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Iridium complex, preparation method thereof and electroluminescent device applying same

A technology of iridium complexes and main ligands, applied in the direction of electric solid devices, electrical components, light-emitting materials, etc., can solve the problems of reduced efficiency, efficiency roll-off, etc., and achieve the effects of excellent performance, high yield and simple preparation method

Inactive Publication Date: 2016-07-06
AAC MICROTECH CHANGZHOU +1
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

In addition, in the current commonly used materials, the hole mobility of hole transport materials is much higher than that of electron transport materials, and the commonly used host materials are mainly hole transport, which will lead to a large number of redundant holes. Aggregation of holes at the interface between the light-emitting layer and the electron-transporting layer
These factors can lead to reduced efficiency and severe efficiency roll-off
Studies have shown that if the iridium complex has a high electron transport ability, it can effectively increase the transport and distribution of electrons in the light-emitting layer, broaden the electron-hole area, balance the number of electron-hole pairs, and greatly improve the device. efficiency, the reduced efficiency of the roll-off

Method used

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  • Iridium complex, preparation method thereof and electroluminescent device applying same
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  • Iridium complex, preparation method thereof and electroluminescent device applying same

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Embodiment Construction

[0019] The present invention will be described in further detail below in conjunction with the accompanying drawings and embodiments. The terms used in the present invention, unless otherwise specified, generally have the meanings commonly understood by those skilled in the art.

[0020] The iridium complexes of the present invention have used iridium trichloride, 4,6-bistrifluoromethylpyridine-3-boronic acid, 4,6-bistrifluoromethylpyridine-4-boronic acid, 2- Bromopyridine derivatives, 2-bromopyrimidine derivatives, 2-bromopyrazine derivatives and 2-bromotriazine derivatives, etc., the synthesis method is similar. The iridium dimeric bridging complex containing two main ligands is mixed with 2-(5-phenyl-1,3,4-oxadiazole-2-)phenol auxiliary ligands and sodium carbonate; the main ligands The body is 2-(4,6-bistrifluoromethylpyridin-3-)ylpyridine, 2-(4,6-bistrifluoromethylpyridin-4-)ylpyridine, 2-(4,6-bis Trifluoromethylpyridin-3-)ylpyrimidine, 2-(4,6-bistrifluoromethylpyridin-...

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Abstract

The invention relates to an iridium complex, wherein the iridium complex has a novel main ligand, and 2-(5- phenyl-1, 3, 4- oxadiazole-2-) phenol serves as an auxiliary ligand; main ligands in the series of iridium complex molecules include 2-(4, 6- bis(trifluoromethyl) pyridine-3-) base pyridine, 2-(4, 6-bis(trifluoromethyl) pyridine-4-) base pyridine, 2-(4, 6- bis(trifluoromethyl) pyridine-3-) base pyrimidine, 2-(4, 6-bis(trifluoromethyl) pyridine-4-) base pyrimidine, 2-(4, 6- bis(trifluoromethyl) pyridine-3-) base pyrazine, 2-(4, 6-bis(trifluoromethyl) pyridine-4-) base pyrazine, 2-(4, 6- bis(trifluoromethyl) pyridine-3-) base triazine and a 2-(4, 6-bis(trifluoromethyl) pyridine-4-) base triazine derivative.The novel iridium complex has the advantages of being high in light-emitting efficiency, high in electronic mobility, stable in chemical property, prone to sublimation and purification and the like and is excellent in device performance.

Description

【Technical field】 [0001] The invention relates to the technical field of organic electroluminescent devices, in particular to a class of iridium complexes, a preparation method thereof and an electroluminescent device using the iridium complexes. 【Background technique】 [0002] Against the background of increasing global energy demand and worrying ecological environment, governments of various countries have vigorously developed sustainable energy-saving technologies and industries based on high technology. Organic electroluminescent devices (OLEDs) have attracted much attention because of their advantages such as wide viewing angle, high brightness, low energy consumption and flexible devices, and are known as the key technology that will dominate the future display world. In recent years, a large number of studies have shown that among many complexes of heavy metal elements, iridium complexes are considered to be the most ideal choice of phosphorescent materials for OLEDs....

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07F15/00C09K11/06H01L51/54H10K99/00
CPCC07F15/0033C09K11/06C09K2211/185C09K2211/1029C09K2211/1007C09K2211/1059C09K2211/1044C09K2211/1048H10K85/342C09K11/025H10K85/631H10K85/654H10K50/11H10K2101/10H10K85/6572H10K50/15H10K50/16H10K50/81H10K77/10
Inventor 郑佑轩潘毅王毅左景林徐秋蕾
Owner AAC MICROTECH CHANGZHOU
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