Composite body of titanium or titanium alloy and resin and preparation method thereof
A technology for titanium alloys and composites, which is applied in the field of titanium or titanium alloys and resin composites and its preparation, can solve the problems of low practicability, environmental pollution, acid and alkali resistance, etc. Simple, less environmental pollution effect
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[0033] In another aspect, the present invention provides a method for preparing a composite of titanium or titanium alloy and resin, the method comprising the following steps:
[0034] (a) Depositing an aluminum film layer 3 on at least part of the surface of the titanium or titanium alloy substrate 1 by physical vapor deposition;
[0035] (b) forming an anodized film 4 on the surface of the aluminum film layer 3 by anodizing;
[0036] (c) performing electrochemical corrosion treatment on the sample obtained in step (b), so that nanopores are formed in the anodized film 4;
[0037] (d) forming a resin layer 5 by injection molding on at least part of the surface of the anodized film 4 , so that the resin layer 5 is combined with the anodized film 4 through nanopores.
[0038] According to the present invention, preferably, in step (a), the titanium or titanium alloy primer layer 2 is first deposited on at least part of the surface of the titanium or titanium alloy substrate 1 ...
Embodiment 1
[0063] This example is used to illustrate the composite body of titanium and resin of the present invention and its preparation method.
[0064] (a) Substrate pre-treatment: cut 0.8mm thick TA1 titanium plate into 15mm×80mm rectangular pieces, put it into a polishing machine and polish it for 20min, and use cathodic electrolytic degreasing until the degreasing is clean (the electrolyte composition is 30g / L sodium phosphate, 30g / L sodium carbonate, working temperature is 70°C, working time is 2min, current density is 5A / dm 2 ), then washed with water, and baked at 80°C for 10 minutes to obtain the pretreated titanium substrate 1.
[0065] (b) Magnetron sputtering coating: Put the above-mentioned pretreated titanium substrate 1 into an intermediate frequency magnetron sputtering ion coating machine, when the pressure in the furnace is 1.0×10 -2 Argon gas was introduced at Pa, and argon ion bombardment treatment was carried out. The conditions of argon ion bombardment treatment ...
Embodiment 2
[0073] This example is used to illustrate the composite of titanium alloy and resin and its preparation method of the present invention.
[0074] (a) Substrate pretreatment: Cut the 0.8mm thick titanium alloy TC4 into 15mm×80mm rectangular pieces, put it into the polishing machine and polish it for 20min, and use cathodic electrolytic degreasing until the degreasing is clean (the electrolyte composition is 30g / L sodium phosphate, 30g / L sodium carbonate, working temperature is 70°C, working time is 2min, current density is 5A / dm 2 ), then washed with water, and baked at 80° C. for 10 minutes to obtain the pretreated titanium alloy substrate 1 .
[0075] (b) Magnetron sputtering coating: Put the above pretreated titanium alloy substrate 1 into an intermediate frequency magnetron sputtering ion coating machine, when the pressure in the furnace is 1.0×10 -2 Argon gas was introduced at Pa, and argon ion bombardment treatment was carried out. The conditions of argon ion bombardment...
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