A kind of method for manufacturing high nitrogen steel with chromium concentrate powder
A technology for chromium concentrate powder and high nitrogen steel is applied in the fields of smelting high-strength stainless steel and high-nitrogen stainless steel. problems such as mass production of steel, to achieve the effect of wide and reliable source of raw materials, reduction of solidification and remelting links, and low carbon content
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Embodiment 1
[0038] A representative Indian chromium concentrate powder is selected as the raw material for the embodiment of the present invention, and its compound composition content (wt%) is about: Cr 2 o 3 56.29, FeO16.20, Al 2 o 3 10.87, CaO0.60, MgO11.60, SiO 2 3.72 and sulfur 0.0062, phosphorus 0.01, others ≤ 1.0. In addition to chromium and iron oxides in the chrome concentrate powder raw materials, other oxides rarely participate in the reaction under the conditions of the present invention, so when preparing decarburized ferrochrome with high-carbon ferrochrome powder, it is only regarded as Cr 2 o 3 and FeO to participate in the chemical reaction; calculated chromium and oxygen in Cr 2 o 3 The content (wt%) in FeO is 68.4 and 31.6 respectively, and the content (wt%) of iron and oxygen in FeO is 77.8 and 22.2 respectively, so that the chromium content (wt%) in the chrome concentrate is 38.5, and the iron content (wt%) is 12.6, and the oxygen content (wt%) participating ...
Embodiment 2
[0048] Prepare about 1000kg of high-nitrogen steel, the main component content (wt%) is Cr18~20, Mn17~19, N0.8~0.9, Mo1.5~2.0, C≤0.03, Si≤1.5, S≤0.05, P≤0.05 . The raw materials used are the same as in Example 1.
[0049] step:
[0050] 1) Preparation of decarburized ferrochrome M=400kg: mix chrome concentrate powder and high-carbon ferrochrome powder according to the molar ratio of carbon to oxygen of 1:1.5 to obtain 188.1kg of chrome concentrate powder and 211.9kg of high-carbon ferrochrome powder , then add sodium silicate binder for mixing, and press it into brick-shaped mixed ferrochrome blocks of 50×100×200. After drying at low temperature, put them into a vacuum heating furnace. The internal pressure is 800Pa, and then the temperature is raised to 1200 to reduce the pressure in the furnace to 500Pa; when the temperature reaches 1500°C after keeping the temperature rising slowly for 5 hours, the pressure in the furnace is controlled at 100Pa and the decarburization rea...
Embodiment 3
[0055] Prepare about 1000kg of high-nitrogen steel, the main components are the same as in Example 1, except that the nitrogen content (wt%) of the solid nitrogen-containing metal manganese of 5.5 is cast after the vacuum smelting and then blown into the nitriding gas for the manganese used, other raw materials With embodiment 1.
[0056] step:
[0057] 1) The preparation of decarburized ferrochrome, nitriding and smelting of high-nitrogen alloy melt is the same as in Example 1;
[0058]2) Melting high-nitrogen steel is to add 220kg of solid nitrogen-containing metal manganese to the high-nitrogen alloy melt at one time after vacuum smelting and then blowing in nitriding gas, and then add 20kg of molybdenum iron to maintain the melt temperature after the metal manganese is melted Between 1550 and 1600°C, add 560kg of industrial pure iron to the melt one after another, at a speed that does not solidify on the surface of the melt, and continue heating for 15 minutes after the i...
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