Porous film, waterproof and moisture-permeable material, and medical clothing and protective clothing using the same
A waterproof, moisture-permeable, porous membrane technology, which is applied in other medical devices, protective clothing, protective equipment, etc., can solve the problems of damaged barrier properties of woven fabrics, poor barrier properties of protective clothing, and low puncture strength. Excellent comfort, excellent moisture permeability, and the effect of reducing stuffiness
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Embodiment 1)
[0158] As a polypropylene resin, 96.5 parts by mass of homopolypropylene manufactured by Prime Polymer Co., Ltd. with an MFR of 4.0 g / 10 min and a homopolymer manufactured by Prime Polymer Co., Ltd. with an MFR of 1,000 g / 10 min were used. 3 parts by mass of polypropylene S10CL, 0.3 parts by mass of N,N'-dicyclohexyl-2,6-naphthalene dicarboxamide (manufactured by Shin Nippon Chemical Co., Ltd., NU-100) as a β-crystal nucleating agent, and Antioxidant "IRGANOX" (registered trademark) 1010 and "IRGAFOS" (registered trademark) 168 manufactured by BASF Co., Ltd., 0.1 parts by mass were mixed at this ratio, and the raw materials were supplied from the metering hopper to the twin-screw extruder. It was melt-kneaded at 303° C., extruded from a die into a strand form, cooled and solidified in a water bath at 25° C., and cut into small pieces to obtain a polypropylene composition (A).
[0159] The obtained polypropylene composition (A) was supplied to a single-screw melt extruder, and ...
Embodiment 2)
[0163] In the stretching step of Example 1, the film was stretched 5 times in the longitudinal direction at a stretching speed of 400,000% / min (4000 times / min) using ceramic rolls heated to 125°C for preheating. Next, the ends are held and introduced with clips in a tenter-type stretching machine, preheated at 152°C for 3 seconds, and stretched at 150°C at a stretching speed of 4,500% / min (45 times / min). The same conditions as in Example 1 were applied except that the thickness was increased to 9.0 times, and a porous film with a thickness of 20 μm was obtained. Table 1 shows the evaluation results.
Embodiment 3)
[0165] In the extrusion step of Example 1, except that the extrusion amount was adjusted so that the thickness of the porous film became 250 μm, the same conditions as in Example 1 were applied to obtain a porous film with a thickness of 250 μm. Table 1 shows the evaluation results.
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