 , optical fiber bundle 11 and spectrometer 12 .

[0094] The differences between the second embodiment of the present invention and the first embodiment are as follows: 1. In the second embodiment, the collected signal is the forward scattered light 9b. The dichroic mirror 34 is used to realize the separation of the forward Raman scattered light collection optical path from the outgoing laser beam 2d; the dichroic mirror is a short-wave pass dichroic mirror, which passes through the laser wavelength and reflects the Raman scattered light . 2. In the second embodiment, the optical resonant cavity is controlled to lock the longitu...

Embodiment 3

[0097] attached Figure 11a A gas sample chamber 4 provided for the third embodiment of the present invention, the difference between the third embodiment of the present invention and the first embodiment is:

[0098] 1. in embodiment three, be provided with a slope reflector 36 between reflector 19 and hollow reflector tube 21, its center is provided with an aperture (diameter D 36 =1mm), the laser beam 2c can freely pass therethrough; Figure 13a It is a schematic diagram of the inclined mirror 36, wherein S36 is a reflecting surface; S36 is inclined relative to the laser beam 2c; the inclined mirror 36 is used to separate the scattered light 9 from the laser beam 2c. The reflective surface S36 of the slope reflector 36 can also be a curved surface, such as Figure 11b and Figure 13b As shown, the scattered light 9 emitted from the hollow reflecting tube 21 becomes collimated light after being reflected by the inclined mirror 36 .

[0099] 2. The cavity 22 is provided w...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Lengthaaaaaaaaaa
Login to View More

Abstract

The invention provides a laser-raman spectrum gas analyzer. The laser-raman spectrum gas analyzer comprises a laser, an optical resonator, a hollow reflection pipe, a scattered light collecting device and a spectrograph. The laser emits laser beams to the optical resonator. The optical resonator is composed of optical resonator reflectors. The hollow reflection pipe is a hollow pipe containing gas to be analyzed and is placed between two of the optical resonator reflectors in the optical resonator, and the laser beams in the optical resonator enter the hollow reflection pipe from one end and are emitted out through the other end of the hollow reflection pipe. The laser beams in the optical resonator transmit in the inner wall of the hollow reflection pipe and act with the gas molecules to be analyzed in the hollow reflection pipe to produce scattered light; the scattered light is reflected by the pipe wall in the hollow reflection pipe for multiple times and then are emitted out from the two ends of the hollow reflection pipe. According to the laser-raman spectrum gas analyzer, the cavity length of the optical resonator is precisely adjusted through piezoelectric ceramics, an external incident laser beam longitudinal mode is locked, and enhanced laser beams are formed in the optical resonator; the enhancing effect is dozens of times or higher that of a pure optical resonator enhancing technology, and the sensitivity of gas detection is improved.

Description

technical field [0001] The invention relates to the field of analysis and detection of gas chemical components, in particular to a laser Raman spectrum gas analyzer. Background technique [0002] In 1928, C.V. Raman experiment found that the frequency of light passing through a transparent medium and being scattered by molecules changes. This phenomenon is called Raman scattering. In the scattering spectrum of a transparent medium, the frequency and the incident light frequency υ 0 The same component is called Rayleigh scattering; frequency symmetric distribution in υ 0 The spectral lines or bands on both sides are the Raman spectrum, in which the component υ with a smaller frequency 0 -Δυ is also known as the Stokes line, the component with a higher frequency υ 0 +Δυ is also called the anti-Stokes line. Since the number of Raman spectral lines, the size of the displacement, and the length of the spectral lines are directly related to the vibration or rotational energy l...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): G01N21/65H01S3/105
Inventor 陈利平
Owner 嘉兴镭光仪器科技有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products